TARTAN STRESSGARD 1/11 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifier Trade name Product code (UVP) 05810050 TARTAN STRESSGARD SDS Number 102000013748 EPA Registration No. 432-1446 Relevant identified uses of the substance or mixture and uses advised against Use Restrictions on use Information on manufacturer Emergency telephone no. Emergency Telephone Number (24hr/ 7 days) Product Information Telephone Number Fungicide See product label for restrictions. Bayer Environmental Science 2 T.W. Alexander Drive Research Triangle PK, NC 27709 United States 1-800-334-7577 SDS Information or Request SDSINFO.BCS-NA@bayer.com SECTION 2: HAZARDS IDENTIFICATION Classification in accordance with regulation HCS 29CFR 1910.1200 Acute toxicity (Inhalation): Category 4 Reproductive toxicity : Category 2 Signal word: Warning Hazard statements Harmful if inhaled. Suspected of damaging fertility or the unborn child. Precautionary statements Avoid breathing mist and spray. Use only outdoors or in a well-ventilated area.
TARTAN STRESSGARD 2/11 Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/ protective clothing/ eye protection/ face protection. IF exposed or concerned: Get medical advice/ attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local regulation. Other hazards No other hazards known. SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Component Name CAS-No. Concentration % by weight Triadimefon 43121-43-3 20.90 Trifloxystrobin 141517-21-7 4.20 56-81-5 10.70 SECTION 4: FIRST AID MEASURES Description of first aid measures General advice Inhalation Skin contact Eye contact Ingestion When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment. Move to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately. Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately. Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately. Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended. Most important symptoms and effects, both acute and delayed Symptoms To date no symptoms are known. Indication of any immediate medical attention and special treatment needed Treatment Appropriate supportive and symptomatic treatment as indicated by the
TARTAN STRESSGARD 3/11 patient's condition is recommended. There is no specific antidote. SECTION 5: FIREFIGHTING MEASURES Extinguishing media Suitable Unsuitable Carbon dioxide (CO2), Dry chemical, Foam, Water spray None known. Special hazards arising from the substance or mixture Advice for firefighters Special protective equipment for fire-fighters Further information Flash point > 93.3 C Autoignition temperature Lower explosion limit Upper explosion limit Explosivity Dangerous gases are evolved in the event of a fire. Firefighters should wear NIOSH approved self-contained breathing apparatus and full protective clothing. Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter drains or water courses. not applicable SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Precautions Methods and materials for containment and cleaning up Methods for cleaning up Additional advice Keep unauthorized people away. Isolate hazard area. Avoid contact with spilled product or contaminated surfaces. Keep in suitable, closed containers for disposal. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Clean contaminated floors and objects thoroughly, observing environmental regulations. Do not allow to enter soil, waterways or waste water canal. Reference to other sections Information regarding safe handling, see section 7. Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13.
TARTAN STRESSGARD 4/11 SECTION 7: HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Hygiene measures Handle and open container in a manner as to prevent spillage. Maintain exposure levels below the exposure limit through the use of general and local exhaust ventilation. Keep away from heat and sources of ignition. Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing. Conditions for safe storage, including any incompatibilities Requirements for storage areas and containers Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components CAS-No. Control parameters Update Basis Triadimefon 43121-43-3 0.7 mg/m3 OES BCS* Triadimefon 43121-43-3 100ug/m3 07 2011 TX ESL (ST ESL) Triadimefon 43121-43-3 10ug/m3 07 2011 TX ESL (AN ESL) Trifloxystrobin 141517-21-7 2.7 mg/m3 OES BCS* 56-81-5 15 mg/m3 02 2006 OSHA Z1 (Total dust.) (PEL) 56-81-5 5 mg/m3 02 2006 OSHA Z1 (Respirable fraction.) (PEL) 56-81-5 5 mg/m3 1989 OSHA Z1A (Respirable fraction.) 56-81-5 10 mg/m3 1989 OSHA Z1A (Total dust.) 56-81-5 10 mg/m3 06 2008 TN OEL (Total dust and mist.) 56-81-5 5 mg/m3 06 2008 TN OEL (Respirable fraction and dust or fume.) 56-81-5 50ug/m3 02 2013 TX ESL
