Revised edition: 26.05.2015 1. 1. 1. Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Fluorescent Pigment Violet 1. 2. Article No.: 56450 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Fluorescent pigment for the production of paint, printing inks and coatings. 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr. 41-47, 88317 Aichstetten, Germany Tel./Fax.: Tel +49 7565 914480, Fax +49 7565 1606 Internet: EMail: www.kremer-pigmente.de info@kremer-pigmente.de 1. 4. 2. 2. 1. Importer: -- Emergency No. Emergency No.: +49 7565 914480 (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) Classification according to Directive No. 67/548/EC or No. 1999/45/EC This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: 2. 2. Possible Environmental Effects: Label Elements Classification according to Regulation (EC) No. 1272/2008 (CLP/GHS) This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: Safety designation: EUH208 May produce an allergic reaction. Hazardous components for labelling: 2
2. 3. 3. 3. 1. 3. 2. Other Hazards Composition/Information on Ingredients Substance Mixture Page 2 Contains formaldehyde: can cause allergic reactions. Formaldehyde can be released when heated. Chemical Characterization: Triazine-toluene sulfonamide-paraformaldehyde polycondensation resin with synthetic coloring matter. CAS No.: Mixture Information on Components / Hazardous Ingredients: Formaldehyde (T, Carc.Cat.3; R23/24/25-34-40-43; H301-311-314-317-331-341-350); REACH Reg.No. 01-2119488953-20-xxxx <0.1 % CAS-Nr: 50-00-0 EINECS-Nr: 200-001-8 EC-Nr: 605-001-00-5 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Remove contaminated clothes immediately. Supply fresh air and seek medical advice in case of complaints. Remove contaminated clothing. Wash with soap and rinse with plenty of water. Rinse open eyes with plenty of water. In case of discomfort seek medical help. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth thoroughly with plenty of water. Do not induce vomiting. Consult physician immediately. Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Foam, carbon dioxide, extinguishing powder, water, water mist. 3
Unsuitable extinguishing media: Water with full jet. 5. 2. Special Hazards arising from the Substance or Mixture Page 3 5. 3. Special hazards: Advice for Firefighters Protective equipment: Dust can form explosive mixtures with air. In case of fire: formation of toxic fumes. Wear self-contained respiratory protective device. 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Avoid contamination of sewage system, open water ways and ground water. 6. 2. Personal precautions: Environmental Precautions Avoid contact with skin and eyes. Do not ingest or inhale. Wear protective clothing. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid dust formation. Protective clothing, see Section 8. See Section 13 for information on disposal. The usual precautionary measures are to be adhered to when handling chemicals. Avoid formation of dust. Provide adequate ventilation. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Do not eat or drink during work. Do not smoke. Storage conditions: Store in tightly sealed containers in a dry room. Protect against overheating. Requirements for storage areas and containers: 4
Information on fire and explosion protection: Storage class (VCI): Page 4 Do not store together with: oxidants. Take measures to prevent electrostatic discharge. 7. 3. Further Information: Specific End Use(s) When the product is applied at higher temperatures, formaldehyde is released. Provide adequate ventilation. 8. 8. 1. Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): Parameters to be controlled: Formaldehyde (CAS 50-00-0); TWA: 0.3 ppm, 0.37 mg/m3; 2 (I) Formaldehyde (CAS 50-00-0); TWA, STEL: GB (EH40): 2 ppm, 2.5 mg/m3 ; FR (VLEP): 0.5 ppm, 1 ppm; NL (MAC): 0.15 ppm, 0.5 mg/m3 Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Do not inhale dust. Do not eat, drink or smoke while working. Wash hands before breaks and at the end of work. Dust mask. Suitable protective gloves recommended, e.g. glove material: nitrile rubber (NBR). Protective glove material: Eye protection: Body protection: Safety glasses with protective shields (EN 166). Protective clothing. Environmental precautions: 9. Physical and Chemical Properties 5
9. 1. Information on Basic Physical and Chemical Properties Page 5 Form: powder Color: violet Odor: neutral Odor threshold: ph-value: 7-10.5 (5g in 100 cc H2O) Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: no information available Lower explosion limit: no information available Vapor pressure: Vapor density: Density: 1.38 g/ml Solubility in water: insoluble Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: No data available. Viscosity, dynamic: Explosive properties: Oxidizing properties: no information available 6
Bulk density: not determined 9. 2. Further Information Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Stable if used according to specifications. Hazardous polymerisation will not occur. Avoid dusting near sources of ignition. Avoid heat. Avoid heat. Strong acids, strong bases and strong oxidizing agents. Carbon oxides, nitrogen oxides, sulfuric oxide, toxic fumes/vapors. Formaldehyde: 600 mg/kg (rat) Formaldehyde: 270 mg/kg (rabbit) Formaldehyde: 0.578 mg/l (4h; rat) Irritant effect on skin: Irritating to skin. 7
Irritant effect on eyes: Irritating to eyes. Page 7 Inhalation: Can cause irritation of the respiratory system. Ingestion: 12. 12. 1. Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: No data available. Formaldehyde: Carc. 1B (EC) No data available. Formaldehyde: LC50: 22.6-25.7 mg/l flow-through (96h; Pimephales promelas); LC50: 1510 µg/l static (96h; Lepomis macrochirus); LC50: 41 mg/l static (96h; Brachydanio rerio); LC50: 0,032-0,226 ml/l flow-through (96h, Oncorhynchus mykiss); LC50: 100-136 mg/l static (96h, Oncorhynchus mykiss); LC50: 23.2-29.7 mg/l static (96h; Pimephales promelas) Formaldehyde: LC50: 2 mg/l (48h; Daphnia magna); EC50: 11.3-18 mg/l static (48h; Daphnia magna) no information available Algae toxicity: 12. 2. Persistency and Degradability 12. 3. Bioaccumulation Formaldehyde: logpow 0.35 12. 4. Mobility Product is not water soluble. 12. 5. Results of PBT- und vpvp Assessment No data available. 8
12. 6. Other Adverse Effects Page 8 Water hazard class: 2 (German Regulation) (Assessment by list): hazardous. Behaviour in sewage systems: Further ecological effects: 13. 13. 1. AOX Value: Disposal Considerations Waste Treatment Methods Product: In accordance with current regulations, product may be taken to an incineration plant. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name 14. 3. 14. 4. ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. ADR/RID: 9
IMDG: Page 9 14. 5. 14. 6. 14. 7. 14. 8. 15. 15. 1. IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: 2, hazardous for water (German Regulation) Local regulations on chemical accidents: Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles: 15. 2. 15. 3. 16. Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information The product/preparation is registered in the following national inventories: EINECS, AICS (AUS), MITI/ENCS (JP), LECS (KR), PRC (CN) EC. REACH, Annex XIV, Candidate List of Substances of very High Concern (SVHC): not regulated / This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.