Date of issue: 19/05/2014 Revision date: 30/12/2014 : Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Synonyms : Mixture : : Derwent Pencils and Colour Sticks Accessories, Aquatone, Artbar, Artists, Charcoal Pencils, Coloursoft, Compressed Charcoal, Drawing Pencils, Hard Back Sketch Books, Inktense, Inktense Blocks, Journals, Metallic Pencils, Natural Graphite, ONYX, Pastel Pencils, Pastels, Sketching, Studio, Tinted Charcoal, Watercolour, Watersoluble Graphitone, Watersoluble Sketching, Willow, XL Product code : 0700049, 0700050, 0700051, 0700052, 0700053, 0700054, 0700055, 0700077, 0700078, 0700101, 0700108, 0700111, 0700114, 0700120, 0700122, 0700125, 0700129, 0700133, 0700135, 0700136, 0700138, 0700143, 0700146, 0700148, 0700149, 0700150, 0700154, 0700156, 0700158, 0700163, 0700165, 0700167, 0700172, 0700173, 0700174, 0700211, 0700212, 0700229, 0700230, 0700231, 0700232, 0700233, 0700234, 0700253, 0700254, 0700255, 0700256, 0700257, 0700258, 0700259, 0700260, 0700267, 0700269, 0700284, 0700286, 0700300, 0700301, 0700302, 0700303, 0700304, 0700307, 0700434, 0700449, 0700456, 0700473, 0700476, 0700481, 0700482, 0700528, 0700624, 0700643, 0700644, 0700659, 0700660, 0700662, 0700663, 0700664, 0700665, 0700666, 0700667, 0700671, 0700672, 0700674, 0700675, 0700676, 0700677, 0700678, 0700679, 0700680, 0700681, 0700682, 0700683, 0700684, 0700685, 0700686, 0700687, 0700688, 0700689, 0700690, 0700691, 0700758, 0700759, 0700821, 0700822, 0700830, 0700836, 0700837, 0700838, 0700862, 0700866, 0700885, 0700903, 0700904, 0700905, 0700906, 0700907, 0700908, 0700909, 0700910, 0700911, 0700912, 0700913, 0700914, 0700915, 0700916, 0700917, 0700918, 0700919, 0700920, 0700921, 0700922, 0700923, 0700924, 0700925, 0700926, 0700927, 0700928, 0700929, 0700930, 0700953, 0700954, 0700955, 0700956, 0700957, 0700958, 0700959, 0700960, 0700961, 0700962, 0700963, 0700964, 0700965, 0700966, 0700967, 0700968, 0700969, 0700970, 0700971, 0700972, 0700973, 0700974, 0700975, 0700976, 0700977, 0700978, 0700979, 0700980, 0700981, 0700982, 0700983, 0700984, 0700985, 0700986, 0700987, 0700988, 0700989, 0700990, 0700991, 0700992, 0700993, 0700994, 0700995, 0700996, 0700997, 0700998, 0700999, 0701000, 0701001, 0701002, 0701003, 0701004, 0701005, 0701006, 0701007, 0701008, 0701009, 0701010, 0701011, 0701012, 0701013, 0701014, 0701015, 0701016, 0701017, 0701018, 0701019, 0701020, 0701021, 0701022, 0701023, 0701024, 0701025, 0701026, 0701027, 0701028, 0701029, 0701030, 0701031, 0701035, 0701039, 0701070, 0701071, 0701089, 2101403, 2101404, 2102174, 2102175, 2102176, 2102177, 2102178, 2102179, 2300023, 2300037, 2300038, 2300039, 2300040, 2300046, 2300077, 2300078, 2300079, 2300080, 2300081, 2300083, 2300086, 2300087, 2300088, 2300089, 2300090, 2300091, 2300123, 2300123A, 2300124, 2300138, 2300139, 2300140, 2300141, 2300142, 2300143, 2300147, 2300151, 2300152, 2300153, 2300154, 2300155, 2300161, 2300172, 2300173, 2300174, 2300179, 2300185, 2300217, 2300219, 2300225, 2300226, 2300230, 2300231, 2300232, 2300233, 2300234, 2300235, 2300236, 2300237, 2300238, 2300239, 2300240, 2300241, 2300242, 2300243, 2300244, 2300245, 2300246, 2300247, 2300248, 2300249, 2300250, 2300251, 2300252, 2300253, 2300254, 2300255, 2300256, 2300257, 2300258, 2300259, 2300260, 2300261, 2300262, 2300263, 2300264, 2300265, 2300266, 2300267, 2300268, 2300269, 2300270, 2300271, 2300272, 2300273, 2300274, 2300275, 2300276, 2300277, 2300278, 2300279, 2300280, 2300281, 2300282, 2300283, 2300284, 2300285, 2300286, 2300287, 2300288, 2300289, 2300290, 2300291, 2300292, 2300293, 2300294, 2300295, 2300296, 2300297, 2300298, 2300299, 2300300, 