China s Coal Conversion Technologies Ren Xiangkun Energy Group of National High Tech R&D Program(863) Beijing Sanju Environmental Protection & New Materials Co.,Ltd China University of Mining and Technology April 17, 2013
Background Coal conversion and relevant policies Coal conversion and technology development Cooperation and outlook
1. Background
Coal Energy Status Is Unique! Coal is main energy source Uneven resource distribution Coal industry satisfies China s rapid development Coal also brings environmental concerns Increasing oil consumption Challenges for oil transportation security Increasing natural gas consumption A new comer for renewable energy development
Clean Coal Industry and Its Technological Development Clean coal Clean conversion of coal Coal-fired power generation Industrial coal and energy conservation CCS CCS Pollution control IGCC polygeneration Gas turbine 5
Clean Conversion of Coal Industry DCL 直接液化 Fe/Slurry Bed 铁基浆态床 CTL 煤制油 F-T 间接液化 Fe/Fluid Bed 铁基浆态床 Cleaning Coal Conversion 清洁煤转化 SNG 煤制天然气 MTG 甲醇制汽油 Co/Fixed Bed 钴基固定床 C1 Chemicals 甲醇羰基化 CTC 煤制化学品 NH 3 合成氨 Methanol 甲醇 MTO/MTP 甲醇制烯烃 MTG 甲醇制汽油 Others 其它 MTD 甲醇制其它燃料
Clean Coal Conversion Technology Calcium carbide 焦炭 Coke 电石乙炔 Ethyne Gasoline 煤焦化 and diesel 煤焦油 Coal tar Crude benzol refining 粗苯精制 BDO Coke oven gas 焦炉气 制氢 Hydrogen production Dimethyl 二甲醚 ether 煤化工产业链 Coal chemical industry line 煤气化 Coal gasification Synthesis 合成气 gas 甲醇 Methanol 烯烃 Olefin 醋酸 Acetic acid 车用燃料 Vehicle fuel Synthesis 合成氨 ammonia Nitrogen 氮肥 fertilizer Direct liquefaction 直接液化 烯烃 Olefin Gasoline and diesel 汽柴油 间接液化 Indirect liquefaction All kinds of oils 各类油品 烯烃 olefin 醇 醛 酮 酸 Alcohol,alde hyde,ketone, acid Traditional 传统煤化工 coal chemical 现代煤化工 Modern coal chemical
2. Coal Conversion and Relevant Policies
Policies Released Time Description Content 2004.6.30 Long-term development strategy of energy CTC is the emphasis 2005.6.7 Healthy coal industry development Proactive and sustainable development 2006.7 Emphasizing healthy development of CTC project Priority and demonstration 2006 Long-term development strategy of CTC Scale limitation 2007.1 11th 5-year plan for coal industry Demonstration 2007.1.13 Policies from Ministry of Finance Taxation and incentives 2007.4 11th 5-year plan for energy Oil substitution 2007.11.2 Coal industry development policies Moderating CTC development 2008.8.4 CTL project management Project limitation 2009.5.18 Adjustment policies on petrochemical Demonstration 2009.9.30 Restriction on some industry capacity Demonstration
Policies Related to Coal Chemical Industry in Recent Years in China June 2010,Circular of NDRC on Regulating the Development of Coal to Natural Gas Industry March 2011,Circular on Regulating the Orderly Development of Coal Chemical Industry issued by NDRC April 2012,MIIT started to release admittance conditions for Coal Chemical Industry May 2012,BOE started discussions on industrial policies on deep coal processing August 2012,started demonstration on new round large scaled coal conversion projects March 2013,front end work was started for several projects
No. Discussion on Policies for Coal Chemical Deep Processing Industry Energy efficiency and resource consumption index of coal chemical deep processing demonstration projects in the 12 th five-year plan Coal consumption(tons of Energy efficiency Fresh water consumption standard coal ) Project Basic Advanced Basic Advanced Basic Advanced 1 Indirect liquefaction 42% 47% 3.6t/t oils 3.4t/t oils 2.75t/t standard coal 2t/t standard coal 2 Coal to natural gas 56% 60% 2.3t/1000M3 natural gas 2.0t/1000M3 natural gas 3.0t/t standard coal 2.5t/t standard coal 3 Coal to olefin 40% 44% 4.4t/t olefin 4.0t/t olefin 3.0t/t standard coal 2.5t/t standard coal 4 Coal to synthesis ammonia 48% 52% 1.5t/t ammonia 1.4t/t ammonia 4t/t standard coal 3.0t/t standard coal 5 Low-rank coal upgrading 75% 85% 0.15t/t feed coal 0.13t/t feed coal
Strategy Study for Sustainable Development, CAE Weight Distribution Reserve 3 SO 2 capacity 0.4 RPR 1 Dust capacity 0.3 Selfsufficiency 2 Soot capacity 0.3 Water extra 2 Regional 1 quantity economic level Region Point Inner 1.47 Mongolia Xinjiang 1.26 Shaanxi 1.20 Shanxi 1.18 Yunnan 1.14 Guizhou 0.97 Heilongjia 0.70 ng Gansu 0.57 Anhui 0.57 Ningxia 0.48 Henan 0.46
