Point-of-use Water Disinfection by Means of UVC LED s

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Point-of-use Water Disinfection by Means of UVC LED s 2nd Conference on Technology and Applications of Nitride Semiconductors Walter Wipprich 19 th of September 2013, Berlin 1

Clean water supply remains a challenge for humankind More than 20% of the world population does not have access to clean and safe drinking water* *Source: World Healthy Organization (WHO) PURION Point-of-use Water Disinfection by Means of UVC LED's - 2

1 PURION your partner within UV-technology 2 UV-disinfection by means of traditional UV-lamps 3 UV-disinfection by means of UVC-LED PURION Point-of-use Water Disinfection by Means of UVC LED's - 3

The company PURION GmbH develops and manufactures UV systems for the disinfection of water, air and surfaces Summary: Company data Hamburg General Data Beginning of the business activity: 2006 Certified according DIN EN ISO 9001 : 2008 All systems are developed and produced at the location of the company PURION in Thuringia. Projects in Germany, Austria, Spain, Thailand, Brazil, Haiti, Switzerland, Portugal, Denmark,... Cologne PURION GmbH Berlin Products Disinfection plants for water, air und surface disinfection based on UV-technology Specialized on small plants for decentralized use (e.g. UVsystems with a power 300-1000 l/h) Actually as radiation source low pressure mercury lamps are used mainly Munich Research Research on future UV-technologies (in cooperation with German universities) Member of the Advanced UV for life group: joint development of UVC-LED point of use systems within the program twenty20 Partnership for innovation (funded by BMBF) PURION Point-of-use Water Disinfection by Means of UVC LED's - 4

Example: PURION products for more information visit our website: www.purion.de Water Air Surface Drinking water Pools Fish ponds Storm water of sewage plants Pharmacy Water of air conditioning Disinfection of permeate Aquariums Breweries Dairies Bakery Packaging industry Breeding farms PURION Point-of-use Water Disinfection by Means of UVC LED's - 5

1 PURION your partner within UV-technology 2 UV-disinfection by means of traditional UV-lamps 3 UV-disinfection by means of UVC-LED PURION Point-of-use Water Disinfection by Means of UVC LED's - 6

Point of use disinfection of water is not only important for developing and transitional countries Examples: challenges and applications of Point of Use disinfection of water Developing and transitional countries Developed countries A central water supply doesn t exist in many countries and regions The use of water sources near the surface of earth is growing (more germs infected then groundwater) Sufficient trustfulness into public water supply is absent in many countries... Essential is the quality of water at the sampling point Mobil applications e.g. ships, caravans and events of rescue and catastrophe Within warm water installations for prevention against legionella Well systems Hygenical high sensitive sampling points e.g. health sector and food industry Essential is the quality of water at the sampling point What is necessary: I. II. appropriate methodology technical solution PURION Point-of-use Water Disinfection by Means of UVC LED's - 7

UV-C radiation is an effective method to disinfect water without toxic impact - Microorganism are destroyed or inactivated by wavelength below 280 nm (UVC) I. Operating principle of UV-C radiation Characterization of UV-C radiation Operating principle of UV-C radiation Part of electro-magnetic radiation bounded by: the lower wavelength extreme of the visible spectrum and the upper end of the X-ray radiation band Spectral range: 100-400 nm (invisible to human eyes) UVC: ~180nm 280nm (short wave radiation) UVC works using a photolytic effect whereby the radiation destroys or inactivates the microorganism it can no longer multiply PURION Point-of-use Water Disinfection by Means of UVC LED's - 8

State of the art is the usage of low pressure mercury UV-lamps as the radiation source within a reactor (mostly stainless steel) II. Components and Installation principle of UV-plants Main Components of UV-plant Installation principle UV-lamp The distance between the UV lamp and the reactor has to be calculated taking account of the transmission of water Flow of water should be from the bottom up to the exit of the reactor reactor Power PURION Point-of-use Water Disinfection by Means of UVC LED's - 9

