Surname entre Number andidate Number Other Names 0 GSE 4472/01 ADDITIONAL SIENE/EMISTRY EMISTRY 2 FOUNDATION TIER A.M. TUESDAY, 14 January 2014 1 hour For s use Question Maximum Mark Mark Awarded 1. 6 2. 6 4472 010001 3. 4 ADDITIONAL MATERIALS In addition to this paper you will need a calculator and a ruler. INSTRUTIONS TO ANDIDATES Use black ink or black ball-point pen. Write your name, centre number and candidate number in the spaces at the top of this page. Answer all questions. Write your answers in the spaces provided in this booklet. 4. 6 5. 7 6. 7 7. 8 8. 4 9. 6 10. 6 Total 60 INFORMATION FOR ANDIDATES The number of marks is given in brackets at the end of each question or part-question. You are reminded of the necessity for good English and orderly presentation in your answers. Assessment will take into account the quality of written communication (QW) in your answer to question 10. The Periodic Table is printed on the back cover of the examination paper and the formulae for some common ions on the inside of the back cover. SM*(W14-4472-01)
2 Answer all questions. 1. (a) The following diagrams represent five different atoms, A E. A B D E Use the diagrams to answer the following questions. (i) Give the electronic structure of element D.... [1] (ii) Give the letters, A E, of the elements that are found in Period 3. [1]... and... (iii) Give the letters, A E, of the elements that are found in Group 7. [1]... and... (iv) Give the atomic number of element.... [1] (b) omplete the following table to show the relative masses and charges of the particles found in an atom. [2] Particle Relative mass Relative charge proton 1... neutron... 0 electron 0 1 6
3 2. A Group 1 metal is burned in a gas jar containing oxygen. oxygen metal burning with a lilac flame (a) Use the information in the diagram above to name the Group 1 metal. [1]... (b) Write a word equation for the reaction taking place. [1]... +...... 4472 010003 (c) Give the name of a Group 1 metal that would react less vigorously than the metal named in (a) above. [1]... (d) A similar reaction can be carried out using chlorine instead of oxygen. The product obtained is a white solid. (i) hoose from the box below a solution that could be used to show that the white solid contains chloride ions. [1] limewater silver nitrate sodium hydroxide sulfuric acid Solution... (ii) State what must be done to the white solid in order to carry out the test. [1] (iii) Give the colour of the precipitate formed. [1]... 6 Turn over.
4 3. hromatography can be used to test if racehorses have been given illegal drugs. Urine samples from four horses, A D, were tested to find out whether they contained caffeine or paracetamol. The following diagram shows the results obtained. 10 solvent front 9 8 Distance moved (cm) 7 6 5 4 3 2 1 0 start line caffeine paracetamol horse A horse B horse horse D (a) Give the letter of the horse, A D, that had been given paracetamol. [1]... (b) State, giving a reason, if any of the four horses had been given caffeine. [1] (c) The R f value can be used to identify a substance. Use the following equation to calculate the R f value of paracetamol. [2] distance moved by paracetamol R f value = distance moved by solvent R f value =... 4
5 4. The following graph shows how the solubility of four different substances varies with temperature. Solubility (g per 100g of water) 180 160 140 120 100 80 60 40 20 potassium nitrate sodium nitrate sodium sulfate sodium chloride 0 20 40 60 80 Temperature ( ) 4472 010005 (a) Name the substance that shows the smallest change in solubility. [1]... (b) Give the temperature at which the solubility of potassium nitrate and sodium nitrate is the same.... [1] (c) If a saturated solution of sodium nitrate in 100 g of water is cooled from 80 to 10, calculate the mass of crystals that will be formed. [2] Mass of crystals formed =... g (d) Describe, using data from the graph, how the solubility of sodium sulfate changes with temperature. [2] Turn over. 6
6 5. The following table shows some information about four organic compounds. Name Molecular formula Structural formula Family of hydrocarbons methane butane 4 10 alkane ethene 2 4 3 6 alkene (a) omplete the table. [4] (b) Ethene undergoes polymerisation to form polythene. The following equation shows the reaction taking place. n n Describe what happens during this process. [2]
(c) Another polymer is PTFE. Its repeating unit is shown below. 7 F F F F n Draw the structure of the monomer used to produce PTFE. [1] 4472 010007 7 Turn over.
8 6. When sodium thiosulfate solution reacts with dilute acid, sulfur forms as a precipitate. The precipitate causes the solution to go cloudy. The rate of reaction can be measured by placing a cross beneath the flask and measuring the time taken for the cross to disappear. add dilute acid and start timing sodium thiosulfate solution cross drawn on paper A pupil studied the effect of temperature on the reaction and obtained the following results. Temperature ( ) 20 30 40 50 60 Time taken for cross to disappear (s) 50 32 25 20 17
9 (a) (i) Plot the results on the grid below and draw a suitable line. [3] 60 50 Time taken for cross to disappear (s) 40 30 20 10 0 10 20 30 40 50 60 70 Temperature ( ) (ii) Describe the trend in the results. [1] (iii) A second student carried out the same experiment using a higher concentration of acid. Draw the line you would expect him to obtain on the same grid. [1] Turn over.
