Date of issue: 10/12/2013 Revision date: 10/12/2013 Supersedes: 16/10/2009 Version: 8.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Name : Product code : LEADE008 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Use of the substance/mixture : Fertilizers 1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Supplier TIMAC AGRO USA, INC P.O. Box 888 - Route 724 & I-176 READING - USA T 1-800-545-5474 info-fds@roullier.com Manufacturer TIMAC AGRO 27 avenue Franklin Roosevelt 35408 Saint-Malo cedex - FRANCE T +33 2 99 20 65 20 info-fds@roullier.com - www.roullier.com 1.4. Emergency telephone number Emergency number : USA Poison Control Center: 1-800-222-1222 Americas : +1-760-476-3962 (Access code : 333021) - Europe/Middle-East/Africa :+1-760-476-3961 (Access code : 333021) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP]Show CLP information + DPD classification in section 2.1 Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove the victim into fresh air. If you feel unwell, seek medical advice. : Wash with plenty of soap and water. If on skin and if skin irritation occurs, seek medical advice and attention. : Immediately rinse with water for a prolonged period while holding the eyelids wide open. Consult an eye specialist if an irritation appears. : Give water to drink if victim completely conscious/alert. If you feel unwell, seek medical advice. 17/11/2014 EN (English) SDS Ref: LEADE008 1/6
4.2. Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed No data / information available. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Chemical powder. Foam. CO2. : None. 5.2. Special hazards arising from the substance or mixture Fire hazard Hazardous decomposition products in case of fire : Non combustible. : Decomposition of the compound under heat into irritating or toxic vapours, carbon monoxide and carbon dioxide. 5.3. Advice for firefighters Protection during firefighting Other information : Do not enter or remain in the danger zone without protection clothing. Wearing autonomous, insulating breathing equipment is recommended when entering the danger zone. : Avoid pouring fire water down the drains. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Refer to protective measures listed in Sections 7 and 8. 6.1.1. For non-emergency personnel 6.1.2. For emergency responders 6.2. Environmental precautions Do not allow into drains or water courses. 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections SECTION 8. SECTION 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling : Take up liquid spill into inert absorbent material. : Recuperate the compound in an appropriate container for evacuation and disposal. Clean contaminated surfaces with an excess of water. Precautions for safe handling : Concerning personal protective equipment to use, see section 8. Hygiene measures 7.2. Conditions for safe storage, including any incompatibilities Storage conditions 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Wash hands after working with the product. Wash contaminated clothing before reuse. Do not drink, eat or smoke in the workplace. : In its original packaging, in a ventilated place, in an area resistant to corrosion, away from frost, at temperatures below 40 C, away from foodstuffs and reactive materials. : 17/11/2014 EN (English) SDS Ref: LEADE008 2/6
8.2. Exposure controls Personal protective equipment : Gloves. Safety glasses. Hand protection Eye protection Skin and body protection Respiratory protection Other information : butyl rubber gloves. Latex gloves. : Safety glasses. : Skin protection appropriate to the conditions of use should be provided. : No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. : Handle in accordance with good industrial hygiene and safety practice. Wash hands after working with the product. Wash contaminated clothing before reuse. Do not drink, eat or smoke in the workplace. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : brown. Odour : slight ammonia. Odour threshold ph : 8-9 Relative evaporation rate (butylacetate=1) Melting point Freezing point : < -1 C Boiling point : > 100 C Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density : 1210 kg/m³ Solubility : Water: Miscible in all proportions Log Pow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : 9.2. Other information SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability Stable under normal conditions of use. 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Freezing. High temperature. 10.5. Incompatible materials None, to our knowledge. 10.6. Hazardous decomposition products In the event of fire: see chapter 5. 17/11/2014 EN (English) SDS Ref: LEADE008 3/6
SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard SECTION 12: Ecological information 12.1. Toxicity Ecology - general Ecology - water ph: 8-9 ph: 8-9 : Avoid discharging large quantities of product into the environment. : Do not allow into drains or water courses. 12.2. Persistence and degradability Persistence and degradability 12.3. Bioaccumulative potential Bioaccumulative potential 12.4. Mobility in soil Ecology - soil Main components of the mixture have a good degradation. 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste treatment methods Additional information Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. : Disposal by incineration or reuse of the material through recycling after cleansing of product residues. Recycling or incineration by an approved company. : Do not allow into drains or water courses. 17/11/2014 EN (English) SDS Ref: LEADE008 4/6
SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number No dangerous good in sense of transport regulations 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards Dangerous for the environment Marine pollutant Other information : No : No : Not classified as a marine pollutant. 14.6. Special precautions for user 14.6.1. Overland transport 14.6.2. Transport by sea 14.6.3. Air transport 14.6.4. Inland waterway transport 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations No REACH Annex XVII restrictions Other information, restriction and prohibition regulations : All the constituents of this preparation are registered in the EINECS inventory or in the ELINCS list. Seveso Information : 15.1.2. National regulations Ensure all national/local regulations are observed 15.2. Chemical safety assessment 17/11/2014 EN (English) SDS Ref: LEADE008 5/6
SECTION 16: Other information Indication of changes: 3.2 Modified 4.1 Modified 6.2 Modified 6.3 Modified 6.4 Added 7.1 Modified 8.2 Modified 9.1 Modified 11 Modified 12.1 Added 13 Modified 14.5 Added Other information : according to Regulation (EC) No. 453/2010. according to Regulation (EC) No. 1907/2006 (REACH). SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 17/11/2014 EN (English) SDS Ref: LEADE008 6/6