MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name Synonym(s) 800001738 CAS # Product Use Manufacturer Gumout X Diesel/Biodiesel Fuel Injector Cleaner Mixture Fuel Injector Cleaner ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON L7G 0C6 CA Phone: 1-905-693-8900 Emergency Telephone: 1-877-504-935 Hazards Identification Emergency Overview Potential short term health effects Routes of exposure Eyes Skin WARNING COMBUSTIBLE LIQUID AND VAPOUR EYE AND SKIN IRRITANT Eye, Skin contact, Skin absorption, Inhalation, Ingestion May cause irritation May cause irritation May be absorbed through the skin ACGIH - Threshold Limit Values - Skin Notations 91-0-3 Skin - potential significant contribution to overall exposure by the cutaneous route NIOSH - Pocket Guide - Skin Notations 98-8-8 Potential for dermal absorption Inhalation May cause respiratory tract irritation Ingestion Target organs Chronic effects May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Blood Eyes Respiratory system Skin Prolonged or repeated exposure can cause drying, defatting and dermatitis Signs and symptoms Symptoms may include redness, oedema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting Potential environmental effects See section 1 3 Composition/Information on Ingredients CAS # 91-0-3 98-8-8 100-41-4 103-65-1 6474-94-5 108-67-8 95-63-6 6474-96-7 6474-95-6 Percent 01-1 01-1 01-1 05-15 1-5 1-5 3-7 60-100 7-13 #0 Page 1 of 7
First aid procedures Eye contact Skin contact Inhalation Ingestion General advice Flammable properties Extinguishing media Suitable extinguishing media 4 First Aid Measures Flush with cool water Remove contact lenses, if applicable, and continue flushing Obtain medical attention if irritation persists Flush with cool water Wash with soap and water Obtain medical attention if irritation persists If symptoms develop move victim to fresh air If symptoms persist, obtain medical attention Do not induce vomiting If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration Never give anything by mouth if victim is unconscious, or is convulsing Obtain medical attention Keep away from sources of ignition No smoking If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire-fighting Measures Combustible by WHMIS criteria Small Fires: Dry chemical Carbon dioxide Sand Large Fires: Water spray, fog or regular foam Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighers Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Handling Storage Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Prevent entry into waterways, sewers, basements or confined areas Stop leak if you can do so without risk Remove sources of ignition Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills in original containers for re-use 7 Handling and Storage Use good industrial hygiene practices in handling this material Avoid contact with eyes, skin and clothing Keep container tightly closed Use only with adequate ventilation Wash thoroughly after handling Keep out of reach of children Do not store at temperatures above 10 F (49 C) Store in a closed container away from incompatible materials Keep away from heat and flame #0 Page of 7
Exposure limit values 8 Exposure Controls / Personal Protection Exposure limit values TWA: 5 ppm TWA: 5 ppm TWA: 0 ppm STEL: 15 ppm TWA: 50 ppm TWA: 10 ppm STEL: 15 ppm Not established TWA: 100 ppm Not established Engineering controls Personal protective equipment Eye/Face protection Hand protection Skin and body protection Respiratory protection Not established Use only under good ventilation conditions or with respiratory protection Wear safety glasses with side shields Rubber gloves Confirm with a reputable supplier first As required by employer code Where exposure guideline levels may be exceeded, use an approved NIOSH respirator General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Colour Form Odour Odour threshold Physical state ph Freezing point Boiling point Pour point Evaporation Rate Flash point Auto-ignition temperature Clear Light yellow Liquid Mild Kerosene Liquid 773 C (17101 F) Setaflash Closed Tester #0 Page 3 of 7
Flammability limits in air, lower, % by volume Flammability Limits in Air, Upper, % by Volume Vapour pressure Vapour density Specific gravity 08-086 Octanol/water coefficient 10 Stability and Reactivity Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials None known Hazardous polymerisation does not occur Stable under recommended storage conditions Heat, open flames, static discharge, sparks and other ignition sources Do not mix with other chemicals None known Hazardous decomposition products May include and are not limited to: Oxides of carbon 11 Toxicological Information Component analysis - LC50 Component analysis - Oral LD50 LC50 3661 ppm rat 4 mg/m3/4h rat 8000 mg/l/4h rat 590 mg/l/4h rat 5 mg/l/4h rat LD50 380 mg/kg rat 3000 mg/kg rat 3500 mg/kg rat 1400 mg/kg rat 490 mg/kg rat; 533 mg/kg mouse; 100 mg/day guinea pig 500 mg/kg rat 7050 mg/kg rat 4700 mg/kg rat Effects of acute exposure Eye May cause irritation Skin May cause irritation May be absorbed through the skin ACGIH - Threshold Limit Values - Skin Notations 91-0-3 Skin - potential significant contribution to overall exposure by the cutaneous route NIOSH - Pocket Guide - Skin Notations 98-8-8 Potential for dermal absorption Inhalation May cause respiratory tract irritation #0 Page 4 of 7
