Page 1/7 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier Registration number: This product is a preparation. Preparations are not registered in compliance with the REACH-regulation. Relevant identified uses of the substance or mixture and uses advised against Application of the substance/the preparation: Compound for surface finishing. Details of the supplier of the safety data sheet Manufacturer/Supplier: Walther Trowal GmbH & Co. KG Phone: +49 (0) 212 957 10 Rheinische Str. 35-37 Fax.: +49 (0) 212 957 1225 D-42781 Haan Email: info@walther-trowal.de Germany www.walther-trowal.de Wheelabrator Group, Ltd. Phone: +44 (0) 121 326 6481 43 / 44 Gravelly Industrial Park, Tyburn Road Fax.: +44 (0) 121 328 0256 Birmingham, B24 8TG Email: walthertrowal@wheelabratorgroup.co.uk United Kingdom www.wheelabratorgroup.com Emergency telephone number: Walther Trowal GmbH & Co. KG Laboratory department Tel.: +49 (0) 212 957 1300 (Languages: German, English) 2 Hazards identification Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xi; Irritant R36: Irritating to eyes. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials. Code letter and hazard designation of product: Xi Irritant
Page 2/7 Risk phrases: 36 Irritating to eyes. Safety phrases: 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. 3 Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of substances listed below with nonhazardous additions. Dangerous components: EINECS: 271-706-6 Fatty acids, C6-12, potassium salts Xi R36 Eye Irrit. 2, H319 Polymer Poly(oxy-1,2-ethanediyl),.alpha.-tridecyl-.omega.-hydroxy-, branched Xi R41 Eye Dam. 1, H318 Polymer Poly(oxy-1,2-ethanediyl),.alpha.-[(9Z)-2-[(1-oxo-9-octadecenyl)amino] ethyl]-.omega.-hydroxy- Xi R36 Eye Irrit. 2, H319 EINECS: 286-238-8 Fatty acids, C6-10, compounds with ethanolamine Xi R36/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319 Additional information: All contents substances or the base materials of polymers are listed in the EINECS/ELINCS. For the wording of the listed risk phrases refer to section 16. 4 First aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Generally the product does not irritate the skin. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor.
Page 3/7 Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Firefighting measures Extinguishing media Suitable extinguishing agents: CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: not known Special hazards arising from the substance or mixture In case of fire, the following can be released: Nitrogen oxides (NOx) Carbon monoxide (CO) Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Particular danger of slipping on leaked/spilled product. Environmental precautions: Dilute with plenty of water. Keep contaminated washing water and dispose of appropriately. Do not allow to enter sewers/ surface or ground water. Do not allow to penetrate the ground/soil. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage Handling Precautions for safe handling No special precautions are necessary if used correctly. Information about fire - and explosion protection: No special measures required. Conditions for safe storage, including any incompatibilities Storage Requirements to be met by storerooms and receptacles: No special requirements.
Page 4/7 Information about storage in one common storage facility: not required Further information about storage conditions: Keep container tightly sealed. Recommended storage temperature: 5-35 C Minimum durability [years]: 2 Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. A contact with the eyes. Do not eat or drink while working. Respiratory protection: not required Protection of hands: not required Eye protection: Tightly sealed goggles Body protection: Protective work clothing 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Colour: Odour: Odour threshold: ph-value at 20 C: 9.1 Fluid Red Characteristic
Page 5/7 ph-value (10 g/l, 20 C): 7,8-8,6 Change in condition Melting point/melting range: undetermined Boiling point/boiling range: > 100 C Setting temperature / range: -2 C Flash point: > 100 C Flammability (solid, gaseous): Ignition temperature: Decomposition temperature: Self-igniting: Danger of explosion: Explosion limits: Lower: Upper: Vapour pressure at 20 C: Density at 20 C: Relative density Vapour density Evaporation rate Solubility in / Miscibility with water: Not applicable. Product is not selfigniting. Product does not present an explosion hazard. 23 hpa 1.02 g/cm³ fully mixable Segregation coefficient (n-octanol/water): Viscosity: Dynamic at 20 C: Kinematic: Other information 10 Stability and reactivity Reactivity Chemical stability 4 mpas No further relevant information available. Thermal decomposition / conditions to be aed: No decomposition if used according to specifications. Possibility of hazardous reactions No dangerous reactions known. Conditions to a No further relevant information available. Incompatible materials: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known.
Page 6/7 11 Toxicological information Information on toxicological effects Acute toxicity: Primary irritant effect: on the skin: no irritant effect on the eye: Irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latest version: Irritant 12 Ecological information Toxicity Aquatic toxicity: No further relevant information available. Persistence and degradability No further relevant information available. Bioaccumulative potential No further relevant information available. Mobility in soil No further relevant information available. General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. Other adverse effects No further relevant information available. 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. European waste catalogue: 07 06 01* aqueous washing liquids and mother liquors Uncleaned packaging Recommendation: Disposal must be made according to official regulations. Recommended cleansing agents: Water * 14 Transport information UN-Number ADR, ADN, IMDG, IATA
Page 7/7 UN proper shipping name ADR, ADN, IMDG, IATA Transport hazard class(es) ADR, ADN, IMDG, IATA Class Packing group ADR, IMDG, IATA Environmental hazards: Marine pollutant: No Special precautions for user Not applicable. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. R36 Irritating to eyes. R36/38 Irritating to eyes and skin. R41 Risk of serious damage to eyes. Department issuing MSDS: Walther Trowal GmbH & Co. KG Laboratory department Email: ehs@walther-trowal.com Contact: Dr. Lutz Rickerich, Dipl.-Ing. Angelika Helten, Philipp Schubert (Languages: German, English) * Data compared to the previous version altered. (GB-EN)