2300301, 2300303, 2300304, 2300305, 2300306, 2300307, 2300308, 2300309, 2300310, 2300311, 2300312, 2300313, 2300314, 2300315, 2300316, 2300317, 2300318, 2300319, 2300320, 2300321, 2300322, 2300323, 2300324, 2300325, 2300326, 2300327, 2300328, 2300329, 2300330, 2300331, 2300332, 2300333, 2300334, 2300335, 2300336, 2300337, 2300338, 2300339, 2300340, 2300343, 2300352, 2300355, 2300357, 2300365, 2300366, 2300367, 2300368, 2300369, 2300370, 2300371, 2300372, 2300373, 2300374, 2300375, 2300376, 2300377, 2300379, 2300381, 2300382, 2300386, 2300406, 2300411, 2300412, 2300418, 2300419, 2300420, 2300421, 2300422, 2300423, 2300424, 2300425, 2300426, 2300427, 2300428, 2300429, 2300430, 2300431, 2300432, 2300433, 2300434, 2300435, 2300436, 2300437, 2300438, 2300439, 2300440, 2300441, 2300442, 2300443, 2300448, 2300449, 2300450, 2300451, 2300452, 2300454, 2300456, 2300457, 2300467, 2300468, 2300469, 2300470, 2300506, 2300541, 2300544, 2300561, 2300563, 2300575, 2300580, 2300582, 2300587, 2300588, 2300589, 2300590, 2300591, 2300592, 2300593, 2300594, 2300595, 2300596, 2300597, 2300598, 2300599, 2300600, 2300601, 2300602, 2300603, 2300604, 2300605, 2300606, 2300607, 2300608, 2300609, 2300610, 2300611, 2300612, 2300613, 2300614, 2300615, 2300616, 2300617, 2300618, 2300619, 2300620, 2300621, 2300622, 2300623, 2300624, 2300625, 2300626, 2300627, 2300628, 2300629, 2300630, 2300631, 2300632, 2300633, 2300634, 2300635, 2300636, 2300637, 2300638, 2300639, 2300640, 2300641, 2300642, 2300643, 2300644, 2300645, 2300646, 2300647, 2300648, 2300649, 2300650, 2300651, 2300652, 2300653, 2300654, 2300655, 2300656, 2300657, 2300658, 2300659, 2300660, 2300661, 2300662, 2300663, 2300664, 2300665, 2300666, 2300667, 2300671, 2300672, 2300675, 2300678, 2300679, 2300680, 2300681, 2300682, 2300683, 2300685, 2300686, 2300687, 2300688, 2301597, 2301598, 2301607, 2301608, 2301610, 2301611, 2301650, 2301660, 2301665, 2301666, 30/12/2014 EN (English) 1/7
2301667, 2301668, 2301669, 2301670, 2301671, 2301672, 2301673, 2301674, 2301675, 2301676, 2301677, 2301678, 2301679, 2301680, 2301681, 2301682, 2301683, 2301684, 2301685, 2301688, 2301689, 2301690, 2301691, 2301698, 2301699, 2301700, 2301711, 2301712, 2301735, 2301756, 2301757, 2301758, 2301760, 2301760A, 2301774, 2301842, 2301843, 2301844, 2301852, 2301853, 2301854, 2301855, 2301856, 2301857, 2301858, 2301859, 2301860, 2301861, 2301862, 2301863, 2301864, 2301865, 2301866, 2301867, 2301868, 2301869, 2301870, 2301871, 2301872, 2301873, 2301874, 2301875, 2301876, 2301877, 2301878, 2301879, 2301880, 2301881, 2301882, 2301883, 2301884, 2301885, 2301886, 2301887, 2301888, 2301889, 2301890, 2301891, 2301892, 2301893, 2301894, 2301895, 2301896, 2301897, 2301898, 2301899, 2301902, 2301915, 2301917, 2301919, 2301920, 2301930, 2301931, 2301932, 2301933, 2301934, 2301936, 2301937, 2301938, 2301940, 2301941, 2301942, 2301944, 2301945, 2301946, 2301947, 2301952, 2301953, 2301954, 2301955, 2301958, 2301962, 2301963, 2301964, 2301965, 2301966, 2301969, 2301970, 2301971, 2301972, 2301974, 2301975, 2301976, 2301977, 2301978, 2301979, 2301980, 2301981, 2301982, 2301984, 2301985, 2301990, 2301991, 2301995, 2301996, 2302000, 2302001, 2302003, 2302004, 2302009, 2302010, 2302011, 2302012, 2302013, 2302014, 2302015, 2302016, 2302017, 2302018, 2302019, 2302020, 2302021, 2302022, 2302023, 2302024, 2302025, 2302026, 2302028, 2302029, 2302030, 2302031, 2302032, 2302033, 2302034, 2302035, 2302036, 2302037, 2302038, 2302039, 2302040, 2302041, 2302042, 2302043, 2302044, 2302045, 2302046, 2302047, 2302048, 2302049, 2302050, 2302051, 2302052, 2302053, 2302054, 2302055, 2302056, 2302057, 2302058, 