(b) 10 Another student suggested using a light sensor and data logger to study the reaction rate. light source light sensor to data logger reaction mixture Describe how the light intensity detected by the sensor would change during the reaction and give one advantage of using a light sensor. [2] 7
11 7. The following table shows information about some atoms, A E. A E are not the chemical symbols for the elements. Atom A B D E atomic number mass number number of protons number of neutrons number of electrons 3 6 10 11 12 14 20 23 3 6 6 10 11 4 6 8 10 3 6 6 10 11 (a) omplete the table. [3] (b) (i) Give the electronic structure of element D.... [1] (ii) Use this information to explain why this element is found in Period 2 and Group 0. [2] (c) hoose the letters, A E, of the atoms that represent isotopes and give a reason for your choice. [2] Letters... and... Reason... 8 Turn over.
12 8. The following diagrams show the structures of diamond, graphite and carbon nanotubes. diamond graphite carbon nanotube (a) Two of the structures shown above conduct electricity. Name both and give the reason why they are able to conduct electricity. [2] Structures... and... Reason... (b) Name the structure above that is used as a lubricant and give a reason why it is suitable for this use. [2] 4
13 9. The reaction of chlorine with iron can be demonstrated using the following apparatus. chlorine gas excess chlorine gas iron wool (a) State why the reaction should be carried out in a fume cupboard. [1] (b) The product of the reaction above is iron(iii) chloride, Fel 3. omplete and balance the following symbol equation for the reaction. [2]... +... Fel 3 (c) alculate the percentage by mass of chlorine in iron(iii) chloride, Fel 3. [3] A r (Fe) = 56 A r (l) = 35.5 Percentage by mass of chlorine =... % 6 Turn over.
14 10. Thermochromic pigments, photochromic pigments and shape memory alloys are types of smart material. Describe your understanding of smart materials. [6 QW] Your answer should include: what is meant by a smart material; some examples of smart materials, their special properties and uses. END OF PAPER 6
15 FORMULAE FOR SOME OMMON IONS POSITIVE IONS NEGATIVE IONS Name Formula Name Formula Aluminium Ammonium Barium alcium opper(ii) ydrogen Iron(II) Iron(III) Lithium Magnesium Nickel Potassium Silver Sodium Zinc Al 3+ + N 4 Ba 2+ a 2+ u 2+ + Fe 2+ Fe 3+ Li + Mg 2+ Ni 2+ K + Ag + Na + Zn 2+ Bromide arbonate hloride Fluoride ydroxide Iodide Nitrate Oxide Sulfate Br 2 O 3 l F O I NO 3 O 2 2 SO 4 Turn over.
16 PERIODI TABLE OF ELEMENTS 1 2 Group 3 4 5 6 7 0 1 1 4 e 2 ydrogen elium 7 Li 3 9 Be 4 11 5 B 12 6 14 N 7 16 O 8 19 F 9 20 Ne 10 Lithium Beryllium Boron arbon Nitrogen Oxygen Fluorine Neon 23 Na 11 24 Mg 12 27 Al 13 28 14 Si 31 P 15 32 16 S 35 17 l 40 18 Ar Sodium Magnesium Aluminium Silicon Phosphorus Sulfur hlorine Argon 39 19 K 40 a 20 45 21 Sc 48 22 Ti 51 23 V 52 24 r 55 25 Mn 56 26 Fe 59 27 o 59 28 Ni 64 29 u 65 30 Zn 70 31 Ga 73 32 Ge 75 33 As 79 34 Se 80 35 Br 84 36 Kr Potassium alcium Scandium Titanium Vanadium hromium Manganese Iron obalt Nickel opper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 86 37 Rb 88 38 Sr 89 39 Y 91 40 Zr 93 41 Nb 96 42 Mo 99 43 Tc 101 44 Ru 103 45 Rh 106 46 Pd 108 47 Ag 112 48 d 115 49 In 119 50 Sn 122 51 Sb 128 Te 52 127 I 53 131 Xe 54 Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver admium Indium Tin Antimony Tellurium Iodine Xenon 133 s 55 137 Ba 56 139 La 57 179 f 72 181 Ta 73 184 W 74 186 Re 75 190 Os 76 192 Ir 77 195 Pt 78 197 79 Au 201 g 80 204 Tl 81 207 Pb 82 209 Bi 83 210 Po 84 210 At 85 222 86 Rn aesium Barium Lanthanum afnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 223 Fr 87 226 Ra 88 227 Ac 89 Francium Radium Actinium Key: Mass number Atomic number A X Element Symbol Z Name