Summary of the Project 1. INTRODUCTION Rotam Crop Protection Pvt. Ltd (RCPPL), proposes to manufacture different types of crop protection products at Plot no.: G- 154,155,156,157,164,165, 166,167, RIICO Industrial area, Village: Sanwad, Tehsil: Mavli, Dist.: Udaipur, Rajasthan, (India)-313205. RCPPL is subsidiary of Rotam Crop Sciences Ltd. which maintains its Corporate Office in Hong Kong. Rotam have strong R&D and manufacturing base in China, Taiwan, Brazil and other countries of the globe. On our strong inspiration for the research skills in India and also with growing market in crop protection products have planned to set up strong R&D and manufacturing base in Sanwad, Udaipur, India. The Rotam Crop Protection Pvt. Ltd. is registered under District Industries Centre, Udaipur in April 2012 for establish of a manufacturing unit for production of Crop protection product Technical, intermediates & formulations. 2. COST OF PROJECT:- The estimated cost of the project for the proposed new manufacturing project is estimated around INR 30 crores. Out of this around INR 3 crores will be invested for pollution control measures. 3. PRODUCTION CAPACITY Production capacity is prescribe below: List of Products Sr. Name of Products Quantity* (MT/Month) Quantity* (MT/Annum) A Plant-1 1. Fenpropimorph 28 300 2. Lambda Cyhalothrin 28 300 3. Tebuconazole 28 300 4. Thiamethoxam 28 300 5. Thiodicarb 14 150 6. Imidacloprid 28 300 7. Dicamba 28 300 8. Boscalid 22.4 240 9. Mesotrione 22.4 240 10. Oxamyl 22.4 240 M/s. Rotam Crop Protection Pvt. Ltd. 0
11. Pyraclostrobin 22.4 240 12. Prothioconazole 22.4 240 13. Tefluthrin 22.4 240 14. Chlorantraniliprole 22.4 240 15. Cyantraniliprole 22.4 240 B Plant-2 16. Nicosulfuron 14 150 17. Metsulfuron 14 150 18. Rimsulfuron 14 150 19. Sulfometuron 14 150 20. Flazasulfuron 14 150 21. Thifensulfuron 14 150 22. Tribenuron 14 150 23. Idosulfuron 14 150 24. Flufenacet 14 150 25. Mesosulfuron 14 150 C R&D products 1.0 12.0 *Note: Unit will have total production capacity 1250 TPA, out of above. The total annual capacity covering product no. 1 to 7 shall not exceed beyond 850 TPA the product as above shall be taken on campaigning basis and plant is designed to take three products simultaneously. Total annual capacity covering product no. 8 to 15 shall not exceed beyond 250 TPA. Only one product from above shall be taken on campaigning basis and plant is designed to produce one products from above at one given time. The total annual capacity covering product no. 16 to 25 shall not exceed beyond 150 TPA the product as above shall be taken on campaigning basis and plant is designed to take one product at a time. List of Raw materials S. Name of Raw Materials Quantity (MT/MT) 1 Fenpropimorph 1 Methylene dichloride (MDC) 1,142 2 4-tert-butylbenzene 633 3 Propionyl chloride 436 4 Aluminium chloride (solid) 629 5 Hydrochloric acid(hcl) 224 6 Dimethyl formamide (DMF) 1,572 7 Phosphorous oxychloride 1,815 8 Sodium hydroxide 3,333 9 Ethylene dichloride (EDC ) 776 10 Palladium on carbon (catalyst,pd/c) 65 11 Methanol 402 12 Toluene 128 13 2,6-Dimethylmorpholine 402 2 Lambda Cyhalothrin 1 n-hexane 495 2 Lambda acid (k-acid) 625 M/s. Rotam Crop Protection Pvt. Ltd. 1
