CETCO-VOLCLAY CG-50 SPECIFICATION GUIDELINES MIX IN PLACE

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CETCO-VOLCLAY CG-50 SPECIFICATION GUIDELINES MIX IN PLACE 1.0 GENERAL 1.1 Scope A. This specification guideline covers the technical requirements for furnishing all labor, materials, equipment, and incidentals required for the installation of the soil/bentonite liner (SBL) described herein. Associated work includes grading, subgrade preparation, and SBL construction. All materials used shall meet the requirements of this specification, and all work shall be performed in accordance with the procedures provided herein and the contract drawings. B. This specification guideline applies to the mix in place method of SBL construction, where the bentonite is mixed with soil that lies within the area to be lined (in-place soil). This specification guideline does not apply if soil/bentonite mixing and subsequent placement of the mixture are performed in separate steps (i.e., via batch or continuous mixing methods). C. The required bentonite application rate of has already been established and is not a part of this specification. D. The moisture/density relationship of the soil-bentonite mixture has been developed by the Engineer, and an acceptable zone has been established using these properties. This specification guideline covers the procedures to be used by the Contractor to construct an SBL whose moisture content and density fall within this acceptable zone. E. Construction Quality Assurance (CQA) procedures for the SBL are not included in this specification. This document is intended for use as a GENERAL GUIDELINE for developing a specification for a specific project. It is NOT intended as a substitute for a detailed specification, which must be written to address site-specific conditions. 1.2 Definitions Page 1 of 7

For the purposes of this specification guideline, the following terms are defined below: Bentonite. A naturally occurring clay composed principally of the mineral sodium montmorillonite. Bentonite Application Rate. The weight of dry (as-received) bentonite that is required to be uniformly mixed with a given unit area of in-place soil so as to provide a finished SBL with the required permeability. Soil/Bentonite Liner (SBL). A field-constructed hydraulic barrier consisting of sodium bentonite clay admixed with a specified soil at a specified application rate, moisture content, and compaction level. 1.3 References ACC 1009 ACC 1010 API 13A/13B ASTM D 422 ASTM D 698 ASTM D 2922 ASTM D 3017 ASTM D 4643 ASTM D 5084 Bentonite Moisture Content Determination Bentonite Free Swell Determination Specification for Drilling Fluid Materials Standard Test Method for Particle Size Analysis of Soils Test Method for Laboratory Compaction Characteristics of Soil Using Standard Effort Standard Test Methods for Density of Soil and Soil-Aggregate in Place by Nuclear Methods (Shallow Depth) Standard Test Method for Water Content of Soil and Rock in Place by Nuclear Methods (Shallow Depth) Determination of Water (Moisture) Content of Soil by the Microwave Oven Method "Hydraulic Conductivity of Saturated Porous Material Using a Flexible Wall Permeameter" 1.4 Unit Prices Measurement and payment will be made on the total weight of bentonite required for completion of the project, calculated as the specified application rate factored over the total area to be lined. Payment will be based on the calculated bentonite requirement, not the actual bentonite used. No allowance will be made for waste or materials used for the convenience of the Contractor. Bentonite installed and accepted as part of the SBL will be paid for at the respective contract unit price (per ton, delivered to the job site) in the bidding schedule. 1.5 Submittals Page 2 of 7

A. With the bid, the Contractor shall furnish the following information: 1. Identification of the proposed bentonite supplier. 2. List of physical/chemical properties of bentonite. 3. Documentation of the bentonite supplier and Contractor qualifications as listed in Section 1.6. B. At the Engineer's or Owner s request, the Contractor shall submit a representative 10 lb (5 kg) sample of the bentonite intended for use. C. Upon shipment of the bentonite, the Contractor shall furnish bentonite Manufacturing Quality Control (MQC) certifications to verify that the materials supplied for the project are in accordance with the requirements of this specification. D. As the installation proceeds, the Contractor shall submit certificates of subgrade acceptance, signed by the Contractor and CQA Inspector (see Section 1.7) for each area to be lined. 1.6 Qualifications A. Bentonite Manufacturer must have supplied at least 100,000 tons of same-quality sodium bentonite for similar applications. B. The SBL Installer must have prior experience in at least 5 projects involving the construction of liners using bentonite as an admixture to native soils. 1.7 Construction Quality Control (CQC) and Assurance (CQA) A. The Contractor shall provide a third-party inspector for CQC/CQA of the SBL installation. The inspector shall be an individual or company who is independent from the Contractor, and who shall be responsible for monitoring and documenting all activities related to the construction of the SBL. A. The B. inspector shall have provided similar services for at least 5 completed SBL projects. Testing of the SBL, as necessary to support the CQC/CQA effort, shall be performed by a third party laboratory retained by the Contractor. The laboratory shall have provided similar QA testing for at least 5 completed projects. C. CQA shall be provided in accordance with the liner CQA Plan provided by the Engineer. 2.0 MATERIALS Page 3 of 7