2302059, 2302060, 2302061, 2302062, 2302063, 2302064, 2302065, 2302066, 2302067, 2302068, 2302069, 2302070, 2302071, 2302072, 2302073, 2302074, 2302075, 2302076, 2302077, 2302078, 2302079, 2302080, 2302081, 2302082, 2302083, 2302084, 2302093, 2302100, 2302101, 2302102, 2302104, 2302107, 2302108, 2302109, 2302110, 2302111, 2302112, 2302113, 2302114, 2302115, 2302116, 2302117, 2302118, 2302120, 2302123, 2302124, 2302125, 2302126, 2302127, 2302140, 2302141, 2302143, 2302147, 2302148, 2302149, 2302151, 2302152, 2302153, 2302154, 2302155, 2302156, 2302157, 2302167, 2302169, 2302170, 2302172, 2302173, 2302174, 2302175, 2302177, 2302178, 2302179, 2302180, 2302181, 2302182, 2302183, 2302184, 2302185, 2302186, 2302187, 2302188, 2302189, 2302193, 2302266, 2302283, 2302284, 2302288, 2302289, 2302290, 3200000, 3200100, 3200200, 3200300, 3200400, 3200410, 3200500, 3200510, 3200600, 3200700, 3200800, 3200900, 3201000, 3201100, 3201200, 3201300, 3201400, 3201410, 3201500, 3201600, 3201610, 3201620, 3201630, 3201700, 3201800, 3201810, 3201900, 3201910, 3202000, 3202100, 3202110, 3202120, 3202200, 3202210, 3202220, 3202300, 3202400, 3202410, 3202500, 3202600, 3202700, 3202800, 3202810, 3202820, 3202830, 3202840, 3202900, 3203000, 3203100, 3203200, 3203300, 3203400, 3203500, 3203600, 3203610, 3203620, 3203700, 3203710, 3203800, 3203900, 3204000, 3204100, 3204110, 3204120, 3204130, 3204140, 3204150, 3204200, 3204300, 3204400, 3204500, 3204600, 3204700, 3204800, 3204900, 3205000, 3205010, 3205100, 3205110, 3205120, 3205130, 3205140, 3205150, 3205160, 3205200, 3205300, 3205310, 3205400, 3205500, 3205600, 3205700, 3205710, 3205720, 3205800, 3205900, 3206000, 3206100, 3206200, 3206300, 3206400, 3206410, 3206420, 3206430, 3206440, 3206450, 3206460, 3206470, 3206480, 3206490, 3206500, 3206600, 3206610, 3206700, 3206800, 3206900, 3206910, 3207000, 3207100, 3207110, 3207200, 32089, 32092, 32093, 32096, 32097, 32098, 32101, 32102, 32103, 32104, 32105, 32106, 32107, 32108, 32109, 32110, 32111, 32112, 32113, 32114, 32115, 32116, 32117, 32118, 32119, 32120, 32121, 32122, 32123, 32124, 32125, 32126, 32127, 32128, 32129, 32130, 32131, 32132, 32133, 32134, 32135, 32136, 32137, 32138, 32139, 32140, 32141, 32142, 32143, 32144, 32145, 32146, 32147, 32148, 32149, 32150, 32151, 32152, 32153, 32154, 32155, 32156, 32157, 32158, 32159, 32160, 32161, 32162, 32163, 32164, 32165, 32166, 32167, 32168, 32169, 32170, 32171, 32172, 32196, 32197, 32198, 32199, 32201, 32801, 32802, 32803, 32804, 32805, 32806, 32807, 32808, 32809, 32810, 32811, 32812, 32813, 32814, 32815, 32816, 32817, 32818, 32819, 32820, 32821, 32822, 32823, 32824, 32825, 32826, 32827, 32828, 32829, 32830, 32831, 32832, 32833, 32834, 32835, 32836, 32837, 32838, 32839, 32840, 32841, 32842, 32843, 32844, 32845, 32846, 32847, 32848, 32849, 32850, 32851, 32852, 32853, 32854, 32855, 32856, 32857, 32858, 32859, 32860, 32861, 32862, 32863, 32864, 32865, 32866, 32867, 32868, 32869, 32870, 32871, 32872, 32881, 32883, 32885, 32889, 32891, 32991, 32992, 32996, 33254, 33255, 33301, 33302, 33303, 33304, 33305, 33306, 33307, 33308, 33309, 33310, 33312, 33317, 33326, 33328, 33329, 33356, 34122, 34132, 34138, 34251A, 34252A, 34253A, 34264A, 34301, 34302, 34303, 34304, 34305, 34306, 34307, 34320, 34322, 34324, 34326, 34328, 34330, 34332, 34341, 34342, 34343, 34344, 34345, 34350, 34357, 34358, 34359, 34386, 34387, 34388, 34389, 34391, 34392, 35985, 35986, 35987, 35988, 35996, 35997, 35998, 35999, 36001, 36002, 36003, 36004, 36005, 36300, 36301, 36302, 36303, 39000, 39003, 39007, 39008, 39009, 90649, 90702 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category Use of the substance/mixture : Consumer use,professional use : For writing purposes 30/12/2014 EN (English) 2/7
