1 CLIENT DETAILS Organisation: Company Contact: Origin Energy Services Ltd Eoghain Maguire Site Address: 101-103 Miller Street, North Sydney NSW 2060 Postal Address: Level 7, 321 Exhibition Street, Melbourne VIC 3000 Telephone Number: 02 9503 5799 Email Address: Eoghain.Maguire@originenergy.com.au 2 PROJECT DETAILS & SCOPE OF WORK REQUESTED Project Number: 610.16876.00000 Project Name: Project Manager: Annual Emission Testing Michael Brecko Monitoring Date(s): 28 November 2016 Production/Operational Conditions: Parameters requested: Normal (greater than 80% load) Molecular weight, dry gas density, nitrogen oxides, moisture, oxygen, temperature, flow, velocity and volatile organic compounds Sample Locations: EPA ID Points 1, 2, 3 and 4 Sample Identification Numbers: Refer to Section 4 This Test Report replaces previously issued SLR Report No. 610.16876.00000, dated 30 January 2017. Please destroy any previous NATA endorsed test reports issued under this SLR Report No. Signatory Michael Brecko Issue Date: 8 February 2017 Accredited for Compliance with ISO/IEC 17025. The results of the tests, calibration and/or measurements included in this document are traceable to Australian/national standards. This report cannot be reproduced except in full. Test Report Page 1 of 8
3 PROCESS EMISSIONS MONITORING - PARAMETER, SAMPLING AND ANALYSIS METHOD AND ANALYSIS LABORATORY 3.1 Test Methods and Analysis References All sampling and monitoring was performed by SLR Consulting Australia Pty Ltd (SLR Consulting) unless otherwise specified. The following table outlines for each parameter requested to be tested, the relevant test method for sampling and analysis and the NATA Accredited Laboratory that completed the analysis. All associated NATA endorsed Test Reports/Certificates of Analysis are provided separately in Section 4. 3.1.1 Point Source Emissions Parameter State Test Method Number for Sampling and Analysis NATA Laboratory Analysis By: NATA Accreditation No. & Report No. Sampling Location NSW TM-1, AS4323.1 Velocity NSW TM-2, USEPA M2A, 2C Duct Temperature NSW TM-2, USEPA M2, 2C Volumetric Flow Rate NSW TM-2, USEPA M2A, 2C Duct Pressure NSW TM-2, USEPA M2, 2C Dry Gas Density NSW TM-23, USEPA M3 Moisture NSW TM-22, USEPA M4 Molecular Weight of Stack Gases NSW TM-23, USEPA M3 Oxygen NSW TM-25, USEPA M3A Oxides of Nitrogen NSW TM-11, USEPA M7E, 7D Volatile Organic Compounds NSW TM-34, USEPA M18 Testsafe Australia, Accreditation No. 3726, Report No. 2016-3937 Test Report Page 2 of 8
3.2 Deviations from Test Methods There were no deviations to the test methods. 3.3 Sampling Times As per the relevant test reference method or State requirement. 3.4 Reference Conditions As per relevant test reference method, State requirement, or Environment Protection Licence or equivalent. 3.5 Identification All samples are individual labelled with reference number, location, sampling date and times. 3.6 Sampling Plane Details Ideal sampling positions: In the absence of cyclonic flow activity ideal sampling plane conditions will be found to exit at 7-8 diameters downstream and 2-3 diameters upstream from a flow disturbance. However, in most cases, a suitable sampling plane will be a position fitting the minimum criteria specified in Table 1 of AS4323.1. Non Ideal sampling position: If the measurement near a bend is unavoidable, the sampling position shall be greater than one duct diameter upstream of the bend or greater than two duct diameters downstream of the bend. When the criteria in Table 1 of AS4323.1 cannot be met, a greater number of sampling points shall be used in order to retain as much accuracy as is practicable. 2A 2B 1A 1B Test Report Page 3 of 8
Parameter Co-ordinates EPA ID Point 1 (Stack 1A) UTM 56H 334106.34m E 6254199.32m S EPA ID Point 3 (Stack 1B) UTM 56H 334106.34m E 6254199.32m S EPA ID Point 2 (Stack 2A) UTM 56H 334106.34m E 6254199.32m S EPA ID Point 4 (Stack 2B) UTM 56H 334106.34m E 6254199.32m S Elevation (ASL) (m) 130m 130m 130m 130m Duct Diameter (m) 0.300 0.300 0.300 0.300 Upstream Requirements Type of Disturbance Exhaust Exit Exhaust Exit Exhaust Exit Exhaust Exit Distance to Disturbance (m) 1.33 1.33 1.33 1.33 No. of Duct Diameters 4.4D 4.4D 4.4D 4.4D Ideal Minimum Distance Criteria 2D 2D 2D 2D Diameters less than Ideal Criteria 0 0 0 0 Sampling Factor 1.00 1.00 1.00 1.00 Downstream Requirements Type of Disturbance Bend (Fan) Bend (Fan) Bend (Fan) Bend (Fan) Distance to Disturbance (m) 4.30 4.30 4.30 4.30 No. of Duct Diameters 14D 14D 14D 14D Ideal Minimum Distance Criteria 8D 8D 8D 8D Diameters less than Ideal Criteria 0 0 0 0 Sampling Factor 1.00 1.00 1.00 1.00 Number of sampling points for manual isokinetic sampling Minimum No. of Sampling Traverses 2 2 2 2 Minimum No. of Access Holes 2 2 2 2 Minimum No. of Sampling Points 4 4 4 4 Combined Sampling Factor 1.00 1.00 1.00 1.00 Total No. of Sampling Points required 4 4 4 4 Comments SLR adopted a total of 12 sampling points to improve the accuracy of the measurement. SLR adopted a total of 12 sampling points to improve the accuracy of the measurement. SLR adopted a total of 12 sampling points to improve the accuracy of the measurement. SLR adopted a total of 12 sampling points to improve the accuracy of the measurement. 