S. Name of Raw Materials Quantity (MT/MT) 3 Dimethyl formamide (DMF) 8 4 Thionyl chloride 310 5 Sodium cyanide 180 6 m-phenoxy benzaldehyde (MPB) 445 7 Triethyl amine (TEA) 120 8 Sodium hypochloride 800 9 Isopropyl alcohol (IPA) 298 3 Tebuconazole 1 Toluene 39 2 Methanol 400 3 p-chlorobenzaldehyde (solid) 600 4 Pinacolone 428 5 Raney nickel (catalyst) 5 6 Tetrahydrofuran(THF) 840 7 Sodium hydroxide 520 8 Hydrogen gas 0 9 Triethylsulfonium iodide (yellow crystalline sloid) 840 10 Potassium hydroxide Flakes 260 11 Ethyl acetate 902 12 1,2,4-Trizole 320 13 Ethanol 400 14 Tetrabutylammonium bromide(tbab) 7 15 Sodium hydroxide 10 4 Thiamethoxam 1 Dimethyl carbonate 307 2 2-chloro-5-chloromethylthiazole (Solid) 764 3 3-methyl-4-nitroimino-perahydro-1,3,5- oxadiazine (Solid) 836 4 Tetramethylammonium hydroxide pantahydrate 18 5 Potassium carbonate (K 2 CO 3 ) 1100 6 Hydrochloric acid (HCl) 1182 5 Thiodicarb 1 Pyridine 42 2 Sulfur dichloride 218 3 Methomyl (solid) 508 4 Sodium hydroxide 229 5 Sodium chloride 470 6 Imidacloprid 1 Butanone 60 2 2-nitroimino imidazolidine (solid) 510 3 2-chloro-5-chloromethylpyridine 577 4 Benzyltriethylammonium chloride (BTEAC Catalyst) 4 5 Potassium carbonate (K 2 CO 3 ) 491 6 Ethanol 60 7 Dicamba 1 Methanol 250 2 1,2,4- Trichlorobenzene 1508 3 Sodium hydroxide flakes 1157 4 Hydrochloric acid (HCl) 6036 5 Xylene 208 6 2,5-Dichlorophenol 850 7 Potasium hydroxide solution 567 M/s. Rotam Crop Protection Pvt. Ltd. 2
S. Name of Raw Materials Quantity (MT/MT) 8 Anhydrous Potassium carbonate 650 9 CO 2 Gas feeding 253 10 3,6-Dichlorosalicilic acid 1083 11 Dimethyl sulfate 1458 12 Caustic lye 3331 8 Boscalid 1 2-Chloro-3-nicotinyl chloride 540 2 2-(4-chlorophenyl)aniline 625 3 Triethyl amine 100 4 Toluene 157 9 Mesotrione 1 1,3-cyclohexadione 387 2 Ethylene dichloride 180 3 Acetone cyanohydrin 107 4 Triethylamine 100 5 2-nitro-4-methylsulfonyl benzoyl chloride 914 6 Sulfuric acid 835 7 Sodium hydroxide 1000 10 Oxamyl 1 Methyl-2-(dimethylamino)-N-hydroxy-2- oxoethanimidothioate 737 2 Sodium cyanate 350 3 Dimethyl sulfate 650 4 Trimethyl amine 18 5 Acetonitrile 140 6 Methylene chloride 180 11 Pyraclostrobin 1 1-(4-Chlorophenyl)-3-hydroxy-1H-pyrazole 530 2 Methyl [2-(bromomethyl) phenyl]methoxycarbamate 750 3 Potassium carbonate 195 4 Dimethyl formamide (DMF) 3450 12 Prothioconazole 1 Thiosemicarbazide derivative 1040 2 isobutyl formate 2500 3 formic acid 250 4 Ethyl acetate 3250 5 40% Ammonium chloride solution 2540 6 Toluene 2400 13 Chlorantraniliprole 1 2-Amino-5-chloro-N-3-dimethylbenzamide 440 2 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5- carbonyl chloride 706 3 Triethyl amine 225 4 Toluene 3150 14 Tefluthrin 1 3-[(1E)-2-chloro-3,3,3-trifluoroprop-1-en-1-yl]- 2,2-dimethylcyclopropane carbonylchloride 675 2 4-methyl-2,3,5,6-tetratluorobenzyl alcohol 503 3 Pyridine 208 4 Toluene 3650 5 5% Hydrochloric acid 1000 6 10% sodium bicarbonate 1500 M/s. Rotam Crop Protection Pvt. Ltd. 3
