Integrated ISRU for Human Exploration Propellant Production for the Moon and Beyond

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Integrated ISRU for Human Exploration Propellant Production for the Moon and Beyond D. Larry Clark, Lockheed Martin - Principal Investigator Kevin Payne, Lockheed Martin Dr. Brejendra Mishra, Colorado School of Mines Bob Gustafson, Orbital Technologies, Inc. International Lunar Conference 2005 9/20/2005 Performed under NASA Contract NNJ05HB57C

Overview Resource collection Oxygen production Oxygen storage Target Mission: Initial Human exploration missions Technology Testbed initially Provide Oxidant and breathing O2 Implemented in a series of test bed missions that have residual value

Program Goals End to End System Excavation to LOX Storage Provide a capability for oxygen production from lunar regolith TRL 6 Demonstrate production of oxygen at rates that support human life support Demonstrate critical hardware in relevant environments Provide mission designers a validated set of implementation criteria

Initial Production System Targets 4 kg LOX per 24 hours, minimum 8 kg LOX per 24 hours target 400 kg system mass Includes Excavators; power production; LOX storage Power <3 kwatt Operational life > 2 years Storage capacity - 300kg Production only during sunlit periods, hibernate during lunar night

Implementation Assumptions System will land on Lunar Mare Power system will be lightweight solar 150 W/kg Would correspond to 20 kg for 3 kw Solar collectors for thermal power is under consideration

Initial Mass Allocations 400 kg Initial System Mass Allocation Power Generation 50kg Regolith Excavator 80kg Oxygen Production 140kg LOX Storage 100kg Margin 20kg

Regolith Collection Baseline Concept: One excavator w/ dump bed Bucket Wheel Excavator Inverted Auger regolith transport Beneficiation Currently only planning to sieve larger rocks Trade study to be performed on other excavation methods DP036-370 DP036-084

Regolith Excavator Bucket Wheel Baseline 50 kg per hour Greatly exceeds reactor requirements Idle time allows robot to haul and dispose of refuse Robotic Platform Not a prime focus of this program Will leverage ongoing activities Use in-house lab robots Excavate in large area with lunar simulant

Task Planning Will leverage ongoing and existing body of knowledge Robot will use preset routes for excavation and disposal Autonomously navigate from lander to disposal area Autonomously navigate from disposal area to predetermined excavation area Leading to functional demonstration Full scale mockup of Phoenix class lander with targets added 10 meter distance to excavation area Obstacle avoidance during traverse

Regolith Collection Challenges Bearings, lifetime, loads, complexity Dust mitigation Power consumption Power Source While not a prime focus of this program, we need to know the energy required for operations Regolith properties The handling of granular materials in reduced gravity is not well understood

Oxygen Production Three methods for initial investigation Hydrogen Reduction Carbothermal Reduction Molten Salt Electrolysis Methods will be compared for effectiveness at end of first year leading to selection of preferred methods

Hydrogen Reduction MV101 MV102 Radiator Reactor Vessel F101 SV101 P301 HX301 HX101 Dust Removal Gas Exchange Probe P101 HX102 FCV301 FCV302 P102 BPR202 HX201 SV201 SV103 BPR201 ELX201 D201 Water Chem P201 T201 P202 D. L. Clark 3/8/2005

Hardware Implementation Reactor Detail Pressure vessel Gate valves Seals pressure vessel Rotating reactor chamber (mixer) Solar concentrator fiber optic heaters

Concept of Operations Oxygen Production - Subsystems 2 3 1 4 Water vapor collection process: Step 1: H2 gas from tank pumped into reactor Step 2: Hydrogen reduction within reactor Step 3: Water vapor leaves reactor, enters heat exchanger Step 4: Water condenses in hydrogen tank Step 5: Water enters treatment plant 5

Concept of Operations Oxygen Production - subsystems Water vapor collection process: 7 Step 6: treated water flows through pressure boost pump into electrolyzer circulation tank Step 7: H2 gas driven through solenoids to run boost pump, vents to large Hydrogen tank 6

Concept of Operations Oxygen Production - subsystems 10 Water processing: Step 8: Water flows from circulation tank through circ pump into electrolyzer 9 Step 9: Water and H2 gas return to circ tank 8 Step 10: O2 gas flows to dryer and LOX tank

Hydrogen Reduction Challenges Regolith Handling Storage, feed hoppers Waste removal Thermal Control Need high efficiency heat exchanger Beneficiation- Is there a way to improves yields by treating the raw regolith Hydrogen Recycle Water Handling and Purification Hydrogen Losses and makeup Solar implanted hydrogen may leave us with net gain in hydrogen Removal of inert gases

Carbothermal Reduction Overview The carbothermal reduction process extracts oxygen from lunar regolith through the carbon reduction of silicon, iron, and titanium oxides By reducing the silicon, iron, and titanium oxides, over 28% of the bulk mass of the JSC-1 lunar regolith simulant mass can potentially be extracted as oxygen SiO 2 = 25.4mass% FeO = 2.1mass% Fe 2 O 3 = 1.0mass% TiO 2 Ti 2 O 3 = 0.2mass% Processing is achieved through the use of methane gas, providing a simple way to produce oxygen by handling only gases and water, with minimal separation techniques necessary Thermal compatibility issues with regolith containers are solved by using the regolith as its own processing container Lunar regolith has a very low thermal conductivity of 0.0172 0.0295 W/mK

