PROCESS SAFETY MANAGEMENT PROGRAM UNIPAR CARBOCLORO

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PROCESS SAFETY MANAGEMENT PROGRAM UNIPAR CARBOCLORO Clorosur Technical Seminar & WCC Safety Workshop Flávia Mariano Pinto November 18, 2016

Facility Cubatao, Sao Paulo -Brazil 1,000 metric tons chlorine/day In operation since April 1964 Products Chlorine Caustic soda Hydrogen Hydrochloric acid Sodium hypochlorite EDC

HES MANAGEMENT HES Principles Golden Rules Environmental aspects are included within the 17 major sections Occupational Safety and Health Program Process Safety Management Program

WHAT IS PSM PROGRAM? 1910.119 Process Safety Management of Highly Hazardous Chemicals Comprehensive management program that integrated technologies, procedures, and management practices. This section contains requirements for preventing or minimizing the consequences of catastrophic releases of toxic, reactive, flammable, or explosive chemicals. These releases may result in toxic, fire or explosion hazards. CCPS A management system that is focused on prevention of, preparedness for, mitigation of, response to, and restoration from catastrophic releases of chemicals or energy from a process associated with a facility. PREVENT

Let sexplore keypoints and plantpracticesin some elements...

SITE PLAN ELEMENT 1: SITE PLAN Explains and defines the facility s process safety management program. SitePlaniscomposedby: Technical Analysis Define covered areas (Ex: Chlorine, EDC, etc) HHC substances Lead to undesirable events Employee Participation Key point => Discipline, motivation, active participation Examples: Employee role on each elements Accident Prevention Committee(National Regulation- NR 5)

INFORMATION SHARING ELEMENT 2: INFORMATION SHARING Identifies how information will be made available while taking into consideration the company s trade secrets. Plantpractices Community: Open Plant Program, Unipar Carbocloro Community Council Associations: ABIQUIM, ABICLOR, FIESP, CIESP e CHLORINE INSTITUTE, etc Employeesand Contractors: Montlhy Safety Meeting(Ex: PSM) Incident Investigation Management of Change, etc

PROCESS SAFETY INFORMATION ELEMENT 3: PROCESS SAFETY INFORMATION Information to support the understanding and identification of hazards. Plant Process Safety Information Available to personnel involved in the process Information groups: Process Chemicals: Process Technology: Process Equipment: Operating Procedures (Electronic system)

PROCESS HAZARD ANALYSIS ELEMENT 4: PROCESS HAZARD ANALYSIS (PHA) Identification of potential hazardous situations, understanding of the hazard scenario, and perform risk evaluation. Plant procedure Review of: Design of existing facility, modifications, additions, new projects, incidents, etc Multidisciplinary team (Methodology + Process Expertise) Important aspects: Each part of the process Human factors, plant lay out, procedures, etc Checklists Layers of protection, Controls in place

PROCESS HAZARD ANALYSIS PHA plant practices: Methodology depends on the process (Hazop, What If, PHA, etc) QRA, Facility siting and consequence study are performed when required Recommendations: Risk Ranking (Matrix) Recommendations to MI Program Revalidation schedule PHA study and action plan presented to plant managers Share information Track recommendations Plant next steps: Working on method and frequency for revalidation based on the level of risk LOPA

MANAGEMENT OF CHANGE & PSSR ELEMENT 5: MANAGEMENT OF CHANGE (MOC) & PSSR Ensure changes to process are reviewed prior to implementation and do not inadvertently introduce new hazards or increase risk of existing hazards. Changes to a process must be thoroughly evaluated to fully assess their impact on employee safety and health and to determine needed changes to operating procedures. Plant Procedure: Define change Categories: Administrative, Procedures and Process (Examples) Except for Replacements in kind Types of Changes: Permanent, Emergency or Temporary Specific practices: Temporary repairs, temporary bypass, temporary impairments, etc MOC owner

MANAGEMENT OF CHANGE & PSSR MOC Plant Procedure: Technical basis are thoroughly reviewed Face-to-face discussions Hazard review Team depends on the type of change Documenting and tracking all activities (electronic system) Level of notification and training is observed Pre-Start Up Safety Review (team) Level of Authorization depends on complexity of change Important points: Identify changes (Training, procedure definition) Multidisciplinary analysis Manage Temporary Changes

OPERATIONAL TRAINING ELEMENT 6: OPERATIONAL TRAINING Ensure that operators have proper training and qualification Plant Training program 4 levels of operator positions New operator will start in the first level In each level the degree of complexity and responsibilities increases. The last level is the DCS operator In each stage, training last 3 months at least In each stage refresher training: every 3 years Assessment consider technical and behavioral skills Includes all aspects of the operational procedures and safe work practices Provide employees with an understanding of hazards associated with their activities

PROCEDURES ELEMENT 7: OPERATING PROCEDURES Plant Procedures provides clear instructions to operate the plant. Items: Steps for each operating phase Safe limits Safety and health considerations Safe Work Practice Lessons Learned A electronic system is used to keep this information up-to-date. Reviewed and updated once a year, or as necessary.