1.2.2. Uses advised against 1.3. Details of the supplier of the safety data sheet Acco UK Ltd. Oxford House, Oxford Road, Aylesbury, Bucks, HP21 8SZ. Telephone: +44 (0) 844 209 8360 (9am to 5pm) Fax: +44 (0) 845 603 1731 Website: Email: informationeurope@acco.com 1.4. Emergency telephone number Emergency number : 0844 2098360 Country Organisation/Company Address Emergency number IRELAND (REPUBLIC OF) UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Centre Beaumont Hospital National Poisons Information Service (NHS Direct) 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] No labelling applicable 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Beaumont Hospital Beaumont Road 9 Dublin This mixture does not contain any substances to be mentioned according to the criteria of section 3.2 of REACH annex II SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : +353 1 8379964 0845 4647 or 111 (England & Wales only) or 112 (EU) or 08454 24 24 24 (Scotland) : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. : Not expected to present a significant hazard under anticipated conditions of normal use. 30/12/2014 EN (English) 3/7
4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if substance enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store aways from other materials. 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Keep container closed when not in use. Keep only in the original container in a cool, well ventilated place away from : Direct sunlight, Heat and ignition sources. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Sources of ignition. Direct sunlight. 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Provide adequate general and local exhaust ventilation. : Protective goggles. Gloves. Hand protection Eye protection : Wear protective gloves. : Chemical goggles or safety glasses. 30/12/2014 EN (English) 4/7
Respiratory protection : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Colourless. Odour : odourless. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) : Non flammable Vapour pressure Relative vapour density at 20 C Relative density Solubility : insoluble in water. Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties : not explosive. Oxidising properties : not oxidising. Explosive limits 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation 30/12/2014 EN (English) 5/7
Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms :. SECTION 12: Ecological information 12.1. Toxicity 12.2. Persistence and degradability Derwent Pencils and Colour Sticks Persistence and degradability 12.3. Bioaccumulative potential Derwent Pencils and Colour Sticks Bioaccumulative potential 12.4. Mobility in soil 12.5. Results of PBT and vpvb assessment 12.6. Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / IMDG / IATA / ADN 14.1. UN number Not dangerous goods in terms of transport regulations 14.2. UN proper shipping name 14.3. Transport hazard class(es) 14.4. Packing group 14.5. Environmental hazards : No supplementary information available. 30/12/2014 EN (English) 6/7
14.6. Special precautions for user 14.6.1. Overland transport 14.6.2. Transport by sea 14.6.3. Air transport 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations No REACH Annex XVII restrictions 15.1.2. National regulations 15.2. Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixturejs, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. SDS EU ACCO This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 30/12/2014 EN (English) 7/7