Relevant R&D Policies China s long-term R&D plan - coal gasification, liquefaction and polygen 11th 5-year R&D plan
3. Coal Conversion and Technology Development
Coal Chemical Industry Cover. Rate CTL CTC CTG Direct Indirect MTG Methanol Ammonia Olefin China 20% 1 set 1.08 MMT/A 3 sets 0.5 MMT/A 3 sets 0.4 MMT/A 1 in service and 4 under construct ion 17.1 BMT/A 230 sets 46.12MMT /A 425 sets 46.12MMT/ A 4 sets 1.78M MT/A US Lower South Africa Higher Others 3 sets 7.60 MMT/A 1 set 0.50 MMT/A 1 set 1.6 BMT/A 1 set 0.85 MMT/A 1 set 0.25 MMT/A 1 set 0.30 MMT/A
3.1 Coal to liquid - DCL
DCL Shenhua s 1 MMT demonstration plant was put into operation in the end of 2008 It gained good profit in 2012 R&D on process, catalyst and Rx. World largest PDU
3.2 Coal to Liquid ICL(F-T)
ICL (F-T) R&D on process, RX, separation and oil upgrading Built several PP: -CAS (Shanxi): 1,000 ton, Fe catalyst, slurry bed -Shandong Yankuang: 10,000 ton, Fe catalyst, slurry bed & fluid bed -Shanxi Lu an: 1,000 ton, Co catalyst, fixed bed -Shaaxi Baoji: 10,000 ton, Co catalyst, fixed bed -Sinopec (Zhenhai): 1,000 ton, Co catalyst, slurry bed -Shenhua (Shanghai): 100 ton, Fe catalyst, slurry bed
ICL(F-T) 3 Demonstration plants (Fe/slurry bed) -Yitai: 160,000 T/A, started in 2009 -Lu an: 160,000 T/A, started in 2009 -Shenhua: 180,000 T/A, started in 2009 Commercial plants -2007 FSR for Ningxia 3MMT/A CTL (Co/Fix bed/shell) -2011, Ningmei 3.8 MMT/A, started construction (Fe/slurry bed) - 2013, Yankuang 1 MMT/A CTL, under construction (Fe/slurry bed) -2012,Shanxi 1 MMT/A CTL, commenced
3.3 CTL Methanol to Gasoline
MTG 2013: Shanxi MTG put into operation (100,000t/a) Yunnan MTG in service (200,000t/a) Neimeng MTG in service (100,000t/a) R&D on new fixed bed, fluid bed and catalyst
3.3 Synthesis Natural Gas
SNG 2009-2013: 4 projects have got permission, 2 in precommissioning and operation, 1 to be completed Several projects are under planning (Inner Mongolia, Shanxi, Xinjiang, etc.) R&D on low quality coal gasification, catalytic gasification, methanation, catalyst and water treatment
3.4 Coal to Olefin
MTO/MTP 3 demonstration projects: -Shenhua Baotou: MTO,1.80 MMT/A methanol,0.60 MMT/A PE&PP, in operation; -Datang Duolun: MTP, 1.80 MMT/A methanol,0.54 MMT/A in service in 2009; - Shenhua Ningxia: MTP,1.76 MMT/A methanol,0.50 MMT/A PP, in service in 2010; 3 PP plants: -Shaanxi/DICP: 0.15 MMT/A -Huaihua/Tsinghua: 0.30 MMT/A - Sinopec Yanshan:.0.30 MMT/A R&D on new process, catalyst,
3.4 Coal to Chemicals
CTC 2013 -NH3: 49.95 MMT/A, 900 plants -Methanol: 26.22 MMT/A, 221 plants -DME: 6.2 MMT/A, 57 plants R&D on new catalyst, process and equipment.
4. Cooperation and Outlook
US-China Cooperation Agreement signed on NOV-18-2009 US-China Clean Energy Cooperation Agreement MOU for Energy Cooperation Projects" - Large-scaled CCS demonstration project is one of which
Cooperation and Outlook Similar energy mix between US and China, with coal as major source and high external dependence. We are both liable for contributions to energy resource, economy and environment construction. Coal conversion is technology intensive, capital intensive and labor intensive, and involves in multiple technical areas and industries. Orderly sci-tech and industrial development of coal chemical industry is the common issue all over the world. US and China have important cooperative topics on coal conversion to be discussed. Coal conversion a complex technology Cooperation prospects between US and China
Cooperation and Outlook Sino-US Fossil Energy Cooperation Protocol has established good foundation for cooperation in areas such as power generation from clean coal, coal-to-oil, energy resource environment and economy, and CCS. US and China established firm foundation for cooperation in clean coal conversion We own the one world and should cope with climate changes. China has already used technology and experience for reference. Cooperation between the two countries should go deep. Only one world; we share the same mission
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