TARTAN STRESSGARD 5/11 (Particulate.) (Particulate.) (Vapor.) (Vapor.) Pyrogenic (fumed) amorphous silica (Particulate.) Pyrogenic (fumed) amorphous silica (Particulate.) (ST ESL) 56-81-5 5ug/m3 (AN ESL) 56-81-5 100ug/m3 (AN ESL) 56-81-5 1000ug/m3 (ST ESL) 112945-52-5 2ug/m3 (AN ESL) 112945-52-5 27ug/m3 (ST ESL) *OES BCS: Internal Bayer CropScience "Occupational Exposure Standard" 02 2013 TX ESL 02 2013 TX ESL 02 2013 TX ESL 02 2013 TX ESL 02 2013 TX ESL Exposure controls Personal protective equipment In normal use and handling conditions please refer to the label and/or leaflet. In all other cases the following recommendations would apply. Respiratory protection Hand protection Eye protection Skin and body protection General protective measures When respirators are required, select NIOSH approved equipment based on actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations. Chemical resistant nitrile rubber gloves Safety glasses with side-shields Wear long-sleeved shirt and long pants and shoes plus socks. Follow manufacturer's instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water. Keep and wash PPE separately from other laundry. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Odor Odour Threshold ph Vapor Pressure green liquid viscous slight 6.5-7.5 at 10 % (25 C) aqueous suspension
TARTAN STRESSGARD 6/11 Vapor Density (Air = 1) Density 1.15 g/cm³ at 20 C Boiling Point Melting / Freezing Point Water solubility Minimum Ignition Energy Decomposition temperature Partition coefficient: n- octanol/water Viscosity dispersible not applicable 600-950 mpa.s Flash point > 93.3 C Autoignition temperature Lower explosion limit Upper explosion limit Explosivity not applicable SECTION 10: STABILITY AND REACTIVITY Reactivity Thermal decomposition Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under recommended storage conditions. No dangerous reaction known under conditions of normal use. freezing No decomposition products expected under normal conditions of use. SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes Immediate Effects Eye Ingestion Ingestion, Eye contact, Skin contact Moderate eye irritation. Harmful if swallowed.
TARTAN STRESSGARD 7/11 Information on toxicological effects Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Skin irritation Eye irritation Sensitisation Assessment repeated dose toxicity LD50 (female rat) 3,129 mg/kg LC50 (male/female combined rat) > 2.1 mg/l Exposure time: 4 h Determined in the form of a respirable aerosol. No deaths LC50 (male/female combined rat) > 8.4 mg/l Exposure time: 1 h Determined in the form of a respirable aerosol. Extrapolated from the 4 hr LC50. LD50 (male/female combined rat) > 5,000 mg/kg No skin irritation (rabbit) Mild eye irritation. (rabbit) Non-sensitizing. (guinea pig) Triadimefon did not cause specific target organ toxicity in experimental animal studies. Trifloxystrobin did not cause specific target organ toxicity in experimental animal studies. Assessment Mutagenicity Triadimefon was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Trifloxystrobin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Assessment Carcinogenicity Triadimefon was not carcinogenic in a lifetime feeding study in rats. Triadimefon caused an increased incidence of tumours in mice in the following organ(s): liver. The mechanism that triggers these tumours is not relevant to humans. Trifloxystrobin was not carcinogenic in lifetime feeding studies in rats and mice. ACGIH NTP IARC OSHA Assessment toxicity to reproduction Triadimefon caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. Triadimefon caused reduced fertility, a reduced pup survival. Trifloxystrobin caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Trifloxystrobin is related to parental toxicity.
