Environment Laboratory, Central Mine Planning and Design Institute Limited, Gondwana Place, Kanke Road, Ranchi, Jharkhand

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Environment, Central Mine Planning and Design Institute Last Amended on - Page 1 of 9 1. POLLUTION & EFFLUENTS 1. Effluent / Waste Water Ammonical Nitrogen Free Ammonia IS 3025 (Part 34):1988, Nessler s Method 0.02-2.5 mg/l Arsenic IS 3025(Part 37):1988 RA : 2003 B.O.D (3 days 27 o C) IS 3025 (Part 44): 1993, RA : 2003 3 day incubation at 27 C 2.0-45.0 µg/l 2.00-100.00 mg/l Cadmium COD Closed Reflux, Titrimetric Method 0.5-15.00 µg/l 4.0-800.0 mg/l Chromium IS 3025 (Part 52) : 2003 AAS-Flame Copper IS 3025 (Part 42) : 1992 AAS-Flame 0.06-15.0 mg/l 0.03-10.0 mg/l Dissolved Phosphate, as PO4-3, Molybdovanadate Method 0.3-45.0 mg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 2 of 9 Iron IS 3025 (Part 53) : 2003, RA : 2009, 0.06-15.0 mg/l Fluoride Hexavalent Chromium SPANDS Method 1,5-Diphenylcarbohydrazide Method 0.01-0.7 mg/l Manganese IS 3025 (Part 59) : 2006, Nickel IS 3025 (Part 54) : 2003, 0.02-5.0 mg/l 0.1-20.0 mg/l Nitrate Nitrogen UV-Spectrphotometric Method 0.5-45.0 mg/l Oil & Grease IS 3025(Part 39):1991, RA : 2003, Partition Gravimetric Method 2.0-1000.0 mg/l Lead 5.0-100.0 µg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 3 of 9 ph value IS 3025 (Part 11):1983, RA : 1996, Electrometric Method 0.2-13.9 Phenolic Compounds 4-Amino antipyrine Method 0.002-0.25 mg/l Selenium IS 3025 (Part 56):2003, 2.0-35.0 µg/l Sulphide Methylene Blue Method 0.005-0.9 mg/l Temperature IS 3025 (Part 9):1984, RA : 2002, Thermometeric 0-100.0 o C Total Kjeldahl Nitrogen Total Residual Chlorine Kjeldahl Method DPD Method 1.0-150.0 mg/l Total Suspended Solids IS 3025 (Part 17):1984, RA : 1996, Gravimetric Method Zinc IS 3025 ( Part 49 ) : 1994, 10.0-5000.0 mg/l 0.01-10 mg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 4 of 9 II. WATER 1. Surface Water Arsenic IS 3025(Part 37):1988 RA : 2003 B.O.D (3 days 27 o C) IS 3025 (Part 44): 1993, RA : 2003, 3 day incubation at 27 C 2.0-45.0 µg/l 2.00-100.00 mg/l Cadmium 0.5-15.00 µg/l Chlorides IS 3025(Part 32):1988, RA : 2007, Argentometric Method 2.0-1500.0 mg/l Colour Platinum Cobalt Method 4.5-500.0 Hazen unit Copper IS 3025 (Part 42) : 1992 Disolved Oxygen IS 3025 (Part 38):1989, RA : 2003, Winkler Azide Method 0.03-10.0 mg/l 0.1-20.0 mg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 5 of 9 Iron IS 3025 (Part 53) : 2003, RA : 2009, 0.06-15.0 mg/l Fluoride Hexavalent Chromium Nitrate Lead SPANDS Method 1,5-Diphenylcarbohydrazide Method UV-Spectrphotometric Method 0.01-0.7 mg/l 0.5-45.0 mg/l 5.0-100.0 µg/l ph value IS 3025 (Part 11):1983, RA : 1996, Electrometric Method 0.2-13.9 Phenolics 4-Amino antipyrine Method 0.002-0.25 mg/l Selenium IS 3025(Part 56):2003, 2.0-35.0µg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 6 of 9 Sulphate Turbidity Method 2.0-70.0 mg/l Total Dissolved Solids IS 3025 (Part 16):1984 RA : 2006, Gravimetric Method Total Suspended Solids IS 3025 (Part 17):1984, RA :1996, Gravimetric Method Zinc IS 3025 ( Part 49 ) : 1994, 2. Drinking Water Alkalinity IS 3025(Part 23):1986, Titration Method Arsenic IS 3025(Part 37):1988 RA : 2003, 25.0-5000.0 mg/l 10.0-5000.0 mg/l 0.01-10 mg/l 4.0-2000.0 mg/l 2.0-45.0 µg/l Boron Carmine Method 0.2-15.0 mg/l Calcium IS 3025 (Part 40): 1991, EDTA Method 1.6-800.0 mg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 7 of 9 Cadmium 0.5-15.0 µg/l, Chlorides IS 3025(Part 32):1988, RA : 2007, Argentometric Method 2.0-1500.0 mg/l Colour Platinum Cobalt Method 4.5-500.0 Hazen unit Copper IS 3025 (Part 42) : 1992 Iron IS 3025 (Part 53) : 2003, RA : 2009, 0.03-10.0 mg/l 0.06-15.0 mg/l Fluoride Hexavalent Chromium SPANDS Method 1,5-Diphenylcarbohydrazide Method 0.01-0.7 mg/l Manganese IS 3025 (Part 59) : 2006, 0.02-5.0 mg/l Nitrate UV-Spectrphotometric Method 0.5-45.0 mg/l

Environment, Central Mine Planning and Design Institute Last Amended on - Page 8 of 9 Odour IS 3025 (Part 5):1983, RA : 2012 Qualitative Lead 5.0-100.0 µg/l ph IS 3025 (Part 11):1983, RA : 1996, Electrometric Method 0.2-13.9 Phenolics 4-Amino antipyrine Method 0.002-0.25 mg/l Selenium IS 3025(Part 56):2003, 2.0-35.0µg/l Sulphate Turbidity Method 2.0-70.0 mg/l Total Dissolved Solids IS 3025 (Part 16):1984 RA : 2006, Gravimetric Method Total Hardness (c a co 3 ) IS 3025 (Part 21):2009, EDTA Method 25.0-5500.0 mg/l 4.0-2000.0 mg/l Total Residual Free chlorine DPD Method

Environment, Central Mine Planning and Design Institute Last Amended on - Page 9 of 9 Turbidity IS 3025 (Part 10):1984, RA : 1996, Nephelometric Method Zinc IS 3025 ( Part 49 ) : 1994, 1.0-100.0 NTU 0.01-10 mg/l III. AIR, GASES & ATMOSPHERE 1. Ambient Air Quality TPM Lab SOP4 based on IS 5182 (Part -23):2006 (PM10 + > PM10 fraction) 5 1000 µg/m 3 RPM IS 5182 (Part -23):2006 3.5 1000 µg/m 3 SO 2 IS 5182 (Part-II) : 1969 West & Gaeke Method NOx IS 5182 (Part VI) : 1975 Jacobs & Hochheiser 10-1050 µg/m 3 06-750 µg/m 3 -X-X-X-X-X-X-X-X-X-X-X-X-X-X-