S. Name of Raw Materials Quantity (MT/MT) 15 Cyantraniliprole 1 2-Amino-5-cyano-N,3-dimethylbenzamide 430 2 3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5- carbonyl chloride 725 3 Triethyl amine 230 4 Xylene 3320 16 Nicosulfuron 1 2-ethoxycarbonylaminosulfonyl-N,N-dimethyl-3- pyridinecarboxamide 809 2 2-Amino-4,6-dimethoxypyrimidine 404 3 Toluene 173 4 Sodium carbonate 250 5 Hydrochloric acid( HCl) 240 17 Metsulfuron 1 o-carboxymethylphenylisocyanate 680 2 2-amino-4-methoxy-6-methyl-1,3,5-triazine 395 3 Triethyl amine 210 4 Acetonitrile 163 18 Rimsulfuron 1 3-(Ehylsulfonyl) pyridine-2-sulfonamide 562 2 Phenyl (4,6-dimethoxypyrimidin-2-yl)carbamate 515 3 Acetonitrile 99 4 Triethylamine 515 5 Hydrochloric acid 550 6 Ethyl acetate 29 19 Sulfometuron 1 4,6-dimethylpyrimidin-2-amine (DMPA ) 346 2 methyl 2-(isocyanatosulfonyl)benzoate (MICNSB) 711 3 Triethylamine 2 4 Acetonitrile 167 20 Flazasulfuron 1 Methyl {[3-(trifluoromethyl)pyridin-2- yl]sulfonyl}carbamate 800 2 4,6-dimethoxy pyrimidin-2-amine 435 3 Triethylamine (TEA) 102 4 Acetonitrile 149 5 MeOH 70 21 Thifensulfuron 1 methyl 3- {[(methoxycarbonyl)amino]sulfonyl}thiophene- 2-carboxylate 764 (MMASTC) 2 4-methoxy-6-methyl-1,3,5-triazin-2-amine (MMTA) 389 3 Acetone 141 4 Potassium carbonate 278 5 Methylchloroformate (liquid) 5 6 Hydrochloric acid 206 22 Tribenuron 1 Methyl 2-(isocyanatosulfonyl) benzoate 650 2 4-Methoxy-N,6-dimethyl-1,3,5-triazin-2-amine 415 3 Acetonitrile 133 M/s. Rotam Crop Protection Pvt. Ltd. 4
S. Name of Raw Materials Quantity (MT/MT) 4 Triethylamine 515 5 Hydrochloric acid 340 23 Idosulfuron 1 2-(aminosulfonyl)-4-iodobenzoic acid 795 2 2-isocyanato-4-methoxy-6-methyl-1,3,5-triazine 405 3 Triethylamine 515 4 Toluene 163 5 Hydrochloric acid 451 6 Acetonitrile 75 24 Flufenacet 1 N-(4-fluorophenyl)-2-hydroxy-Nisopropylacetamide 520 2 2-(Methylsulfonyl)-5-(trifluoromethyl)-1,3,4- thiadiazole 635 3 p-toluenesulfonic acid (Catalyst, PTSA) 6 4 Sodium hydroxide 369 5 Hydrochloric acid 160 6 Methanol 70 7 Ethylene dichloride 123 25 Mesosulfuron 1 Methyl 2-(aminosulfonyl)-4- {[(methylsulfonyl)amino]methyl}benzoate 780 2 2-Isocyanato-4,6-dimethoxypyrimidine 440 3 Triethylamine 489 4 Toluene 178 5 Hydrochloric acid 500 6 Ethyl acetate 1400 4. Manufacturing Process Detailed manufacturing process is given in Annexure-II of form-1. 5. Water Balance: The total water requirement will be 216.5 KL/day (143 Fresh + 73.5 recycle) which will fulfill by RIICO water supply. The breakup of water consumption is given below: Sr. Sources Water consumption kl/day 1. Domestic 6.0 2. Process & lab 32.0 3. Water treatment 9.0 4. Cooling 43 + 59* 5. Boiler 48 6. Gardening 14.5* 7. Floor washing 5.0 Total 216.5 (143+73.5*) M/s. Rotam Crop Protection Pvt. Ltd. 5
Water balance diagram All units are in KLD Water consumption 216.5 KLD (143 Fresh + 73.5* recycle) Domestic 6 Process & Lab 32 Washing 5 Utilities 100 Green belt 14.5* Water retained With RM 12 Drying/Evp. Loss 2.0 Water treatment 100 Domestic effluent 5.0 Effluent 41 Scrubber 1 9 Soak pit Cooling 59*+43 Boiler 48 20 0.5 20.5 ETP 41 +1+5+9+20.5=76.5 KLD Reject 30 RO 76.5 Permeate 46.5* Salt 3 MEE 30 Condensate 27* To Land fill site M/s. Rotam Crop Protection Pvt. Ltd. 6
