Advanced technology in wear

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Advanced technology in wear is a wear resistant steel offering up to 50% extra in service life compared with a 400 HB water quenched steel. combines several modern metallurgical concepts which, depending on thickness, use different combinations of an enriched chemical analysis (Cr, Mo, Ti ) and controlled quenching rate. Creusabro 4800 (P) is designed to provide the optimun combination of wear resistance controlled hardness and ease of processing. Rather then using just a high hardness level, it achieves this aim by using proven and controlled metallurgical mechanisms, which are more complex but more efficient then the simple effect of hardness alone. - Work-hardening and Cr Mo micro-carbides, the basic CREUSABRO concept, - TRIP (*) effect originally developed with CREUSABRO 8000, - Reinforcement of the structure with Titanium carbides. The limited as delivered hardness of Creusabro 4800 (P) makes processing operations like cutting, machining and forming no more difficult then processing 400HB water quenched steel. Creusabro 4800 (P) is ideal for applications in mines and quarries, cement and the Steelmaking industries, publics works and agricultural machinery. It is suitable for all types of abrasion, sliding or impact, dry or wet media including high temperature abrasion up to 350 C. (1) TRansformation Induced by Plasticity STANDARD CHEMICAL ANALYSIS Guaranteed values (Weight %) C S P Mn Ni Cr Mo Ti 0.20 0,005 0,018 1,60 0,20 1.90 0,40 0,200 MECHANICAL PROPERTIES Typical values (as supplied) Hardness YS UTS E KCVL-20 C Elasticity modulus HB MPa MPa % J/Cm² GPa 370 900 1200 12 45 205 Guaranteed values (as supplied) Hardness : 340/400 HB (P) Trademark Patented grade - Ed 15.04.2003 - Page 1

Mechanical properties at high temperature (Typical values) 1400 Rm and Rp (MPa) El% (5d) 1200 Rm 1000 Rp 0,5 800 600 El% (5d) 400 200 0 Temperature 100 200 300 400 500 600 30 25 20 15 10 5 0 PHYSICAL PROPERTIES Expansion coefficient - average (x 10-6. C -1 ) 20/100 C 20/200 C 20/300 C 20/400 C 20/500 C 20/600 C 12,4 13,1 13,9 14,4 14,7 15,0 METALLURGICAL CONCEPT Abrasion resistance is not exclusively associated with the hardness of the steel in the supplied condition. Its composition and structure strongly influence the actual performance in service. The chemical composition and the manufacturing processes applied to develop a metallurgical structure, which contributes strongly to the improvement of its wear resistance through the following effects. Work hardening in service When entering in service, takes profit of a surface hardening of about 70 HB whatever the applied strain level is (impact, pressure.) HB 430 400 + 70HB with substantial hardening Ordinary 400 HB steel 360 As supplied In service Delay of chip removal Creusabro 4800 (P) has the advantage of a higher capacity for plastic deformation caused by impact s. This extra-ductility induces a delay in the chip removal ensuring a slower wear rate (weight loss) than on 400HB water quenched steels. 1 2 1 400 HB water quenched Hardening effect 2 deformation 3 Delay of chip removal with - Ed 15.04.2003 - Page 2

