PROJECTS AT GAZ DE FRANCE WGC 2006

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OPERATIONAL CO 2 SEQUESTRATION PROJECTS AT GAZ DE FRANCE S. SAYSSET, C. RIGOLLET, J. GITTON, R. DREUX WGC 2006

Change in the energy mix Coal, oil Natural gas Renewables Energy management Improvement in energy efficiency and rational energy use Technical solutions for reducing CO 2 emissions Carbon cycle management Diapo 2 Natural carbon stocks Industrial techniques for capturing and storing CO 2 emissions

Capture Different techniques are available About 75% of the CCS costs NEED to REDUCE COSTS Transport Pipe or ships What are the costs of CCS? What are the main Costs depend strongly on the volumes being transported and on the distances involved : 2 to 7 /t CO 2 for 100 km challenges for CCS? NO BIG TECHNICAL CHALLENGE Diapo 3 Storage Natural underground reservoir (depleted O&G fields, coal seams, saline aquifers ) Costs depend on the site, its location : 2 to 10 /t CO 2 NEED to DEMONSTRATE the FAISABILITY through PILOT PLANTS

Gaz de France and operational CCS SNOVHIT CASTOR (EU) K12B (CRUST) RECOPOL (EU) Diapo 4 PICOREF

CASTOR project (EU - FP 6) «CO 2, from Capture to Storage» Objectives Reduce the cost of CO 2 post-combustion capture Contribute to the feasibility & acceptance of the geological storage concept Diapo 5 Validate the concept on real sites Pilot testing for capture (25 t CO 2 / day) Detailed studies of future storage projects

CASTOR project Budget: 15,8 M EU funding: 8,5 M Duration: 4 years (2004 2008) 30 partners from 11 European countries Diapo 6 R&D IFP (FR) TNO (NL) SINTEF (NO) NTNU (NO) BGS (UK) BGR (DE) BRGM (FR) GEUS (DK) IMPERIAL (UK) OGS (IT) TWENTE U. (NL) STUTTGARTT U. (DE) Oil & Gas STATOIL (NO) GAZ de FRANCE (FR) REPSOL (SP) ENITecnologie (IT) ROHOEL (AT) Power Companies VATTENFALL (SE) ELSAM (DK) ENERGI E2 (DK) RWE (DE) PPC (GR) POWERGEN (UK) Co-ordinator: IFP Chair of the Executive Board: Statoil Manufacturers ALSTOM POWER (FR) MITSUI BABCOCK (UK) SIEMENS (DE) BASF (DE) GVS (IT)

CASTOR project : capture Esbjerg Power unit (Elsam) Application in modern coal-fired power station: Esbjerg PS operated by ELSAM Capacity 1 ton/h CO 2 Pilot plant is the largest test facility in the world Boiler house Turbine hall De-SOx plant Diapo 7

Objectives CASTOR project : storage Focus on field cases to cover some geological variability Casablanca case (Repsol, Spain): Depleted offshore oil field, deep. Atzbach-Schwanenstadt case (Rohoel AG, Austria): Depleted onshore gas field, shallow. K12B case (Gaz de France, Netherlands) Enhanced gas recovery, offshore, deep; injection started in 2004. Diapo 8 Snøhvit case (Statoil, Norway) Aquifer below gas/condensate field, offshore; injection will start in 2007.

K12-B Diapo 9 K12-B is part of the dutch CRUST project CO 2 Reuse through Underground STorage

K12-B, The Netherland Before 2004 K12-B gas field has been operated since 1987 The gas produced contains a relatively large amount of CO 2 (13%) CO 2 was separated from natural gas and vented K12-B to the atmosphere before injection project Diapo 10 Since 2004, CO 2 is re- injected Amsterdam In the framework of : CO2 Reuse though Underground Storage (NL) CO2GEONET and CASTOR (EU) Partner : Gaz de France, TNO (NL)

K12-B a 3 phases project Feasibility study (2002-2003) Operational implementation test (2004-2006) 20 kt CO 2 /y about 22 /t CO 2 Scale-up potential of 400 kt CO 2 /an about 8 /t CO 2 Diapo 11 Reservoir size estimated to 8Mt CO 2, i.e. 0.5% of the industrial emission of the Netherlands over 20 years.

PICOREF project (RTPG - ANR) «CO 2 trapping in reservoir in France» Main objectives Identify injection sites in France and define pilot operations from a selection of geological reservoir targets Elaborate and test a methodological work-flow chart able to address a site evaluation for a CO 2 storage project Diapo 12 R&D BRGM IFP INERIS Industry Air Liquide Alstom CFG Services CGG Correx Gaz de France Gaz de France Géostock Magnitude La SNET Total Universties ARMINES-ENSM ICMCB-CNRS LMTG-CNRS LGIT-CNRS TPHY-ISTEEM LAEGO-INPL

RECOPOL project (EU - FP 5) «Reduction of CO 2 emission by means of CO 2 storage in coal seams in Silesian Coal Basin in Poland» Main objectives Evaluate the feasibility of CO 2 sequestration in coal beds Combine CO 2 sequestration with natural gas production Diapo 13 CH 4 CO ² MS4 Old well MS3 In course Partners: TNO, IFP, Air Liquide, Gazonor, Gaz de France, SBI-GUT, Advanced ressources International, Aachen University, Delt Technical university, Central mining Institute, CSIRO, IEA.

SNØHVIT, Norway The gas produced will contain about 6-12% of CO 2 Production will begin late 2006, and 0.75 Mt CO 2 /y injected Diapo 14 Partners : Statoil, Petoro, Total, Gaz de France, Amerada Hess and RWE

CONCLUSIONS Following IPCC, Carbon Capture and Storage can make a significant contribution to GHG emission reduction It is estimate to 2000 Gt CO 2 and may represent 15%- 55% of the mitigation effort to 2100, depending of economic conditions. Carbon capture and storage challenges : Capture costs reduction Pilot and demonstration plants Diapo 15 Public awareness and acceptance Legal and regulatory framework Long-term policy framework