Developments in Anaerobic treatment of F&B wastewaters

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Developments in Anaerobic treatment of F&B wastewaters More biogas at lower investment and operating costs 3 rd European Food Manufacturing & Safety Summit 2013 Noordwijk; February 11/12 Jan Pereboom

Veolia Environnement Veolia Environnement offer a complete range of creative solutions for the environment. About us Supplying water and recycling wastewater; collecting, treating and recovering waste; supplying heat and cooled air; and optimizing industrial processes. These solutions are designed to find a balance between the development of human activities and environmental protection. 2

Veolia Environnement The reference in environmental solutions About us VEOLIA ENVIRONNEMENT 29.6 billion revenue More than 330 000 employees in 77 countries WATER The global benchmark for water services WASTE MANAGEMENT The global benchmark for waste management & resource recovery ENERGY SERVICES The global benchmark for energy optimization TRANSPORTATION Setting the standard for managing safe and sustainable mobility services 3

Veolia Water Veolia Water resolve the complexities of guaranteeing water services by: About us Managing water and wastewater services for public authorities and industry. Designing solutions and building the infrastructures. Construction, rehabilitation and maintenance of networks. 4

9% revenue Americas France 36% revenue 8% revenue 32% revenue Africa- Middle East Veolia Water Europe (excl. France) Asia - Pacific 15% revenue About us 12.6 billion revenue 96 650 employees in 69countries 5

Veolia Water Solutions & Technologies Veolia Water Solutions & Technologies provide the complete range of services required to design, build, maintain and upgrade water and wastewater treatment facilities and systems for public authorities and industrial clients. About us 6

Veolia Water Solutions & Technologies Our all-encompassing range of solutions and technologies is dedicated to leverage the value of water and wastewater resources. About us Combined with local presence and a worldwide network of experts, we ensure our customers the best possible solutions to treat or reuse wastewater, produce or recovery energy, extract raw materials and capitalize on byproducts. 7

Veolia Water Solutions & Technologies 2.3 billion revenue 10,767 in figures employees 8

Revenue breakdown 3876 Key figures North America 12% revenue 969 France 21% revenue 2153 29% revenue Europe (excl. France) South America 11% revenue 1400 16% revenue 1292 Africa- Middle East 11% revenue 1077 Asia-Pacific 10,767 2.3 billion 9

HPD; VWS subsidiary Evaporators, Dryers, Crystallizers; 675 plants supplied HESC High Efficiency Stillage Concentration System 10 10

Berkefeld; VWS subsidiary Process and boiler water make-up RO, UF membrane systems 11 11

Veolia s complete service possibilities Bio energy plant Wastewater treatment and water recycling Cooling water and Boiler Sludge handling Boiler water make-up Process water make-up 12

Industrial wastewater treatment The current State-of-the-Art: combination of Anaerobic pre-treatment and Aerobic post treatment Biogas Hydraulic buffer tank Anaerobic reactor Aeration tank Surplus sludge 13

Anaerobic versus Aerobic WWT Heat loss CH 4 26-30 Nm 3 CO 2 5-12 Nm 3 100 kg BOD COD Air (O 2 ) to Aerobic 45% Carbon Dioxide 50% Biomass 2-10 kg COD BOD 100 kg COD (25 O C 35 O C) to Anaerobic 75% Biogas (75% Methane) 5% Biomass Aeration (100 kwh) 10-20 kg COD Sludge, 30-60 kg Sludge, 5 kg 1 kg COD removed 0.35 Nm 3 CH 4 or 3.8 kwh 14 14

Biothane Worldwide Specialist in anaerobic wastewater treatment 35 years of experience 530 references Part of Veolia since 2008 3 offices worldwide BC, BSI, BAP Biothane Corporation Camden NJ USA Biothane Systems International Delft, The Netherlands Biothane Asia Pacific (VWS SEA) Singapore 15

Biothane s Granular Technologies Biobed Advanced UASB or EGSB Granular Sludge Bed Up to 30 kg COD/m3/d Biobed Modular Plant Compact off-site construction 50 ~ 200 m3 reactor volume 0.5 ~ 4.0 tcod/day 16 16

Biothane technologies; non-granular Biobulk CSTR Solid waste digestion With or without sludge recirculation Suitable for high COD / SS / FOG waste(water) Memthane Anaerobic MBR Upthane Municipal UASB technology for tropical climates Novel design New technology for high strength wastewater Using Cross-flow UF membranes High COD / SS removal efficiencies Pomethane CSTR Palm Oil Mill Effluent 17 17

Biothane expertise by industry sector Other, 2% Pulp & Paper, 8% Pharmaceutical, 1% Food, 39% Beverage, 6% Breweries, 23% Fermentation, 13% Chemical, 8% 18

Selection of Anaerobic References in F&B

1. Biobed Advanced Anaerobic granular technology at the next level Reduced investment and operating costs

Based on fundamental research 5 years research by committed team Many with more than 25 years of experience Lab scale testing Hydraulic model testing at 1:1 scale Pilot scale testing at 7 m3 Full scale testing and data gathering 21

Novel Biobed Advanced Settler Patented new settler and reactor design Multi level biogas separation TTS; Tilted Tube Separator on top of the settler Increasing the settler surface area for Improving the retention of biomass and SS in the reactor Robust effluent pipes which replace conventional effluent gutters 22

Objectives of Biobed Advanced Improving the anaerobic performance Thus reducing investment and operating costs hydraulic buffer tank Anaerobic reactor 80 % Aeration tank Improving COD removal rate Hydraulic buffer tank Anaerobic reactor 85 % Aeration tank 10 ~ 25% smaller 23