6. Manpower requirements: Total manpower requirement at all level of plant will be in the range of 60-70. 7. SOURCE OF POLLUTION Details of Air Pollution There will be only one flue gas stack and two process gas stacks which are the main emission source from the plant under the Air Pollution Control Act, 1981. FO will be used as a fuel. Proper Stack height will be provided in order to achieve norms prescribed by statutory authority. The details of stacks are given below: Sr. Stack attached to Fuel Type Stack Height APC measures Probable emission Flue Gas Stacks 1 Boiler (steam generation) 4T/hr FO-190 kg/hr 30 m -- PM<150 mg/nm 3 SO 2 <80 ppm NO x <80 ppm 2 Boiler 4T/hr (stand by) PM<150 mg/nm 3 SO 2 <80 ppm NO x <80 ppm 3 D.G. set (1 x 250 KVA) HSD-50 ltr./hr 11 m - PM<150 mg/nm 3 SO 2 <80 ppm NO x <80 ppm Process Gas stacks 1 Vent attached to -- 11 m Alkali scrubber HCl<20 mg/m 3 Lambda followed by Cl 2 <9 mg/m 3 Cyhalothrin water scrubber reactor 2 Vent attached to -- 11 m Alkali scrubber HCl<20 mg/m 3 Fenpropimorph followed by SO 2 <45 mg/m 3 reactor water scrubber Source of Wastewater The main source of the industrial wastewater generation will be from process, washing and utilities. Entire quantity of wastewater will be treated in ETP. Treated water from ETP will be passed through RO & M/s. Rotam Crop Protection Pvt. Ltd. 7
Sr. reject of RO will be sent to MEE for further treatment. RO permeate & Condensate from MEE will be reused for utility & greenbelt development, so there will be no effluent discharge from unit. Domestic effluent will be disposed of into soak pit. Source and disposal of Hazardous wastes There will be seven sources of Solid/hazardous waste generation. ETP Sludge will be disposed off to approve TSDF site. Waste carbon, process residue & off specific products will be sent for Incineration at CHWIF (common hazardous waste incineration facility) approved by RSPCB. Spent oil will be sold to actual users and Drums & liners will be sold to registered recyclers. The details of Solid/hazardous waste are given below: Type of Waste Sources Category of Waste as per HWM Rules 2008 Quantity in MTPM Disposal facility 1. ETP Sludge ETP 34.3 112 Collection, Storage, Transportation & Disposal at TSDF site approved by RSPCB. 2. Waste Carbon 3. Process Reside 4. Off specific products 5. Discarded containers/ liners 6. Used Lubricating Oil Process 35.3 1.0 Collection, Storage, & Incineration at CHWIF (common hazardous waste incineration facility) approved by RSPCB. Process 29.1 20 Collection, Storage, & Incineration at CHWIF (common hazardous waste incineration facility) approved by RSPCB. Process 29.3 As & when generated Process 33.3 Drum:500 Nos./month Liner:0.2 MT/month Driving unit & D.G. set Collection, Storage, & Incineration at CHWIF (common hazardous waste incineration facility) approved by RSPCB. Being used for packing of ETP sludge in case of excess it will be sold to approved recycler or traders. 5.1 1.0 Kl/Year Collection, Storage, Transportation & disposal by selling to Registered Recyclers M/s. Rotam Crop Protection Pvt. Ltd. 8
8. Funds for pollution control measures The management is quite conscious of its responsibility for maintaining clear environment adequate funds can be provided for the pollution control measures as a part of overall project financing. Necessary provision for Environmental management system is in practice and will be part of practice in future expansion projects. M/s. Rotam Crop Protection Pvt. Ltd. 9