Tacolyn resin dispersions

Tacolyn resin dispersions

Contents Tacolyn resin dispersions 3 Product Range 3 Piping 4 Pumps 4 Filtration 4 Sampling 5 Chemical contamination 5 Storage and handling of Tacolyn water-based resin dispersions 5 Shipping 5 Bulk storage 6 Temperature 6 Application data 7 2

Tacolyn resin dispersions A major supplier to the adhesives industry, Eastman manufactures and sells dispersions of rosin- and hydrocarbon-derived tackifying resins for use in waterbased adhesives and sealants. These dispersions are prepared through a proprietary, solvent-free process. With a broad range of hydrocarbon- and rosin-derived base resins from which to start, Eastman offers a complete line of Tacolyn resin dispersions. Eastman manufactures dispersions with a range of softening points and polymer compatibility for use in many pressure-sensitive and non-pressure-sensitive adhesive applications. Safety Data Sheets (SDSs) for these products are available online at www.eastman.com or on request by contacting Eastman at one of the locations shown on the back cover. Product Range Ring & ball softening point a ( C) ph tolerance range Resin dispersion typical properties % Solids Viscosity b (cps) Density (lb/gal) Particle size c (nm) Coarse particles d Products ph Rosin ester resin dispersions Tacolyn 3509 73 7.0 4 13 55 230 8.8 200 0.1000% max. Hydrogenated rosin ester resin dispersions Tacolyn 3100 92 10.0 4 13 55 900 8.5 250 0.1000% max. Tacolyn 3400 92 10.0 >7 55 1,100 8.6 225 0.1000% max. Aliphatic hydrocarbon resin dispersions Tacolyn 5070 70 4.0 4 13 50 100 8.1 250 0.1000% max. Tacolyn 5085 82 10.0 4 13 55 1,300 8.2 250 0.1000% max. Pure monomer hydrocarbon resin dispersions Tacolyn 5194 85 12.0 >7 55 460 8.4 250 0.1000% max. Aromatic modified hydrocarbon resin dispersions Tacolyn 1070 70 10.0 4 13 55 1,400 8.4 250 0.1000% max. Tacolyn 5002 70 10.5 >7 55 400 8.4 250 0.1000% max. Tacolyn 5003 130 11.0 >7 45 1,000 8.5 250 0.1000% max. a Dispersed phase (base resin + emulsifier) b Brookfield, 25 C c Average particle size d Wt% of particles > 45 microns Shelf life of all Tacolyn dispersions is 6 months. 3

Tacolyn resin dispersions Piping The size of the piping is determined by the desired volumetric throughput. Care must be taken to keep turbulence to a minimum. A velocity of 3 ft/s is the recommended maximum. Any metal is suitable where only the possible contamination to the product is to be considered. Polyethylene materials are also suitable. The excellent cold-water stability of the products permits rapid flushing. Provisions should be made for flush-out connections at both ends of the piping. Plugged or capped tee-connections allow rapid flushing and minimum pipe maintenance. If flushing into the product storage tank, softened or deionized water should be used. Avoid using solvents, even low-boiling solvents, to flush piping since any residual solvent will be emulsified when the dispersion passes through the piping again. Pumps Wherever possible, it is advisable to use air pressure or gravity systems for moving the dispersions. These systems are relatively maintenance free and have the least possibility of causing mechanical damage to the product. Avoid using positive-displacement or centrifugal pumps. This is particularly true in recirculating systems. Air-operated, double-diaphragm pumps are suggested for applications requiring higher head pressures or volumetric throughput. Filtration Filtration is recommended for applications sensitive to coarse particles. The average particle size of Eastman water-based resin dispersions is less than 1 µm. Coarse particles, formed as a result of evaporation in partially used drums, are generally larger than 45 µm and are easily filtered. Avoid filtration through very small micron size filters at either high pressure or high rate because the shear forces may cause additional coarse particles to form. 4

Tacolyn resin dispersions Sampling Creaming or sedimentation may occur during storage and shipment. These do not in any way represent a breaking of the product and are fully reversible processes. However, the dispersion products should be carefully mixed before sampling and analysis. Tank-truck quantities should be sampled from the top and the bottom and analyzed separately, or the material should first be pumped into the storage tank and then sampled. Drummed or toted material can be mixed with a low-shear motorized mixer or by hand, using a paddle. Chemical contamination Contamination of process equipment and piping with incompatible materials should be avoided. Eastman waterbased resin dispersions are sensitive to some electrolytes and may be permanently damaged by contamination with quantities as low as 80 parts per million (ppm). Such contaminants include acids, bases, and metal salts. Ion tolerance may be greater with some products than others. Storage and handling of Tacolyn water-based resin dispersions Shipping Tacolyn water-based resin dispersions are shipped in lined fiber drums, disposable totes, or tank trucks. For drums and totes, these products may be pumped or gravity fed into the storage tank. For tank trucks, these products may be pumped, gravity fed, or blown. When using air pressure to unload these products from tank trucks, care must be taken not to blow air through the material, which will result in foaming. Foaming can be prevented by the gradual throttling of the unloading valve when the truck is nearly empty. 5