Biobed Advanced in F & B applications Distillery; Mexico Breweries; South Korea and USA Dairy; Panama Soya processing; Italy Soft drinks; Thailand Sugar; Egypt Potato; Indonesia, Belgium 38 tcod/d 30 and 19 tcod/d 6.0 tcod/d 9.3 tcod/d 8.1 tcod/d 32 tcod/d 3.0 and 7.2 tcod/d 24

Dual Anaerobic; preferred approach for potato Sedimentation Sludges + peels treated in suspended Biobulk digester Wastewaters to Biobed Advanced Aerobic post-treatment Biobulk digester 25

2. Biobed SMART Sludge Management and Reactor control Techniques

Biobed SMART reactor control system (1) Sludge Management and Reactor Control Techniques Objectives : Achieve more stable reactor operation Achieve higher COD removal efficiency Reduce operating costs Dynamic reactor control Measuring online load load control Various online measurements Biogas composition Sludge bed level In-situ sludge activity Result in early warnings 27 27

Objectives of Biobed Advanced & SMART Improving the anaerobic performance Thus reducing investment and operating costs hydraulic buffer tank Anaerobic reactor 80 % Aeration tank Improving COD removal rate Hydraulic buffer tank Dynamic control Anaerobic reactor 85 % Aeration tank 10 ~ 25% smaller 28

kg COD/d kg COD/d % kg/year m3 NG/year Dynamic Control: Client Case-study COD load COD out COD removal Caustic need Energy need 2000 700 100 70000 140000 1500 1000 500 600 500 400 300 200 100 80 60 40 20 60000 50000 40000 30000 20000 10000 120000 100000 80000 60000 40000 20000 0 before after 0 before after 0 before after 0 before after 0 before after + 11% -40% +32% -56% -43% Net Biomass growth Reduction in N-consumption despite of increased average load Stable operation reduced operator and analysis cost 29

Biobed SMART in situ real-time video imaging 30

3. Memthane The preferred solution for high-strength wastewaters resulting in crystal clear effluents

Memthane step-by-ste Conditioning of highstrength wastewaters. Influent is fed to the anaerobic bioreactor where the organic components are converted into energy-rich biogas. Cleaning In Place (CIP) After anaerobic treatment, the UF membrane unit separates the clean permeate from the biomass. If required, several polishing techniques are available to further treat the suspended solids free effluent for reuse or recovery of nutrients, while the low COD permeate is often clean enough for direct discharge to sewer. Biomass is returned to the bioreactor, while a small amount of biomass is removed from the system and discharged after dewatering. 32

Memthane ; Features Treat high-strength effluent previously considered untreatable High concentrated streams : COD 15,000 250,000 ppm Superb effluent quality Create product for nutrient recovery (N+P) Maximize renewable green energy production Generates biogas from wastewater Minimizes carbon footprint and water footprint Remove COD efficiency: > 98% Avoids costly aerobic post treatment Generates more biogas Reduced OPEX Reduces disposal costs while generating biogas 33

Impact of membranes on anaerobic process 34

Case study 1; ARLA Aylesbury, UK Contract signed 2012 Memthane for treatment middle-high strength wastewater from milk processing dairy ELGA RO for direct treatment of low strength wastewater Scope: Turn Key Supply Value: approx. GBP 2,5 M Start Up: Medio 2013

Case study 2; Carriage House Inc.; USA Bottling of foods jams, jellies, salsa, BBQ sauce, etc Influent Parameters: Flow : 500 m3/d Total COD : 20,000 mg/l Total SS : 2,000 mg/l Sewer requirements 250/250 BOD & TSS Strong fluctuations Design and Build contract Operations 10 year by VWNA 36

Case study 3; Dutch food company Pilot plant: May September 2012 Competition: DAF + conventional anaerobic Memthane (> 99% COD) Turn Key 2.5 mln Veolia Operations 3 year Decision early 2013 37

GHG emissions (Ton CO 2 eq/y) Case study 3; Dutch food company Sustainable Positive Carbon Foot Print Future Option Water Re-Use Nutrient Recovery Process Security 100% Biomass Retention 0% Solids in Effluent Max. COD conversion Simplest Process Outline and Operation Lowest Opex 200,000 Minimal PE discharge Maximal Biogas Production 0 to absolute minimal Sludge Production GHG emissions for the two options 1500 1000 500 0-500 -1000-1500 400,000 300,000 100,000 - - 100,000-200,000-300,000 AnMBR Comparison Operational Expenses Memthane versus Granular Sludge Technology UASB Emissions Avoided emissions Net emissions Memthane UASB Chemicals DAF Membranes Energy An. Sludge Pr sludge Biogas VE 38

Memthane ; Track record Proven Innovation 10 full-scale Memthane plants 4 years of full-scale industrial operation 14 pilot plant tests Implemented in: Dairy industries Bio-ethanol plant; thin stillage Cellulosic Bio-ethanol; condensate Biodiesel plant Food processing 39

Observations and Conclusions Biobed Advanced reactor Reduced investment and operating costs Biobed SMART control system Substantial reduction in operating costs More stable operation Especially as retrofit to existing plants Memthane AnMBR Cost effective solution for concentrated wastewaters Crystal clear effluents 40

Biothane: Establishing growth through innovation Thanks for your attention For further information or questions Please contact: Jan Pereboom; Marketing Manager at Biothane jan.pereboom@veoliawater.com 41