Titanium carbides In addition to the fine and homogeneous distribution of chromium and molybdenum carbides (respectively 1500 HV and 1800 HV) common to CREUSABRO steels. Creusabro 4800 (P) is a new generation steel in the field of wear resistance steels with a significant addition of Titanium resulting in the formation of a structure with very hard and fines particules of titanium carbide, TiC reaching a hardness level of 3200 Hv. These carbides give to the steel an increased wear resistance.. Wear resistance Summary 400HB water quenched Conventional route Passive material Just connected to supplied hardness PASSIVE STEEL Innovative route Active material Combining In service hardening TRIP Effect Microcarbides + Titanium effect REACTIVE STEEL Process Low alloyed steel (C, Mn, B) Water quenching Specific addition of alloying elements (Cr, Mo, B, Ti ) Controlled cooling rate Structure 100% martensitic structure Structure : bainite/martensite + retained austenite + micro-carbides Transformation of retained austenite into fresh martensite under abrasive effect Fine micro-carbides homogeneously dispersed + Very hard Titanium carbides PROPERTIES AT HIGH TEMPERATURE chemical composition, Chromium and Molybdenium contents principally give a high resistance to softening in hot conditions, much better than that of 400 HB water quenched steel. Hardness HB 500 450 400 350 300 250 400 HB WQ* 200 100 200 300 400 500 600 C Temperature (holding time : 1 h) Heating 500 C + Deformation + Air cooling 340 HB ( ) 290 HB (400 HB Water Quench) These properties enablethe steel to be processed in the hot condition (450/500 C). Forming of thick plates, for example, followed by a slow cooling without inducing any significant drop of hardness. Hot resistance of allows its use in hot environments where pieces are heated up to 350 C - Ed 15.04.2003 - Page 3

SERVICE LIFE metallurgical concept improves its wear resistance compared to other anti-abrasion grades available in the market, and in all service conditions. 250 200 150 100 Average life time in abrasive conditions Reference 50 400HBWQ* CR4800 CR8000 *WQ = Water quench Creusabro 4800 (P) benefits from the optimumcompromise between wear resistance and ease of processing. Average life time 250 200 CREUSABRO 8000 CREUSABRO Optimum combination 150 CREUSABRO 4800 500 WQ (*) 100 400 TE (*) 450 TE (*) Reference 50 Easy (*) WQ = Water quenched Processintg ability Dificult PROCESSING Cutting All classical thermal processes (oxygen-plasma-laser) can be used. Plasma/Laser processes are specially recommended, they provide a better precision and cutting aspects and producde a narrower Heat Affected Zone (HAZ). Whatever process (thermal) is used, following conditions are sufficient to avoid cold cracking : Plate temperature Thickness 60mm (2.4") Thickness >60mm (2.4") 10 C (50 F) No preheating Preheating : 150 C (302 F) < 10 C (50 F) All thicknesses : Preheating 150 C (302 F) Water jet cutting can by used. Machining Drilling can be done with high speed tools, HSSCO type. (ex. AR.2.9.1.8 according to AFNOR, M42 according to AISI) Lubrication with soluble oil diluted to 20%. Tool Ø mm Cutting speed (m/min) Revolution speed (rev/min) Feed (mm/rev) HSSCO AR.2.9.1.8 (M42) 5 10 15 20 25 30 15 20 13 17 12 15 11 14 9 12 8-10 950 1250 415 540 255 320 175 220 115 150 85-105 0.07 0.09 0.10 0.12 0.15 0.20 Indicative parameters - Ed 15.04.2003 - Page 4

Milling shall be done with HSSCO tools (AR.6.5.2.5. accordind to AFNOR, M35 acording to AISI or AFNOR AR.12.0.5.5 / AISI T15). Lubrication with soluble oil. Tools HSSCO AR 12.0.5.5 (T15) Depth (mm) 1 4 8 Cutting speed (m/min) 12-15 10-12 7-9 Feed (mm/tooth) 0.08 0.10 0.15 Forming Cold forming of can be done without any problem when the following conditions are met : - No marks or scratches in shaped zones, mainly on external face ; - Bevelling by grinding of edge angle specially on extended skin Eventually grinding to remove cutting heterogeneities ; - Minimum internal bending radius (table below) ; - Plate temperature > 10 C (50 F) Bending Internal bending radius (min.) Direction // Direction Die opening V (mini) r i 3th r i 4th V 12th The strength necessary to bend depends on UTS and plate thickness as well as bended length and die opening V. Indicative values, for die opening V = 12th (V bending) th plates (mm) Bending strength L = 1 m ton/m 5 70 10 130 20 250 Spring back : allow for a tight bending angle to compensate spring back effect. Example : for r i / th = 5, anticipate an angular correction of about 10. Safety : Due to high elastic energy of the steel it is advice not to stand in front of the machine, but at the side. Rolling has to be done using the following conditions Ø i 30 th (plate temperature > 10 C) The force necessary to roll a plate will be about double that of a S355 type steel. - Ed 15.04.2003 - Page 5