Ingestion Sensitisation Chronic effects Carcinogenicity May cause stomach distress, nausea or vomiting Aspiration of material into lungs can cause chemical pneumonitis Non-hazardous by WHMIS criteria Non-hazardous by WHMIS criteria Contains potential carcinogens - IARC group B (possibly carcinogenic) ACGIH - Threshold Limit Values - Carcinogens 100-41-4 A3 - Confirmed animal carcinogen with unknown relevance to humans 91-0-3 A4 - Not Classifiable as a Human Carcinogen IARC - Group B (Possibly Carcinogenic to Humans) 100-41-4 Monograph 77 [000] 91-0-3 Monograph 8 [00] Mutagenicity Non-hazardous by WHMIS criteria Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products Non-hazardous by WHMIS criteria Contains a potential teratogen 1 Ecological Information Ecotoxicity Components of this product have been identified as having potential environmental concerns Ecotoxicity - Freshwater Algae - Acute Toxicity Data 100-41-4 7 Hr EC50 Pseudokirchneriella subcapitata: 46 mg/l; 96 Hr EC50 Pseudokirchneriella subcapitata: >438 mg/l; 7 Hr EC50 Pseudokirchneriella subcapitata: 6-113 mg/l [static]; 96 Hr EC50 Pseudokirchneriella subcapitata: 17-76 mg/l [static] 98-8-8 7 Hr EC50 Pseudokirchneriella subcapitata: 6 mg/l 91-0-3 7 Hr EC50 Skeletonema costatum: 04 mg/l Solvent naphtha (petroleum), heavy aromatic 6474-94-5 7 Hr EC50 Skeletonema costatum: 5 mg/l Ecotoxicity - Freshwater Fish - Acute Toxicity Data 95-63-6 96 Hr LC50 Pimephales promelas: 719-88 mg/l [flow-through] 108-67-8 96 Hr LC50 Pimephales promelas: 348 mg/l 100-41-4 96 Hr LC50 Oncorhynchus mykiss: 110-180 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: 4 mg/l [semi-static]; 96 Hr LC50 Pimephales promelas: 755-11 mg/l [flow-through]; 96 Hr LC50 Lepomis macrochirus: 3 mg/l [static]; 96 Hr LC50 Pimephales promelas: 91-156 mg/l [static]; 96 Hr LC50 Poecilia reticulata: 96 mg/l [static] 98-8-8 96 Hr LC50 Pimephales promelas: 604-661 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 48 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 7 mg/l [semi-static]; 96 Hr LC50 Poecilia reticulata: 51 mg/l [semi-static] 91-0-3 96 Hr LC50 Pimephales promelas: 574-644 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 16 mg/l [flow-through]; 96 Hr LC50 Oncorhynchus mykiss: 091-8 mg/l [static]; 96 Hr LC50 Pimephales promelas: 199 mg/l [static]; 96 Hr LC50 Lepomis macrochirus: 31065 mg/l [static] Solvent naphtha (petroleum), heavy aromatic 6474-94-5 96 Hr LC50 Pimephales promelas: 19 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: 34 mg/l; 96 Hr LC50 Lepomis macrochirus: 1740 mg/l [static]; 96 Hr LC50 Pimephales promelas: 45 mg/l [flow-through]; 96 Hr LC50 Pimephales promelas: 41 mg/l Solvent naphtha (petroleum), light aromatic 6474-95-6 96 Hr LC50 Oncorhynchus mykiss: 9 mg/l Ecotoxicity - Water Flea - Acute Toxicity Data 95-63-6 48 Hr EC50 Daphnia magna: 614 mg/l 108-67-8 4 Hr EC50 Daphnia magna: 50 mg/l 100-41-4 48 Hr EC50 Daphnia magna: 18-4 mg/l 98-8-8 48 Hr EC50 Daphnia magna: 06 mg/l; 48 Hr EC50 Daphnia magna: 79-141 mg/l [Static] 91-0-3 48 Hr LC50 Daphnia magna: 16 mg/l; 48 Hr EC50 Daphnia magna: 196 mg/l [Flow through]; 48 Hr EC50 Daphnia magna: 109-34 mg/l [Static] Solvent naphtha (petroleum), 6474-94-5 48 Hr EC50 Daphnia magna: 095 mg/l heavy aromatic Solvent naphtha (petroleum), light aromatic 6474-95-6 48 Hr EC50 Daphnia magna: 614 mg/l Persistence and degradability Bioaccumulation/accumulation Mobility in environmental media Environmental effects Aquatic toxicity #0 Page 5 of 7
Partition coefficient Chemical fate information Other adverse effects Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Review federal, provincial, and local government requirements prior to disposal 14 Transport Information Transportation of Dangerous Goods (TDG - Canada) Not regulated as dangerous goods 15 Regulatory Information Canadian federal regulations This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations Canada - CEPA - High Priority Chemicals as Identified by DSL Categorization 91-0-3 Batch 1, published February 3, 007 Canada - CEPA - Schedule I - List of Toxic Substances 91-0-3 Present Canada - WHMIS - Ingredient Disclosure List 95-63-6 01 % 108-67-8 01 % 100-41-4 01 % 98-8-8 1 % 91-0-3 1 % WHMIS classification Class B - Division 3 - Combustible Liquid, Class D - Division A, B WHMIS status WHMIS labeling Controlled Inventory Status Country(s) or region Canada Canada Inventory Name Domestic Substances List (DSL) Non-Domestic Substances List (NDSL) On Inventory (Yes/No)* Yes No A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information LEGEND HMIS/NFPA Severe Serious Moderate Slight Minimal 4 3 1 0 Health * Flammability Physical Hazard Personal Protection 0 X 0 #0 Page 6 of 7
Disclaimer Effective Date Expiry Date Information contained herein was obtained from sources considered technically accurate and reliable While every effort has been made to ensure full disclosure of product hazards, in some cases data is not available and is so stated Since conditions of actual product use are beyond control of the supplier, it is assumed that users of this material have been fully trained according to the requirements of all applicable legislation and regulatory instruments No warranty, expressed or implied, is made and supplier will not be liable for any losses, injuries or consequential damages which may result from the use of or reliance on any information contained in this document 01-Nov-011 01-Nov-014 Prepared by Dell Tech Laboratories Ltd (519) 858-501 Other Information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z4001/Z191-010 Standard #0 Page 7 of 7