APFCXXX-MAA100 Date of issue: 05/27/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : M/A Cyclone Powder Floor Cleaner : APFCXXX-050-001 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.3. Details of the supplier of the safety data sheet M/A Associates P.O. Box 4336 St Paul, MN 55104 - USA T 651-227-8901 1.4. Emergency telephone number Emergency number : 651-227-8901 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Corr. 1A Eye Dam. 1 STOT SE 3 Full text of H-phrases: see section 16 H314 H318 H335 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Danger GHS05 GHS07 : H314 - Causes severe skin burns and eye damage H318 - Causes serious eye damage H335 - May cause respiratory irritation : P260 - Do not breathe dust P261 - Avoid breathing dust P264 - Wash clothing, hands, forearms and face thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P280 - Wear eye protection, face protection, protective clothing, protective gloves P301+P330+P331 - If swallowed: rinse mouth. Do NOT induce vomiting P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a doctor, a POISON CENTER P312 - Call a doctor, a POISON CENTER if you feel unwell P363 - Wash contaminated clothing before reuse P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 Page 1
SECTION 3: Composition/information on ingredients 3.1. Substance 3.2. Mixture Name Product identifier % Classification (GHS-US) Sodium Carbonate (CAS No) 497-19-8 20-50 Skin Corr. 1A, H314 Eye Dam. 1, H318 Sodium Metasilicate (CAS No) 6834-92-0 20-50 Skin Corr. 1A, H314 Eye Dam. 1, H318 STOT SE 3, H335 Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a poison center or doctor/physician. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after eye contact : Causes serious eye damage. 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapors. 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 2/7
6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact during pregnancy/while nursing. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. : Wash... thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Comply with applicable regulations. : Keep only in the original container in a cool, well ventilated place away from : Keep container tightly closed. : Strong bases. Strong acids. SECTION 8: Exposure controls/personal protection 8.1. Control parameters M/A Cyclone Powder Floor Cleaner ACGIH OSHA ACGIH OSHA ACGIH : Sources of ignition. Direct sunlight. OSHA 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection Eye protection Skin and body protection Respiratory protection : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Color : Yellow Odor : characteristic Odor threshold ph ph solution : 12.4 (2%) Melting point Freezing point Boiling point Flash point 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 3/7
Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) Explosion limits Explosive properties Oxidizing properties Vapor pressure Relative density Relative vapor density at 20 C Solubility : Water: Solubility in water of component(s) of the mixture : : 22 g/100ml : > 18 g/100ml : : Log Pow Log Kow Auto-ignition temperature Decomposition temperature Viscosity Viscosity, kinematic Viscosity, dynamic 9.2. SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapors. 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapors. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rabbit ATE US (oral) LD50 dermal rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) 2800 mg/kg (Rat; Experimental value) > 2000 mg/kg (Rabbit; Experimental value) 2800.000 mg/kg body weight > 5000 mg/kg body weight (Rat; Read-across; OECD 402: Acute Dermal Toxicity) : Causes severe skin burns and eye damage. : Causes serious eye damage. : May cause respiratory irritation. 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 4/7
Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after eye contact : Based on available data, the classification criteria are not met. : May cause respiratory irritation. : Causes serious eye damage. SECTION 12: Ecological information 12.1. Toxicity LC50 fish 1 EC50 Daphnia 1 EC50 other aquatic organisms 1 LC50 fish 2 EC50 Daphnia 2 TLM fish 1 TLM other aquatic organisms 1 Threshold limit algae 1 LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 Threshold limit algae 1 300 mg/l (96 h; Lepomis macrochirus) < 424 mg/l (48 h; Daphnia magna) 14 mg/l (168 h; Plankton) 740 mg/l (96 h; Gambusia affinis) 265 mg/l (48 h; Daphnia magna) 300 ppm (96 h; Lepomis macrochirus) 500 ppm (96 h; Daphnia magna) 242 mg/l (5 days; Algae) 210 mg/l (96 h; Brachydanio rerio) 216 mg/l (96 h; Daphnia magna; GLP) 2320 mg/l (96 h; Gambusia affinis) 632 mg/l (96 h; Lymnaea sp.) 207 mg/l (72 h; Scenedesmus subspicatus; GLP) 12.2. Persistence and degradability M/A Cyclone Powder Floor Cleaner Persistence and degradability Persistence and degradability ThOD Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. Low potential for adsorption in soil. (inorganic) Biodegradability: not applicable. No (test)data on mobility of the substance available. 12.3. Bioaccumulative potential M/A Cyclone Powder Floor Cleaner Bioaccumulative potential Log Pow -6.19 (Estimated value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 5/7
: Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport by sea Air transport SECTION 15: Regulatory information 15.1. US Federal regulations Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations 15.3. US State regulations SECTION 16: : None. 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 6/7
Full text of H-phrases: ------ Eye Dam. 1 Serious eye damage/eye irritation Category 1 ------ Skin Corr. 1A Skin corrosion/irritation Category 1A ------ STOT SE 3 Specific target organ toxicity (single exposure) Category 3 ------ H314 Causes severe skin burns and eye damage ------ H318 Causes serious eye damage ------ H335 May cause respiratory irritation SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 06/19/2015 EN (English US) SDS ID: APFCXXX-MAA100 7/7