can be hot formed at a temperature of 450/500 C without any further heat treatment. At this temperature the force necessary to deform the plate will be lower than at room temperature, and the deformation capability of the steel will be higher (smaller forming radius). It is possible to deform a plate thicknesses th 20mm within temperature range 870/1000 C followed by air cooling without affecting steel properties. This process is particularly interesting to reduce bending / rolling forces and to increase the deformation capability of the steel. Welding can be welded by all traditional welding processes : manual, semi-automatic under gas, automatic under fluxes. For welds non exposed to wear, the following welding rods can be used. Processes AFNOR DIN AWS Manual Stick electrode Semi-automatic Under gas A81-309 E51 4/3 B A81311 GS2 A81350 TGS 51BH TGS 47BH DIN 1913 Class E51 43 B10 DIN 8559 SG2 DIN 8559 SGB1 CY 4255 AWS 5-1 Class E7016 or 7018 AWS A-5-18 Class ER70S4 ou ER 70S6 AWS-5-20 Class ER 71T5 For welds exposed to wear, please ask for advice on the choice of welding products and processes and parameters. Welded area must be free of grease, water, oxides Electrodes and flux shall be stoved according to supplier recommendations. Following preheating conditions shall be met (weld without excessive stresses ). Welding process Heat input Pre and post-heating conditions Combined thickness (mm) (kj/cm) 30 40 50 60 70 80 90 15 1 Semi-automatic under gas 30 2 Manual welding 10 Stick electrode 20 20 3 Automatic under solid flux 30 Without preheating Pre-post heating at 75 C Pre-post heating at 125 C - Ed 15.04.2003 - Page 6

Combined thickness calculation t'2 t'3 t1 t2 Comb. t = t1+t2 t'1 Comb. t = 2xt'1+t'2+t'3 APPLICATIONS Quarries Public works Blades, bucket liners, chutes, liner platesers, crusher lateral stiffeners, screens, dumper bodies and trommels, Mines Extraction equipment, conveyor bottom plates, hoppers, helical gravity and screw conveyors, skips, ventilators, discharge plates, Cement plants Wheel excavators buckets, crusher lateral shield, clinker chutes, buckets, ventilators, dust separators, bagging machines Steel plants Guiding plates, hoppers, chutes, discharge plates, scrap containers / charging boxes, DIMENSIONAL PROGRAM Thicknesses 3mm to 150 mm Standard sizes Flatness 1 500 x 3 000 mm 2 000 x 6 000 mm 2 500 x 8 000 mm 5mm/m Indicative dimensional program Other dimensions available on request. - Ed 15.04.2003 - Page 7

NOTA : 1. This technical data and information represents our best knowledge at the time of printing. However, it may be subject to some slight variations due to our ongoing research programme on abrasion resistant grades. We therefore suggest that information be verified at time of enquiry or order. Furthermore, in service, real conditions are specific for each application. The data presented here is only for the purpose of description, and may only be considered as guarantees when our company has given written formal approval. Further information may be obtained from the following address. 2. : Application range. has been developed specifically for its abrasion resistance. Customer's usage of CREUSABRO 4800 for any other purposes, not directly resulting from its abrasion resistance, is his own prerogative but won't, in any way, engage INDUSTEEL's responsability. In addition to the recommendations given in this document, Customer will have to follow the Industry standard quality rules for any processing operation performed on this material. For all information : INDUSTEEL 56 Rue Clemenceau 71202 LE CREUSOT CEDEX - FRANCE Tel +33 3 85 80 58 04 Sales Fax +33 3 85 80 55 00 Mkt & Develop t Tel Fax +33 3 85 80 55 37 +33 3 85 80 55 99 - Ed 15.04.2003 - Page 8