MATERIAL SAFETY DATA SHEET 1. Product and Company Identification Product name CAS # Product use Manufacturer ECOWATER Distiller Cleaner Mixture Water Processing Equipment Cleaner Pro Products LLC 721 Engle Road Fort Wayne, IN 4684-5875 US Phone 26-483-2519 Emergency Phone: 1-8-424-93 (CHEMTREC) Severe Serious Moderate Slight Minimal LEGEND 4 3 2 1 HEALTH FLAMMABILITY PHYSICAL HAZARD PERSONAL PROTECTION / 3 X 3 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA regulatory status 2. Hazards Identification DANGER MAY CAUSE CHEMICAL BURNS TO EYES AND SKIN. Eye, Skin contact, Inhalation, Ingestion. May cause chemical burns. May cause blindness. May cause chemical burns. Potential environmental effects See section 12. May cause respiratory tract irritation. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Eyes. Skin. Mucous membranes. Prolonged or repeated exposure can cause drying, defatting and dermatitis. The product may cause burns to eyes, skin and mucous membranes. This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. 3. Composition/Information on Ingredients Components CAS # Percent Citric acid Sulfamic Acid 4. First Aid Measures 77-92-9 3-6 5329-14-6 3-6 First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician Immediately flush with cool water. Remove contact lenses, if applicable, and continue flushing for 15 minutes. Obtain medical attention immediately. Brush away excess of dry material. Immediately flush with cool water for 15 minutes. Obtain medical attention if irritation persists. Wash contaminated clothing well before reuse or discard. If symptoms develop move victim to fresh air. If symptoms persist, obtain medical attention. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth if victim is unconscious, or is convulsing. Obtain medical attention. #288 Page: 1 of 6
General advice If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Avoid contact with eyes and skin. Keep out of reach of children. 5. Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment and precautions for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Not flammable by WHMIS/OSHA criteria. Carbon dioxide. Water spray. Dry chemical. Foam. Firefighters should wear a self-contained breathing apparatus. Firefighters should wear full protective clothing including self contained breathing apparatus. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 6. Accidental Release Measures Personal precautions Environmental precautions Methods for containment Methods for cleaning up Keep unnecessary personnel away. Do not touch or walk through spilled material. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Keep people away from and upwind of spill/leak. Do not discharge into lakes, streams, ponds or public waters. Prevent entry into waterways, sewers, basements or confined areas. Use water spray to reduce vapors or divert vapor cloud drift. Before attempting clean up, refer to hazard data given above. Use broom or dry vacuum to collect material for proper disposal without raising dust. Rinse area with water. Prevent large spills from entering sewers or waterways. Contact emergency services and supplier for advice. Large Spills: Wet down with water and dike for later disposal. After removal flush contaminated area thoroughly with water. 7. Handling and Storage Handling Storage Use good industrial hygiene practices in handling this material. Do not get in eyes, on skin or on clothing. Use only with adequate ventilation. Wash thoroughly after handling. Keep container tightly closed. Avoid breathing dust. Keep out of the reach of children. Store in a closed container away from incompatible materials. Exposure limits Engineering controls Personal protective equipment Eye / face protection Hand protection 8. Exposure Controls/Personal Protection Use only under good ventilation conditions or with respiratory protection. Wear chemical goggles. Rubber gloves. Confirm with a reputable supplier first. Skin and body protection As required by employer code. Rubber apron recommended. Respiratory protection General hygiene considerations Where exposure guideline levels may be exceeded, use an approved NIOSH respirator. Use good industrial hygiene practices in handling this material. When using do not eat or drink. Wash hands before breaks and immediately after handling the product. #288 Page: 2 of 6