TARTAN STRESSGARD 8/11 Assessment developmental toxicity Triadimefon caused developmental toxicity in only at dose levels toxic to the dams. Triadimefon caused an increased incidence of non-specific malformations. Trifloxystrobin caused developmental toxicity only at dose levels toxic to the dams. The developmental effects seen with Trifloxystrobin are related to maternal toxicity. Further information Only acute toxicity studies have been performed on the formulated product. The non-acute information pertains to the active ingredient(s). SECTION 12: ECOLOGICAL INFORMATION Toxicity to fish Toxicity to aquatic invertebrates LC50 (Oncorhynchus mykiss (rainbow trout)) 0.015 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient trifloxystrobin. LC50 (Oncorhynchus mykiss (rainbow trout)) 4.08 mg/l Exposure time: 96 h The value mentioned relates to the active ingredient triadimefon. EC50 (Daphnia magna (Water flea)) 0.016 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient trifloxystrobin. EC50 (Daphnia magna (Water flea)) 7.16 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient triadimefon. Toxicity to aquatic plants Biodegradability IC50 (Desmodesmus subspicatus) 0.0053 mg/l Growth rate; Exposure time: 72 h The value mentioned relates to the active ingredient trifloxystrobin. IC50 (Pseudokirchneriella subcapitata) 2.01 mg/l Growth rate; Exposure time: 120 h The value mentioned relates to the active ingredient triadimefon. Triadimefon: ; not rapidly biodegradable Trifloxystrobin: ; not rapidly biodegradable Koc Triadimefon: Koc: 150-510 Trifloxystrobin: Koc: 2377 Bioaccumulation Mobility in soil Environmental precautions Triadimefon: Bioconcentration factor (BCF) 31; Does not bioaccumulate. Trifloxystrobin: Bioconcentration factor (BCF) 431; Does not bioaccumulate. Triadimefon: Moderately mobile in soils Trifloxystrobin: Slightly mobile in soils Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark.
TARTAN STRESSGARD 9/11 Drift and runoff from treated areas may be hazardous to aquatic organisms in adjacent sites. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not apply when weather conditions favor runoff or drift. Apply this product as specified on the label. Do not allow to get into surface water, drains and ground water. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Product Contaminated packaging RCRA Information Dispose in accordance with all local, state/provincial and federal regulations. Follow container label instructions for disposal of wastes generated during use in compliance with the product label. Triple rinse containers. Puncture container to avoid re-use. Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke. Characterization and proper disposal of this material as a special or hazardous waste is dependent upon Federal, State and local laws and are the user's responsibility. RCRA classification may apply. SECTION 14: TRANSPORT INFORMATION 49CFR Not dangerous goods / not hazardous material IMDG UN number 3082 Class 9 Packaging group III Marine pollutant Proper shipping name IATA UN number 3082 Class 9 Packaging group III Environm. Hazardous Mark Proper shipping name YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIFLOXYSTROBIN SOLUTION) YES ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (TRIFLOXYSTROBIN SOLUTION )
TARTAN STRESSGARD 10/11 This transportation information is not intended to convey all specific regulatory information relating to this product. It does not address regulatory variations due to package size or special transportation requirements. SECTION 15: REGULATORY INFORMATION EPA Registration No. 432-1446 US Federal Regulations TSCA list 56-81-5 US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D) SARA Title III - Section 302 - Notification and Information SARA Title III - Section 313 - Toxic Chemical Release Reporting Triadimefon 43121-43-3 25,000lbs US States Regulatory Reporting CA Prop65 This product does not contain any substances known to the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Triadimefon 43121-43-3 Developmental toxin. Triadimefon 43121-43-3 Male reproductive toxin. Triadimefon 43121-43-3 Female reproductive toxin. US State Right-To-Know Ingredients Triadimefon 43121-43-3 NJ 56-81-5 MN Canadian Regulations Canadian Domestic Substance List 56-81-5 Environmental CERCLA Clean Water Section 307 Priority Pollutants Safe Drinking Water Act Maximum Contaminant Levels International Regulations European Inventory of Existing Commercial Substances (EINECS) Triadimefon 43121-43-3 56-81-5 EPA/FIFRA Information:
TARTAN STRESSGARD 11/11 This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information required on the pesticide label: Signal word: Hazard statements: Caution! Harmful if swallowed. Moderate eye irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. SECTION 16: OTHER INFORMATION NFPA 704 (National Fire Protection Association): Health - 2 Flammability - 1 Instability - 0 Others - none HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide) Health - 1 Flammability - 1 Physical Hazard - 0 PPE - 0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard Reason for Revision: Revised according to the current OSHA Hazard Communication Standard (29CFR1910.1200) Revision Date: 11/25/2014 This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.