Point of use disinfection of water today is realized by using small UV plants natural boundaries given by the minimal length of the UV-lamp II. Example: Point of use applications today Developing countries: Tropics Box Developed countries Realisation of a compact system to ensure uvdisinfection of surface water The system should be adequate according to tropical conditions and suitable for been run independent from power supply systems Suitable to for operation via solar power Possibility for decentralized disinfection of water for Caravans, expedition vehicles etc. System should be space-saving and shatter proofed PURION Point-of-use Water Disinfection by Means of UVC LED's - 10

1 PURION your partner within UV-technology 2 UV-disinfection by means of traditional UV-lamps 3 UV-disinfection by means of UVC-LED PURION Point-of-use Water Disinfection by Means of UVC LED's - 11

relatively effect UVC-radiation for disinfection of water can be emitted by LED technical solutions to be developed I. Basics: disinfection by means of UVC LED s Disinfection effect of the UV radiation from LED s Structure of the intensity of UV radiation from LED s (surface emitting diode) 1,4 1,2 1 0,8 0,6 0,4 0,2 UVC-Hg-lamp Hg-Lampe 0 200 220 240 254260 280 300 wavelength[nm] Spectral line of cell inactivation UVC-LED The adapted wavelength of LED allows an increase of efficiency by approx.y 20% to HG lamp Radiation intensity of a UV-LED is distributed elliptical Full intensity immediately after switch on PURION Point-of-use Water Disinfection by Means of UVC LED's - 12

-8 mm -6 mm -4 mm -2 mm 0 mm 2 mm 4 mm 6 mm 8 mm The development of geometries for disinfection plants has to base on the diffusion pattern I. Design of pipe geometries Simulation of the Structure of the UV radiation from LED s (surface-emitting diode) Development of pipe geometries Idealer Rohrquerschnitt 0 mm 2 mm 4 mm 6 mm 8 mm 10 mm circle Kreis ideal 12 mm 14 mm The diffusion of radiation starting from the surface of the chip has been simulated The circle is not the optimal geometry for a homogenoues radiation How to get elliptical geometries? PURION Point-of-use Water Disinfection by Means of UVC LED's - 13

PURION already did first research regarding possible geometries of a reactor for usage of LED II. Examples for reactor geometries First test results with swirl with double notches with triple notches Aim: Development of reactor design under consideration of UV-LED radiation pattern, adjustment of water flow and circulation Approach: Deformation of the quartz pipe to generate turbulences in the area of radiation PURION Point-of-use Water Disinfection by Means of UVC LED's - 14

Due to the small size of UVC-LED s installation can be carried out very flexible and close to the sampling point II. Example Schematic example for installation Questions to be answered Optimal geometry of the quarz pipe Typ Optimal arrangement of the UVC-LED s Packing density of UVC-LED s UV-LED Quartz tube Optics for LED PURION Point-of-use Water Disinfection by Means of UVC LED's - 15

Further R&D regarding UVC-LED has to be carried out - the potential advantages of this technology are extensive Summary of potential advantages of UVC-LED Energy efficiency due to o Possibility to adjust the wavelengths of the UV-light according to the maximum of the DNA - absorbent band o Immediate readiness for operation after switch on Small power and voltage peaks during switch on Safe operation due to safety extra-low voltage Possibility to adjust the radiation characteristics Narrowband emission without disturbing side peaks (unwanted generation of OZON) Ecologically friendly due to absence of mercury No thermal radiation New geometries also for very small flow rates Robust and shatter proofed UVC-LEDs are a great opportunity to improve the existing UVC water disinfection technology It will become possible to realize the disinfection of water directly at the sampling point. PURION Point-of-use Water Disinfection by Means of UVC LED's - 16

Your contact Walter Wipprich Managing Director E-Mail walter.wipprich@purion.de Phone +49.3682.479087 Fax +49.3682.479086 Schubertstreet 18 98544 Zella-Mehlis www.purion.de