Carbothermal Reduction Overview The baseline carbothermal reduction process has three basic steps Step 1. Reduction of Metallic Oxides MO x + CH 4 CO + 2H 2 + M (processing temperature of >1625 C) Step 2. Methanation Process CO + 3H 2 CH 4 + H 2 O (processing temperature of ~250 C) Step 3. Water Electrolysis 2H 2 O 2H 2 + O 2 Together, these processing steps can form a nearly closed-loop system Slag By-products Lunar Silicates CH 4 Metal Oxide Reduction Metals Silicon CO Carbon Oxide Reduction H 2 O Water Reduction O 2 Oxygen Liquifier Lunar LO 2 Step 1 Step 2 Step 3 H 2 CH 4 H 2

Carbothermal Reduction Hardware Regolith Hopper Inlet Valve Gas Storage Tanks Regolith Hopper Methanation Packed Bed Reactor Regolith Feed Drive Motor Gas Transfer Equipment Regolith Feed System Carbothermal Reduction Reactor

Carbothermal Reduction Challenges Material Heating Current plans will use concentrated solar energy Product release CO bubbles trapped in spent material Material Handling Material Disposal Thermal Control Methane losses and makeup

Molten Salt Reduction Electrochemical Reduction in conductive molten salt Use of lunar regolith as a solid (powder or pressed pellet) cathode in an inert molten halide with production of oxygen on an inert anode LiCl-KCl [60-40 mol. pct.] 375 C NaCl-KCl [50-50 mol. pct.] 650 C CaCl2 850 C

Subsystem Overview The subsystem using molten salt extraction is being adopted using two fundamentally different schemes: 1.Use of lunar regolith as a solid (powder or pressed pellet) cathode in an inert molten halide with production of oxygen on an inert anode Process Variables: salt constituents and temperature System Variables: cathode container (powder or pellet), suspended pellet 2.Use of partial lunar regolith as dissolved species in an inert molten halide with production of oxygen on an inert anode Process requirements: filtration of undissolved regolith

Hardware Implementation Test Reactor

Molten Salt Reduction Challenges Material Handling Salt recovery Losses and makeup Oxygen recovery and purification Refuse disposal Thermal Control

Cryogenic Oxygen Storage Baseline design: Pulse tube cryocooler liquefaction 300 kg storage tank Self pressurization for outflow

System Schematic Radiator HX702 Oxygen Inlet 400 psia Precooler P702 Pulse Tube Coldhead HX501 He Line SV601 HX701 RV601 PR601 SV602 Pressurization Charge Tank P701 Cryocooler Compressor T601 MLI Structural Supports SV603 SV502 Liquid Outlet

Hardware Implementation Cryocooler Compressor Cold Head LOx storage tank (300kg capacity) Dryer GOx line from electrolyzer LOx outflow port

Pulse Tube Cold Head Characteristics The cold head has no moving parts Minimal vibration Eliminates motor or pneumatics for phase control with compressor No wear out or failure mechanisms (except working gas leakage) No tight tolerance components Simple, reliable and light weight Well proven, predictable design

PILOT Cryocooler Coldhead PILOT based on well established single stage Cold-head Warm Flange 2 L Pulse Tube 1 Regenerator Syste m Weigh t (Kg) L (mm) 1 (mm) 2 (mm) Cold Tip Interface DEPO T PILOT 4 1.4 140 110 165 80 400 140

Cryocooler Compressor Compressor is high reliability design without any wear out mechanisms (design life of 10 year is common) Utilizes linear (voice coil) type motor for piston drive Two motors drive pistons in opposition to provide pressure wave and minimize vibration (momentum cancellation) Clearance seals between piston and cylinder eliminate wear, produce negligible gas leakage Flexures operating below infinite stress levels provide piston alignment, allow compression/expansion stroke Advanced moving magnet motor utilized Result is light weight, reliable, efficient compressor

PILOT Cryocooler Compressors PILOT compressors are baselined to utilized the M5 motors M4 Compressors shown (M5 similar in physical size) M5 MIDI: (PILOT Tank) Weight 4.7 Kg Physical size - L: 252mm :119mm M5 MEGA: (DEPOT Tank) Weight - 16 Kg Physical size - L: 410mm :165mm

Baseline Cryocooler for PILOT Following plot shows cooling capacity up to ambient temperature 90 80 Oxygen Liquefier Cooling Power (W) 70 60 50 40 30 20 10 0 - M5MIDI Compressor - 300K heat rejection - 240W Compressor Electrical Power 50 100 150 200 250 300 350 Cold Tip Temperature (K) Assumptions: M5MIDI Compressor 300 mm separation between compressor and coldhead

Cryogenic Oxygen Storage Challenges Thermal control Tank Insulation Heat rejection Power draw System mass

Impact to Exploration Architecture For 1000 kg System Basis Reduce Landed Propellant Mass 2.2 metric tonnes LOX produced enables option to Deliver 2.2 tonnes additional cargo to lunar surface Reduce earth launch mass by 15 tonnes Reduce Earth Launch Mass by 15 tonnes Launch cost savings of $165 million @ $5 K/lb Mass-mT 25 20 15 10 5 0 $0 3 10 100 50 500 Mission duration-days DP036-736 Potential mission cost reductions with ISRU supplied oxygen 45 $350 40 Earth launched mass Total oxygen mass $300 35 Breathing oxygen mass 30 Ascent vehicle propellant $250 Mission cost reduction $200 $150 $100 $50 Cost reduction per mission