2.1 Material Properties A. The bentonite to be mixed with site soils shall be natural, granular Wyoming-type sodium bentonite meeting the properties listed in Table 1. The bentonite shall be Volclay CG-50 supplied by CETCO, or an engineer-approved alternative. Table 1. Required properties for sodium bentonite. Property Test Method Required Value Test Frequency Free Swell ACC 1010 24 ml/2g min. 50 tons (45 tonnes) Filtrate Loss API 13A/13B 18 ml max. 50 tons (45 tonnes) Moisture Content ACC 1009 12 % max. 50 tons (45 tonnes) Particle Sizing ASTM D422 5 % max. + #10 15 % max. - #200 50 tons (45 tonnes) B. Prior to using an alternate bentonite, the Contractor must furnish independent test results demonstrating that the proposed alternate material meets all requirements of this specification. The Contractor also must obtain prior approval of the alternative bentonite by the Project Engineer. 2.2 Product Quality Documentation The bentonite manufacturer shall provide the Engineer or other designated party with MQC certifications for each shipment of bentonite. The certifications shall be signed by a responsible party employed by the Manufacturer and shall consist of certificates of analysis for the bentonite clay in accordance with the parameters, methods, frequencies, and required values shown in Table 1. 3.0 EXECUTION 3.1 Bentonite Shipping and Handling The bentonite manufacturer assumes responsibility for initial loading of the bentonite. Shipping will be the responsibility of the party paying the freight. Unloading, on-site handling, and storage of the bentonite are the responsibility of the Contractor or other designated party. 3.2 Bentonite Storage Page 4 of 7

A. Storage of the bentonite shall be the responsibility of the SBL installer. A dedicated storage area shall be selected at the job site that is away from high traffic areas and is level, dry and well-drained. B. Bags of bentonite should be stored on their original pallets. Pallets of bentonite should be stored at a height no higher than that at which the lifting apparatus can be safely handled (typically no higher than two). C. All stored bentonite must be covered with a plastic sheet or tarpaulin until use. D. The integrity and legibility of the labels and markings on the bags/sacks shall be preserved during storage. 3.3 Subgrade Preparation A. The surface upon which the SBL is installed shall be graded, prepared and compacted in accordance with the project specifications and drawings. B. At a minimum, the subgrade surface should be prepared by removing all vegetation, rocks, and other matter which could penetrate the SBL or decrease the uniformity of the mixture. The largest allowable rock shall have no dimension greater than one-third the finished thickness of the SBL. C. The subgrade shall be scarified to the maximum extent practicable to break up large clods, expose oversized rocks, and to allow easier bentonite mixing and moisture adjustment. Scarification should be performed to the same depth as the finished thickness of the SBL, using the same equipment intended for mixing the soil/bentonite as described in Section 3.4. D. At completion of scarification, the largest allowable clod shall have no dimension greater than one-third the finished thickness of the SBL. A minimum of four cross-directional scarification passes are required. 3.4 SBL Construction A. Before applying the bentonite, soil moisture should be adjusted to 2-3% above optimum moisture as defined by ASTM-D 698 or as necessary to fall within the acceptable zone defined and specified by the Engineer. The daily work area shall extend no greater than necessary to maintain acceptably moist soil conditions and continuous operations. B. The bentonite application rate has been determined by the Engineer and the bentonite manufacturer. The bentonite shall be applied uniformly at this rate to provide the SBL with a maximum coefficient of permeability of 1 x 10-7 cm/sec after mixing and compaction is completed. Page 5 of 7