3.7 Results Results are presented at actual conditions unless otherwise stated. All volumes and concentrations are reported as dry at temperature of 0 o C and at absolute pressure of 101.3 kpa unless otherwise stated. Where measured values have been corrected to reference conditions (i.e. normalised or standardised ) the measured values are reported prefixed with an N (e.g. Nm 3 ). Test Report Page 4 of 8
Parameter Unit Reporting Conditions Average Measured Value Location -- -- EPA ID Point 1 (Stack 1A) EPA ID Point 3 (Stack 1B) EPA ID Point 2 (Stack 2A) EPA ID Point 4 (Stack 2B) Date Tested -- -- 28-Nov-16 28-Nov-16 28-Nov-16 28-Nov-16 Sampling start times hours AESTD 7:55 7:55 10:41 10:41 Sampling finish times hours AESTD 9:20 9:15 12:00 12:00 Duct diameter m actual 0.30 0.30 0.30 0.30 Cross sectional area m 2 actual 0.071 0.071 0.071 0.071 Temperature o C actual 363 353 363 347 Velocity m/s actual 23.3 20.0 20.9 22.0 Volumetric Flow m 3 /s actual 1.65 1.41 1.48 1.55 Volumetric Flow Nm 3 /s 101.3kPa, 0 o C, dry 0.64 0.55 0.57 0.62 Atmospheric Pressure kpa actual 101.5 101.5 101.5 101.5 Absolute Stack Pressure kpa actual 101.3 101.3 101.3 101.3 Molecular Weight Dry Stack Gas g/g mole actual, dry 29.2 29.3 29.3 29.2 Gas Density kg/m 3 actual, dry 1.3 1.3 1.3 1.3 Moisture % by vol. actual 9.6 10.1 10.2 9.3 Oxygen % Carbon Dioxide % 101.3kPa, 0 o C, dry 101.3kPa, 0 o C, dry 13.6 12.5 11.8 13.5 4.0 4.7 5.2 4.3 Carbon Monoxide mg/nm 3 101.3kPa, 0 o C, dry Nitrogen Oxides (as NO 2) mg/nm 3 0 o C, dry, corrected to 101.3kPa, 5% O 2 434 507 530 428 237 239 233 249 Volatile Organic Compounds (as n-propane equivalent) mg/nm 3 101.3kPa, 0 o C, wet, corrected to 5% O 2 15.0 2.03 1.40 10.0 EPA ID Point 1, 2, 3 and 4 Nitrogen Oxide (as NO 2) 100 percentile concentration limit is 250 mg/m 3 at 5% O 2. EPA ID Point 1, 2, 3 and 4 Volatile organic compounds 100 percentile concentration limit is 40 mg/m 3 at stack O 2. Test Report Page 5 of 8
Key: C = degrees Celsius < = less than % = percentage AESTD = Australian Eastern Standard Time Daylight Savings EPA ID = Environment Protection Agency Identification kg/m 3 = kilograms per cubic metre of air kpa = kilopascals g/g mole = grams per gram mole m 3 /s = cubic metre of air per second m = metres m 2 = metres square m/s = metres per second mg/m 3 = milligrams per cubic metre of air NO 2 = Nitrogen dioxide O 2 = oxygen ppm = parts per million 3.8 Instrument Calibration Details Asset No. Instrument Description Date Last Calibrated Calibration Due Date 2002, 2004 VOC Sampling Pump 30/06/2016 & On-site pre & post calibrations 30/06/2017 1789 Digital Barometer 21/03/2016 21/03/2017 2060 Field Balance On use within ±2g of Field Mass On use within ±2g of Field Mass Satisfactory for use 1793 Field Mass (100g) 26/03/2016 26/03/2017 2388 Gas Analyser 08/11/2016 08/05/2017 2100 Gas Analyser 08/11/2016 08/05/2017 2323 Diluter 25/08/2016 25/08/2018 1809 Manometer (Digital) 09/04/2016 09/04/2017 1833 Pitot Tube 28/06/2013 Visual inspection for damage, defects or blockages on use Satisfactory for use 1839 Thermocouple 10/10/2016 10/04/2017 1805 Thermometer (Digital) 05/09/2016 05/03/2017 1828 Timepiece 2325 Volumetric Air Flow Calibrator I-phone satellite reference NA 16/03/2016 16/03/2017 Test Report Page 6 of 8
3.9 Calibration Gases Information Special Gas Mixtures Certified Concentration Cylinder No. Expiry Date NO NO x 2,000 ppm 2,020 ppm ALSY0579 06/02/2018 CO 980 ppm ALTU2297 14/01/2018 O 2 10.1% ALTV2608 14/05/2019 CO 2 9.8% ALTV2608 14/05/2019 3.10 Measurement Uncertainty Parameter Associated Test Method Uncertainty Velocity TM-2, AS 4323.1, USEPA M2A, 2C ± 5% Temperature TM-2, USEPA M2C +2 o C Moisture TM-22, USEPA M4 ± 25% Oxygen TM-25, USEPA M3 ± 15% Carbon monoxide TM-32, USEPA M10 ± 15% Carbon dioxide TM-24, USEPA M3 ± 15% Nitrogen oxides TM-11, USEPA 7E ± 15% Volatile organic compounds (adsorption tube) TM-34, USEPA M18 ± 25% Test Report Page 7 of 8
4 CERTIFICATES OF ANALYSIS Test Report Page 8 of 8