9. Physical and Chemical Properties Appearance Color Form Odor Odor threshold Physical state ph Freezing point Boiling point Melting point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, upper, % by volume Flammability limits in air, lower, % by volume Vapor pressure Vapor density Specific gravity Partition coefficient (n-octanol/water) Solubility (water) Relative density Viscosity VOC Percent volatile Reactivity Possibility of hazardous reactions Chemical stability Conditions to avoid Incompatible materials Hazardous decomposition products Crystalline. Blue Solid Odorless Solid. 1.2-1.6 (1% solution) 1. Stability and Reactivity This product may react with reducing agents. May react with strong bases or oxidizing agents. Hazardous polymerization does not occur. Stable under recommended storage conditions. Do not mix with other chemicals. Caustics. Oxidizers. Bases. Reducing agents. May include and are not limited to: Oxides of carbon. Oxides of nitrogen. Oxides of sulfur. 11. Toxicological Information Toxicological data Components Citric acid (CAS 77-92-9) Acute Dermal LD5 Oral LD5 Species Rabbit Mouse Rat Test Results 5 mg/kg 54 mg/kg 3 mg/kg #288 Page: 3 of 6
Components LC5 Acute Oral LD5 Species Guinea pig Mouse Rat Test Results 15 mg/kg 1312 mg/kg 316 mg/kg Effects of acute exposure Eye contact Skin contact Inhalation Ingestion Sensitization Chronic effects Carcinogenicity Mutagenicity Reproductive effects Teratogenicity Name of Toxicologically Synergistic Products May cause chemical burns. May cause blindness. May cause chemical burns. May cause respiratory tract irritation. Harmful if swallowed. May cause chemical burns to mouth, throat and stomach. Not classified or listed by IARC, NTP, OSHA and ACGIH. 12. Ecological Information Ecotoxicity See below Ecotoxicological data Components Aquatic Fish LC5 Species Fathead minnow (Pimephales promelas) Test Results 14.2 mg/l, 96 hours Persistence and degradability Bioaccumulation / Accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information 13. Disposal Considerations Disposal instructions Waste from residues / unused products Contaminated packaging Review federal, state/provincial, and local government requirements prior to disposal. 14. Transport Information U.S. Department of Transportation (DOT) Basic shipping requirements: UN number UN1759 #288 Page: 4 of 6
Proper shipping name Corrosive solids, n.o.s. (Sulfamic Acid) Hazard class 8 Packing group III Special provisions 128, IB8, IP3, T1, TP33 Packaging exceptions 154 Packaging non bulk 213 Packaging bulk 24 Transportation of Dangerous Goods (TDG- Canada) Basic shipping requirements: UN number UN1759 Proper shipping name CORROSIVE SOLID, N.O.S. (Sulfamic Acid) Hazard class 8 Packing group III Special provisions 16 DOT TDG Canadian federal regulations Canada WHMIS Ingredient Disclosure: Threshold limits WHMIS status 15. Regulatory Information This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations. Citric acid (CAS 77-92-9) 1 % 1 % WHMIS classification WHMIS labeling Controlled Class E - Corrosive Material Occupational Safety and Health Administration (OSHA) 29 CFR 191.12 hazardous chemical US federal regulations Yes This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 191.12. TSCA Section 12(b) Export Notification (4 CFR 77, Subpt. D) #288 Page: 5 of 6
CERCLA Hazardous Substance List (4 CFR 32.4) Not listed. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (4 CFR 68.13) Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List CERCLA (Superfund) reportable quantity None Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories State regulations Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance Not listed. US - New Jersey RTK - Substances: Listed substance US - Texas Effects Screening Levels: Listed substance Citric acid (CAS 77-92-9) US. Massachusetts RTK - Substance List US. Pennsylvania RTK - Hazardous Substances US. Rhode Island RTK Inventory status Listed. Listed. Listed. Country(s) or region Inventory name On inventory (yes/no)* Canada Domestic Substances List (DSL) Yes Canada United States & Puerto Rico Non-Domestic Substances List (NDSL) Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) Disclaimer Issue date Effective date Expiry date 16. Other Information The data contained in this material safety data sheet was obtained from sources that were technically accurate, reliable, and state of the art when this document was prepared. If data was unavailable to complete certain sections, the absence of that data is identified in this document. Because the supplier cannot know the exact circumstances during actual use of this product, other hazards, exposure scenarios, disposal considerations, and regulations may apply and it is the responsibility of the user to read and understand the product label and this document before use. Do not use the product for purposes other than those stated in Section 1. 24-January-214 31-August-213 31-August-216 Prepared by Dell Tech Laboratories, Ltd. Phone: (519) 858-521 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document. No Yes #288 Page: 6 of 6