1/8 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Kræves ikke Container size: 3.9 kg / 1000 tablets 1.2. Relevant identified uses of the substance or mixture and uses advised against Application: For laboratory use for Kjeltec Systems 1.3. Details of the supplier of the safety data sheet Supplier: FOSS Analytical AB Comp.Reg.No. 556105-6564 Pål Anders väg 2 SE-263 21 Höganäs Tel:+46 42 361500 Fax: +46 42 331465 info@foss.dk www.foss.dk Responsible for material FOSS_SDS_info@dhigroup.com safety data sheet authoring. Any questions to the contents of this material safety data sheet should be sent to: 1.4. Emergency telephone number Emergency telephone: Poison Control Centers may be available in specific States.
2/8 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture The product is classified: N;R50-53 Human health: Environment: 2.2. Label elements May irritate eyes and skin. The product is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S57 S60 S61 2.3. Other hazards PBT/vPvB: Use appropriate containment to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheets. NFPA Rating: Health:1 Fire:0 Reactivity:0 Other:- Dangerous for the environment SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures The product contains: inorganic salts 67/548/EEC: %: CAS-No.: EC No.: REACH Reg. No: 10-<20 7758-99-8 - - Copper(II) sulfate pentahydrate References: Chemical name: Hazard classification: Notes: Xn;R22 Xi;R36/38 N;R50-53 The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16.
3/8 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Inhalation: Skin contact: Eye contact: Ingestion: 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects: 4.3. Indication of any immediate medical attention and special treatment needed Medical attention/treatments: Move injured person into fresh air and keep person calm under observation. If uncomfortable: Seek hospital and bring these instructions. Remove contaminated clothing immediately and wash skin with soap and water. Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids widely. If irritation persists: Seek medical attention and bring these instructions. Immediately rinse mouth and drink plenty of water. Keep person under observation. Seek medical advice and bring along these instructions. See section 11 for more detailed information on health effects and symptoms. Not known. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media: 5.2. Special hazards arising from the substance or mixture Specific hazards: 5.3. Advice for firefighters Protective measures in fire: Use fire-extinguishing media appropriate for surrounding materials. When heated and in case of fire, toxic vapours/gases may be formed. Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: 6.2. Environmental precautions Environmental precautions: 6.3. Methods and material for containment and cleaning up Spill Cleanup Methods: 6.4. Reference to other sections Avoid inhalation of dust and contact with skin and eyes. For personal protection, see section 8. Follow precautions for safe handling described in this material safety data sheet. Do not discharge onto the ground or into water courses. Collect spillage with vacuum cleaner, shovel, broom or the like. Flush contaminated area with plenty of water. References: For waste disposal, see section 13.
4/8 SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Safe handling advice: Technical measures: Technical precautions: Avoid inhalation of dust and contact with skin and eyes. Avoid spreading dust. Extraction Hood 7.2. Conditions for safe storage, including any incompatibilities Technical measures for safe storage: Storage conditions: 7.3. Specific end use(s) Specific use(s): No special precautions. Keep well closed and protected from direct sunlight and moisture. Store at room temperature. TRANSPORT CONDITIONS: Temperature not critical. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Occupational exposure limits: CAS-No.: Chemical name: As: Exposure limits: Type: Notes: References: - Copper dusts and mists Cu 1 mg/m3 TWA - ACGIH - Copper, fume Cu 0.1 mg/m3 TWA - OSHA - Copper, dusts and mists Cu 1 mg/m3 TWA - OSHA - Copper, fume - 0.2 mg/m3 TWA - ACGIH 8.2. Exposure controls Engineering measures: Personal protection: Respiratory equipment: Hand protection: Eye protection: Environmental Exposure Controls: Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of inhalation of dust. Personal protection equipment should be chosen according to the the ANSI standards and in collaboration with the supplier of the personal protective equipment. Risk of inhalation of dust: Use respiratory equipment with particle filter, type P2. Risk of contact: Wear protective gloves. Nitrile gloves are recommended. Alternative types of gloves: Butyl rubber, neoprene or PVC Risk of contact: Wear goggles/face shield. No information available.
5/8 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance: Odor: ph: Melting point: Boiling point: Flash point: Explosion limits: Relative density: Solubility: 9.2. Other information Other data: flat round blue speckled tablets Odorless not relevant not available not available not available not relevant not available soluble in water Not available. SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity Reactivity: 10.2. Chemical stability Stability: 10.3. Possibility of hazardous reactions Hazardous Reactions: 10.4. Conditions to avoid Conditions/ materials to avoid: 10.5. Incompatible materials Stable. None specific. 10.6. Hazardous decomposition products Hazardous decomposition products: None in particular. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects Inhalation: Skin contact: Eye contact: Ingestion: Specific effects: Dust may irritate throat and respiratory system and cause coughing. May irritate. Dust in the eyes will cause irritation. Risk of corneal damage. Irritating. May cause nausea, stomach pain and vomiting. LD50 (oral, rat): 300 mg/kg for Copper(II) sulfate pentahydrate This product contains no ingredient listed on the NTP, OSHA or IARC carcinogen lists.
6/8 SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Ecotoxicity: 12.2. Persistence and degradability Degradability: 12.3. Bioaccumulative potential Bioaccumulative potential: 12.4. Mobility in soil Mobility: 12.5. Results of PBT and vpvb assessment PBT/vPvB: 12.6. Other adverse effects Other adverse effects: The product is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 0,01 < EC50 0,1 mg/l (Copper(II) sulfate pentahydrate) The product solely consists of inorganic compounds which are not biodegradable. No data available on bioaccumulation. The product is water soluble and may spread in water systems. No data available. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Dispose of waste and residues in accordance with local authority requirements. Waste is classified as hazardous waste. Waste from residues: EWC-code: 16 05 06
7/8 14. SECTION 14: TRANSPORT INFORMATION 14.1. UN number UN-No: 3077 14.2. UN proper shipping name Proper Shipping Name: 14.3. Transport hazard class(es) Class: 9 14.4. Packing group PG: 14.5. Environmental hazards Marine pollutant: Environmentally Hazardous substance: 14.6. Special precautions for user Special precautions: 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Transport in bulk: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Copper(II) sulfate pentahydrate) III Yes Yes SECTION 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Specific provisions: National regulation: National specific regulation may apply. Europe/USA: 15.2. Chemical Safety Assessment This Material Safety Data Sheet has been prepared according to the EUregulation. The following lists and legislation have been checked: Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and Directive 91/689/EEC on hazardous waste with amendments. Threshold Limit Values (2010), ACGIH, by the American Conference on Governmental Industrial Hygienists. The Code of Federal Regulation, Title 29, part 1910. Occupational Safety and Health Standards, Air contaminants (OSHA), with amendments. U.S. Department of health and human services: 2005 - Report on Carcinogens - 11th Edition. International Agency for Research on Cancer (IARC): IARC Monographs on the Evaluation of Carcinogenic Risks to Humans. Lyon: IARC, World Health Organization. CSA status:
8/8 SECTION 16: OTHER INFORMATION The user must be instructed in the proper work procedure and be familiar with the contents of these instructions. The following sections contain revisions or new statements:1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15. Additional information: - R22 Harmful if swallowed. R36/38 Irritating to eyes and skin. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information on this data sheet represents our current data and is reliable provided that the product is used under the prescribed conditions and in accordance with the application specified on the packaging and/or in the technical guidance literature. Any other use of the product which involves using the product in combination with any other product or any other process is the responsibility of the user. Made by DHI - Environment and Toxicology, Agern Allé 5, DK-2970 Hørsholm, Denmark. www.dhigroup.com.