Tacolyn resin dispersions Bulk storage Products should be stored in coated, iron, or steel tanks or in polyethylene tanks if not exposed to freezing conditions. Any suitable coating or the use of stainless steel storage vessels is advisable. Tanks should be equipped with a manhead at least 18 in. in diameter for occasional inspection and cleaning. The tank drain should be 3 in. in diameter and flanged. Charging the tank by pumping in through the drain is preferred. Care must be taken to avoid free fall and the generation of foam. Dip lines should not be used; they retain a stagnant product that might separate on standing. All other tank openings should be reasonably tight to reduce evaporation. It is important to keep the product moving during storage to prevent sedimentation and surface crusting. However, high shear agitation will cause mechanical damage to the product and should therefore be avoided. It is recommended that the interior or storage vessels be periodically cleaned to lessen the risk of bacterial attack. Some resin dispersions contain biocides which lose effectiveness over time while other dispersions are naturally resistant to bacteria. Temperature The recommended storage temperature range is 50 100 F. Freezing must be avoided. At temperatures below 50 F, the material may paste. Chilled or near-frozen material may be brought back to a usable condition by slowly elevating the temperature with no agitation. Because temperature cycling may lead to permanent damage of the product, it is important to maintain a constant storage temperature. Heated tanks must be designed to maintain temperatures without creating localized surface heating above 100 F. When products are stored in a warehouse, be aware of localized heating. Do not store products near space heaters or steam heaters such as fin pipe steam heaters that run along walls. Jacketed vessels and jacketed piping that circulate a heattransfer fluid in a closed-loop system are preferred. Note: Freeze indicators are applied before shipment to every tenth drum of product to monitor handling conditions while in transit. Freeze indicators are also applied to every fourth tote shipment. Contact your local Eastman technical representative, email us at adhesives@eastman.com or call 1-800-EASTMAN, Ext. 0507 for more information concerning your specific application. 6

Tacolyn resin dispersions Application data Application Latex polymer Suggested resin dispersion Comments 2-Ethylhexyl acrylate Tacolyn 3509 Low surface tension tackifier that generally does not require the post-addition of wetting agent when coating to silicone release liner. Excellent cohesion and humidity resistance. Vinyl acrylate Acrylic with ph <6 Tacolyn 1070 Promotes adhesion to low-energy substrates and recycled corrugated board while offering excellent cohesive strength. May be used in clear filmic label applications. Labels Tacolyn 3100 Tacolyn 3509 Highly hydrogenated and very high compatibility with various polymer systems. Good performance in high-temperature applications. May be used in clear filmic label applications. Low surface tension tackifier that generally does not require the post-addition of wetting agent when coating to silicone release liner. Excellent cohesion and humidity resistance. Butyl acrylate Acrylic with ph <6 Tacolyn 1070 Promotes adhesion to low-energy substrates and recycled corrugated board while offering excellent cohesive strength. May be used in clear filmic label applications Tacolyn 3100 Highly hydrogenated and very high compatibility with various polymer systems. Good performance in high-temperature applications. May be used in clear filmic label applications. Tacolyn 5085 Good reinforcing agent that maintains excellent peel control. Styrene-butadiene Tapes rubber Natural rubber Tacolyn 5002 Tacolyn 5070 Excellent all-purpose SBR tackifier. Minimal surfactant package makes it useful in foam bonding where quick break is necessary. Ideal for low-peel applications, as it imparts peel strength in small increments relative to resination level. Excellent resistance to acids as well as alkalis. Tacolyn 5085 Good reinforcing agent that maintains excellent peel control. Tacolyn 5002 Good cohesive strength due to minimal surfactant package. Contact adhesives Polychloroprene (neoprene) Tacolyn 5003 Promotes very high-temperature performance. Can be used in adhesives that require postforming bonds of high pressure laminate to particleboard. Tacolyn 3400 Excellent high-temperature strength. Cleared for food contact applications in adhesive formulations at 21 CFR 175.105 and 21 CFR 175.125, subject to the provisions in these regulations. 7

Eastman Chemical Company Corporate Headquarters P.O. Box 431 Kingsport, TN 37662-5280 U.S.A. Telephone: U.S.A. and Canada, 800-EASTMAN (800-327-8626) Other Locations, (1) 423-229-2000 Fax: (1) 423-229-1193 Eastman Chemical Latin America 9155 South Dadeland Blvd. Suite 1116 Miami, FL 33156 U.S.A. Telephone: (1) 305-671-2800 Fax: (1) 305-671-2805 Eastman Chemical B.V. Fascinatio Boulevard 602-614 2909 VA Capelle aan den IJssel The Netherlands Telephone: (31) 10 2402 111 Fax: (31) 10 2402 100 Eastman (Shanghai) Chemical Commercial Company, Ltd. Jingan Branch 1206, CITIC Square No. 1168 Nanjing Road (W) Shanghai 200041, P.R. China Telephone: (86) 21 6120-8700 Fax: (86) 21 5213-5255 Eastman Chemical Japan Ltd. MetLife Aoyama Building 5F 2-11-16 Minami Aoyama Minato-ku, Tokyo 107-0062 Japan Telephone: (81) 3-3475-9510 Fax: (81) 3-3475-9515 Eastman Chemical Asia Pacific Pte. Ltd. #05-04 Winsland House 3 Killiney Road Singapore 239519 Telephone: (65) 6831-3100 Fax: (65) 6732-4930 www.eastman.com Although the information and recommendations set forth herein are presented in good faith, Eastman Chemical Company makes no representations or warranties as to the completeness or accuracy thereof. You must make your own determination of their suitability and completeness for your own use, for the protection of the environment, and for the health and safety of your employees and purchasers of your products. Nothing contained herein is to be construed as a recommendation to use any product, process, equipment, or formulation in conflict with any patent, and we make no representations or warranties, express or implied, that the use thereof will not infringe any patent. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE, OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS AND NOTHING HEREIN WAIVES ANY OF THE SELLER S CONDITIONS OF SALE. Safety Data Sheets providing safety precautions that should be observed when handling and storing our products are available online or by request. You should obtain and review available material safety information before handling our products. If any materials mentioned are not our products, appropriate industrial hygiene and other safety precautions recommended by their manufacturers should be observed. 2014 Eastman Chemical Company. Eastman and Tacolyn are trademarks of Eastman Chemical Company. WA-85C 2/14