C. The bentonite shall be spread uniformly across the accepted subgrade surface at the specified application rate, using a customized agricultural seed or lime spreader or other equipment as approved by the engineer. D. The bentonite may alternately be applied at the designated application rate by distributing individual bags containing a known weight of the bentonite within a marked grid pattern. Each square of the grid should have the dimensions necessary to result in the required areal application rate when the bags are opened and the bentonite is spread uniformly within the grid squares. E. Tarpaulins or drop cloths of known area shall be laid in random locations at the rate of at least one per 10,000 square feet (1,000 m 2 ) and weighed after spreading bentonite to verify the proper application rate. F. The bentonite shall be thoroughly mixed to a depth of. An adjustable high-speed rotary tiller, asphalt road reclaimer, or similar mixing equipment is strongly recommended. A disc harrow is not allowed due to its poor mixing capabilities. The maximum compacted lift thickness is 6 inches (150 mm). G. Multiple cross-directional passes with the mixing equipment shall be performed until the soil/bentonite mixture is homogeneously mixed as determined by visual inspection for color uniformity. H. The soil-bentonite layer shall be compacted to a minimum of 90% of the maximum density as determined by the Standard Proctor Test, ASTM-D698, using a vibratory compactor, or a flat steel wheel roller. Compaction equipment must be approved by the engineer after a demonstration of its effectiveness. Compaction with a sheepsfoot roller is not permitted. A minimum of 4 passes will be required on each area of each lift to remold the SBL regardless of whether the lift meets the compaction criteria. I. The Contractor shall only work on an area that can be completed in one working day. Completion shall be defined as subgrade preparation, scarification, soil moisture adjustment, spreading of the bentonite, mixing the soil with the bentonite, compaction of the soil-bentonite mixture, and covering of the SBL as described in Section 3.6. J. If desiccation and/or crusting of the surface of the SBL occurs before final cover placement, any such areas shall be scarified, re-wetted, and recompacted. K. Transition from the end of one completed section of the liner to the beginning of the next will be accomplished by re-mixing and recompacting within a transition zone that is not less than 3 feet (1 m) in width. 3.5 Detail Work Sealing the SBL around pipe penetrations, walls, and all other structures shall be performed by applying and hand-compacting a mixture of 1 part bentonite to 3 parts soil into a nominally-sized notch excavated into the subgrade around these structures. The moisture content of the bentonite- Page 6 of 7

rich mixture shall be adjusted to impart adequate plasticity and compactibility during placement of this material. 3.6 Cover Placement A. Cover soils shall be free of angular stones or other foreign matter which could damage the SBL. Cover soils should be approved by the project Engineer with respect to particle size, uniformity and angularity. B. A minimum thickness of 1 foot (300 mm) of soil or stone cover shall be applied over the SBL for protection against erosion, desiccation, vehicular traffic, animals, etc. A cover layer 600 mm in thickness is required on side slopes or where heavy equipment traffic may be present. Stone cover with a maximum particle size of 6 inches (150 mm) may be substituted for the upper 300 mm of soil in these areas. 3.7 Construction Quality Control (CQC) A. Construction Quality Control (CQC) tests as indicated in Table 2 shall be performed by the third-party quality Inspector at regular intervals upon completion of the SBL. Table 2. CQC Requirements for SBL. Parameter Test Method Test Frequency per Lift Moisture Content ASTM D 3017 1 per 10,000 ft 2 (1,000 m 2 ) Density ASTM D 2922 1 per 10,000 ft 2 (1,000 m 2 ) Flexible-Wall Permeability ASTM D 5084 1 per 100,000 ft 2 (10,000 m 2 ) B. All CQC test results shall achieve the required values as established by the engineer. Failure to achieve these values shall require re-working of the soil/bentonite mixture in the failed areas. 3.8 Activation For maximum SBL effectiveness if contaminated liquids are to be contained, the SBL shall be hydrated with fresh water for 72 hours prior to use. This fresh water may be applied to the SBL by sprinkling from a water truck, flooding the impoundment, or by waiting for natural rainfall prior to use. Page 7 of 7