INCIDENT INVESTIGATION ELEMENT 8: INCIDENT INVESTIGATION PURPOSE: Identify root causes and system failures Propose corrective action plan in order to prevent reocurrence Learn from experience Facility has a formal program for HES incidents investigation, which includes: Criteria for incidents investigation and Severity classification Investigation of near misses RCA Team: Process knowledge + Methodology Development of RCA mentality Not Just For HES Incidents! Communicate of findings Automated System

MECHANICAL INTEGRITY ELEMENT 9: MECHANICAL INTEGRITY PROGRAM Ensure that process equipment are designed, constructed, installed and maintained properly. Plant Practices: Written procedures Training for maintenance activities Inspection, testing, and repair Equipment deficiencies management (SAP) Quality assurance (Ex: Technical specifications, PMI) Training program for maintenance personnel includes: Legal requirements Technical specific practices (knowledge sharing sessions). Engineer team monitors deficiencies, evaluates performance, and proposes correction actions to MI program and practices.

Electrical equipment and systems -Depends on the system: Detailed Inspection, Visual Inspection, Oil Analysis, Electrical Tests, Thermography, Battery Tests Rotating equipment - ABC classification - Vibration Analysis, Sensitive Maintenance, Oil Analysis. Maintenance and Inspection Practices Relief devices and vent systems -Routine maintenance and applicable function tests for Relief Devices in HHC service not to exceed 2 years, other Relief Devices follows National Regulation NR13. Pressure vessels -Technical references for pressure vessels MI monitoring: API 510, CI e NR13. Emergency shutdown systems, control systems and alarms -Frequency of tests and inspections follow recognized and generally accepted engineering practices and evaluation of risk associated to the loop (implementation in progress) Storage tanks - References: API 650/653 Piping systems and components - References: API 570, Chlorine Institute and NR13

CONTRACTORS ELEMENT 10: CONTRACTORS Ensure that contractors have programs consistent with plant PSM. Plant procedures: Contractor activity classification determines: PPE, Required training, Requirements for occupational safety and health program Training topics are stated by Unipar Carbocloro(regulation and specific hazards) General safety information When starting to work Refresher training: annually Monthly Safety Meetings and Safety Dialogs Evaluating and tracking contractor safety performance Audits

SAFE WORK PRACTICES ELEMENT 11: SAFE WORK PRACTICES Procedure for issuing written permission to perform safe work services. Plant Practices: Applied to employees and resident contractors Refresher training every 3 years The permit shall be kept on file until work completion Valid for one work day Lock, TagandTry Hot work Confined space entry Line breaking Fall protection Critical non-routine activities Non-critical non-routine activities Key Procedures Each activity has a speficicprocedure and form

EMERGENCY PLANNING AND RESPONSE ELEMENT 12: EMERGENCY PLANNING AND RESPONSE The Emergency Response Plan details how the facility will respond to and mitigate emergency situations. Facility has a written plan which: Assigns responsibilities Details emergency steps Is based on State Fire Department regulations and on specific hazards Response team composed by employees Training and drills are based on selected accidental scenarios Selection of drills scenarios are based on a classification Plan is periodically evaluated and improved(yearly)

EMERGENCY PLANNING AND RESPONSE Training and Drills Training Yearly training of employees and contractors Visitors receive safety and the emergency plan information Emergency Response Team: 3 levels of training based on role established on the ERP Emergency Response and Evacuation Drills 4 Emergency Response drills per year, one of them includes plant evacuation and one of them includes confined space rescue Community evacuation drill performed every five years Emergency exercises on a school nearby company(one per semester) The drills are evaluated and recommendations are tracked

FIRE PROTECTION SYSTEMS ELEMENT 13: FIRE PROTECTION SYSTEMS Plant Procedures and systems: Fixed systems and mobile apparatus that is intended to either aid in the extinguishment and/or control of fires or explosions (Fire pumps, deluge systems, hydrants, underground distribution piping, etc) Fixed systems installed to notify personnel that a fire and/or gas release has occurred (Combustible gas detection systems and smoke detection systems) Defined frequency of Inspections, tests, and maintenance activities Formal documentation and approval for temporary impairment

AUDIT ELEMENT 14: AUDIT Verify if the obligations outlined in the PSM Program are being met. Facility PSM audit program: Cover the specific process safety aspects Includes contractor and maintenance activities Conducted every three years(all elements) Carriedoutbyemployee orexternalteam 9 employees certified by Abiquim(Responsible Care Program Audit) Non-compliance investigation Track action plan

METRICS ELEMENT 15: METRICS Main objective: Monitor PSM effectiveness and suggest improvements. Plant Procedure: Metrics considers: Report MOC Incident Investigations and recommendations Last Line of Defense Mechanical Integrity program (Inspection and maintenance) Monthly metrics Some items are discussed weekly

Final Comments Continuous effort is essential to PSM program performance: Commitment from all levels of management and staff Understanding of plant hazards. Analyze and manage risks Conduct periodic audits Management of barriers integrity Keep continuous improvement culture

QUESTIONS? 27

THANK YOU! Flávia Mariano Pinto flaviapinto@uniparcarbocloro.com.br www.uniparcarbocloro.com.br www.fabricaaberta.com.br