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Available online at www.sciencedirect.com ScienceDirect Procedia Engineering 157 (2016 ) 285 292 IX International Conference on Computational Heat and Mass Transfer, ICCHMT2016 The Calculation Of The Amount Of Energy Needed To Keep The Solar Collector Absorber Surface Above The Freezing Point Of Water In The Polish Climate All Year Round Paweł Solak a, Leszek Kulesza a * a Cracow University of Technology, Instytut Inżynierii Cieplnej i Ochrony Powietrza, 31-155 Kraków ul Warszawska 24, Poland Abstract One of the simplest methods of employing solar energy is using the heat generated in solar collectors for the heating of household water. When there is a lack of heat collected from the tanks holding the water, while a large amount of sunlight is present on the collectors, stagnation occurs. One of the main effects of stagnation is faster degradation of solar fluid. Our paper suggests that changing the solar fluid to water can bring benefits, as it is non-toxic, publicly available, and allows for easy dosing of the system. The main objective of this paper is the calculation of the amount of energy needed to keep the temperature of the water in the installation above freezing throughout the year. This allows the comparison between water and antifreeze as energy carriers. In the current paper, we only consider the use of the installation for hot water, because the demand for it is generally constant throughout the year. The use of water is advantageous during filling, since it is cheaper and non-toxic. It is more convenient for supplementing, filling, and emptying the installation. If water is left in the plant all year round, however, the user must bear in mind the energy costs of maintaining the collectors at temperatures above 0 o C, and the increased cost of providing the pump drive to the collector during these cold periods. In the case of flush installations for the winter, these costs are not incurred. 2016 Published The Authors. by Elsevier Published Ltd. This by Elsevier is an open Ltd. access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). Peer-review under responsibility of the organizing committee of ICCHMT2016. Peer-review under responsibility of the organizing committee of ICCHMT2016 Keywords: solar fluid; solar panels; solar collectors; heat loss in stagnation * Corresponding author. Tel.: +0-000-000-0000 ; fax: +0-000-000-0000. E-mail address: lkulesza@wp.pl 1877-7058 2016 Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). Peer-review under responsibility of the organizing committee of ICCHMT2016 doi:10.1016/j.proeng.2016.08.368

286 Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 1. Introduction One of the simplest methods of using solar energy is the transmission of the heat generated in solar collectors for the heating of household water [1, 2, 3]. The water is used for the purposes of sanitation or other household needs. Water heating systems using solar collectors are simple to build, and do not require advanced technology, which contributes to their increasing popularity. Flat solar collectors are treated as heat exchangers, which convert solar energy into heat. As the intermediary in the transfer of energy, antifreeze is often used. The most important element of the solar collector is the absorber, i.e. the disc that takes in the energy. As a result of the lack of transfer of heat from the tanks holding the heated water - while a large amount of sunlight is incident on the collectors - stagnation can occur. One of the main effects of stagnation is faster degradation of the solar fluid, which contributes to the need to rinse the solar installation and remove degraded exchange intermediary agent (solar fluid). Therefore, in this paper we propose to change the solar fluid to water, which is non-toxic, publicly available, and gives easy dosing of the system. Nomenclature A the surface area of the absorber [m 2 ], d a the width of the air gap [m], h a radiation heat transfer coefficient [W/(m 2 K)], k a effective thermal conductivity [W / (m * K)], Q heat loss flux [W], Q d heat flux supplied to the absorber by the water [W], Q r solar heat flux [W], R the resistance of the "penetration" heat from the absorber to the outdoor air [(m 2 K) /W], R a complex thermal resistance of the air gap [(m2k) / W], T 1 absorber temperature [K], T 2 the temperature of the inner side of the glass [K], T 3 the temperature of the outer side of the glass [K], outside temperature [K] T z 2. Purpose and scope of the paper The main objective of this paper is the calculation of the amount of energy needed to keep the water s temperature above freezing in the installation throughout the year. This gives the opportunity to compare the economics of water as an energy carrier with antifreeze liquid. This paper is only concerned with using solar energy for hot water, because the demand for it throughout the year is constant, allowing for greater efficiency. The calculations are for flat collectors with meandrical fluid flow. Did not take into account other types of collectors, such as pipes. If the calculation results in this article would give a chance to cost savings could also consider other types of collectors. The amount of heat that must be delivered to the solar collector to prevent freezing of the collector during the period under consideration is calculated in three ways: without taking into account the radiation in the air gap, taking into account the radiation in the air gap, According to PN-EN ISO 6946 [4]. Our paper is an attempt to estimate the profitability of the conversion of the heat transfer fluid from antifreeze to water.

Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 287 3. The objective of the conversion of heating agent The layout of the solar installation for the production of domestic hot water is designed to provide heat, taken from the solar collector, to the tank, in which household water is collected. Solar radiation enters through the solar glass and falls on the absorber. The absorber, the main element of the solar collector, is made of heat-conducting metal. The absorber is attached to channels, through which the working fluid flows. The geometric layout of the channels under the absorber is either a harp pattern or meandrical; the channels should be adjacent to the absorber, in order to receive the greatest amount of energy. The aim of this paper is also to check whether water can be used as a carrier of energy suitable for working under pressure in solar installations. We considered only flat collectors with a meandrical pipe layout (Figure 1), because these ensure smooth flow. Solar Panel manufacturers devote much attention to the issue of stagnation in solar collectors [5,6,7,8,9]. Problems that arise from stagnation include: Figure 1. Solar Collector of the meandrical system. The solar liquid undergoes more rapid degradation this results in more frequent replacement of solar liquid, and the cleaning of the entire installation, the possibility of the destruction of the solar installation components such as the pump, expansion vessel, joining elements, and insulation, operation of the safety valve in the system and the ejection of solar liquid, unpleasant water hammer in the solar installation. Stagnation occurs when a large amount of solar radiation is incident on the solar collector, while at the same time there is a lack of use of heated water. Such situations may occur when: there is an oversized collector area, the water tank is too small, there is a failure of electrical power, and there is no extra emergency power supply, pumps fail,

288 Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 the user is absent (e.g., vacation). During stagnation, accelerated aging of the solar fluid occurs. At temperatures above 200 o C the destruction of ethylene glycol and inhibitor happens. Figure 2 shows the difference between destroyed fluid (left hand side) and undestroyed fluid (right hand side). In the freezing solution used in Figure 3 heavily damaged solar fluid polymerization products can be seen [10]. Figure 2. The antifreeze fluid. On the left side a destroyed fluid and on the right side unused [10] Figure 3. Heavily damaged solar liquid with polymerization products [10]

Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 289 As the solar fluid can be destroyed during the operation of solar installations, it is proposed to use water as a transfer medium. 4. The assumptions for the calculation of the amount of energy needed the isolation of the solar collector is ideal, in the calculation of heat losses in the intake, the absorber has a constant temperature of 5 0 C, the calculations are carried out for one year, the irradiance threshold above which it is receiving heat from the absorber of the collector is 100 Wm -2. Due to the conversion of the solar installation to water, without antifreeze, it s necessary to provide energy to the heat absorber at temperatures below 5 0 C, so as not to destroy the solar collector as a result of the freezing of the water in the fluid channels. The limit of 5 0 C gives security, taking into account, for example, the measurement error of the sensor and the uneven temperature field in the absorber. The calculations were carried out for the surface of a 1 m 2 collector. Outside temperature climate data were taken from the measuring point at the Balice measuring station [11]. The temperature of interest was defined from the lowest to 5 0 C. In the reference year there were 3303 hours in which such a state occurred. Data and dimensions needed for the calculations were provided from a drawing of the solar collector, Figure 4 [12]. 5 4 1 5 4 50 O12 7 2 6 4 3 Figure 4. The cross-section of the solar collector [12] 1. solar glass 4 [mm] thick, 2. copper sheet absorber, 3. thermal insulation, 4. housing, 5. Solar glass mount to the housing, 6. copper pipe with a diameter of 12 mm, 7. the air layer ( empty ) with a height of 50 mm 5. The calculation of the amount of energy needed In consideration conditions (temperature below 5 C) absorber energy balance has the form: Q d = Q Q r (1)

290 Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 The remaining heat loss are omitted, in accordance with the assumed that there was a perfect insulation of the absorber from the side of the housing. The correctness of these assumptions can be checked experimentally, which is intended in the future. The heat flux supplied to the absorber by solar radiation Q r is minimal during the period considered and its value depends on the weather. For safety the collector can be assumed that Q r = 0. The amount of heat that must be delivered to the solar collector in order not to freeze the collector for the period under consideration, is calculated in three ways: without taking into account the radiation in the air gap, taking into account the radiation in the air gap, According to PN-EN ISO 6946 [4]. The basic formula used for the calculation: Q=A*(1/R)*(T 1-T z) (2) The resistance to the "penetration" of heat from the outside air to the absorber R consists of resistance to heat conduction through the air layer, resistance to heat conduction through the glass, and seize on the outer surface of the heat resistance, adjoining the outside air. In order to calculate the loss of heat, the heat transfer resistance was calculated for each of the methods. Only the way of determining the resistance of heat conduction through the air gap varies according to the methodology used. Other components of R clearly defined for all methods are calculated in the same way. A characteristic variable in the calculation is the slit width, and the physical properties of the fluid are designated for a medium temperature T m, where: T m=(t 1+T z)/2 (3) Solar collector heat loss without radiation in the air gap. Heat loss occurs by natural convection in closed space, as the air circulates. In order to calculate the heat flux, note that instead of the thermal conductivity of the fluid, we have to use the effective thermal conductivity, taking into account the effect of convection [13]. For the calculation of the efficient thermal conductivity the equation containing the Grashoff Number and the Prandtl Number is used. As a result of our calculations, not including radiation in the air gap, the demand for energy required to maintain a constant temperature in the absorber amounted to 33 kwh/(m 2 a). Solar collector heat loss with regard to radiation in air gap. In the calculation of the solar collector s heat loss, radiation in the air gap occurs simultaneously with convection heat loss [13]. Thermal resistance R, in contrast to the previous method, instead of resistance for heat conduction through the air layer, contains complex thermal resistance of the air gap: R a = 1/( k a/d a + h a) (4) Using a calculation method that takes into account the radiation in the air gap, heat demand to cover the losses amounted to 93 kwh/(m 2 a). Heat flow that must be brought to the absorber to maintain a constant temperature, calculated according to PN EN ISO 6946. PN EN ISO 6946 gives, inter alia, the thermal resistance of the non-ventilated air layer. The thermal

Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 291 resistance for different thicknesses is read from table 2 from [4]. In our case it is 0.16 (m 2 K) /W for a gap of 50 mm. This resistance is used instead of the other formulas used in previous methods for determining the air layer s resistance. After we carried out the calculations, we found that the demand for heat to maintain a constant value of 5 0 C in the absorber is 99 kwh/(m 2 a). 6. The calculation analysis Of the three methods of computing, two gave very similar results: calculations with regard to the radiation in the slit and the calculation according to ISO standards. The results of the third are three times smaller, and prove only that the impact of radiation cannot to be ignored Table 1. Further calculations were based on the two results that were similar to each other. Table 1. Table of heat losses for 1 [m 2 ] absorber The Method of Calculating the Losses Heat Flow [kwh/(m 2 a)] Without radiation in the air gap. 33 With the radiation in the air gap 93 According to the PN EN ISO 6946. 99 The financial burden that must be considered for the season for a solar panel, with the factor of about 100 kwh/m 2, needed to maintain a temperature of 5 O C, can be calculated. In addition to this, it is worth mentioning that the pump in a solar installation with water needs to be running continuously throughout the period in which temperatures are below 5 O C, while the installation of the glycol pump requires action only in the case of an overrun of the threshold radiation intensity (this is 100 W/m 2 ). Table 2 compares the solar fluid and water in terms of cost. The calculations are carried out for a 1 m 2 absorber for the season; the bills relate to a solar installation consisting of a 10 m 2 absorber and the valves necessary for the proper operation of the system. The comparison takes into account only the period of temperatures below 5 o C. Table 2. Comparison of the economics of solar fluid (glycol) and water Type of costs Water [PLN] Glycol [PLN] Pressing the heating factor -82.00-45.00 Type of energy used for heating Gas Electricity Gas Electricity Annual maintenance of the thermal absorber at 5[ o C] is 100 [kwh/m 2 ] -30.00-70.00 - - The cost of servicing with replacement of fluid every three years -17-17 -44-44 The yield of radiant heat over 100 [W/m 2 ] during the period considered +43 +100 +43 +100 The sum of above -86-69 -46 +11 7. Summary and conclusions This paper shows how much energy is needed per year to maintain a constant temperature during the times when absorber temperatures are lower than 5 0 C. The advantages of promoting the use of water as an intermediary agent are:

292 Paweł Solak and Leszek Kulesza / Procedia Engineering 157 ( 2016 ) 285 292 ability to supplement the solar system by a person without technical capacity at any time, without the need to wait for a service, the possibility to empty the system of water to the sewage system (e.g. during long absences from the building), without incurring recycling costs, as is the case for antifreeze, purchase costs of non-toxic water in relation to solar fluid are comparably low; having regard to the maintenance and exchange of fluid every three years, the annual difference in cost between water and solar liquid is about 27.00 PLN/(m 2 * season), easy and unlimited availability of water, no need for expensive, specialized tools, to supplement and control its characteristics, no significant costs due to the risk of a failure associated with overheating of the fluid; in the case of the replacement of glycol occurring earlier than after three years, it's hard to determine how often this may occur and what will be the cost. Solar fluid is superior to water in some respects: no permanent financial expenditure on the maintenance of the absorber at positive, no financial burden associated with maintaining a constant pump operation during temperatures below 5 o C; it's about 37.00 PLN/(m 2 * season) to the detriment of water, no need to invest in an additional emergency source of electrical power, in the event of a power failure and lack of additional electrical power during periods of cold weather, a solar system flooded with water can be completely destroyed. There are currently no solar installations using water as the initial heat transfer fluid on the market. To avoid the stagnation of fluid in the solar collectors in glycol installations, you need to adhere to the manufacturer s guidelines. If you use a flush installation with water as a heat transfer fluid for the winter, you do not have to bear any additional costs. 8. References [1] Kusto Z., Praktyczne obliczenia w instalacjach słonecznego ogrzewania wody, Zeszyty naukowe Wydziału Elektrotechniki i Automatyki Politechniki Gdańskiej Nr 27/2010 [2] http://www.globenergia.pl/dzialy-tematyczne/kolektory-sloneczne/159-kolektory-1/2087 [3] Lewandowski W.M., Proekologiczne odnawialne źródła Energii,Wydawnictwo Naukowo-Techniczne, Warszawa 2010 [4] PN EN ISO 9646 [5] Jeleń I., Temperatura stagnacji a sprawność kolektora słonecznego (2). Ochrona przed przegrzewem. Magazyn Instalatora, 5 (189) maj 2014, pp 42 44 [6] www.solarblog.pl [7] www.optimapolska.com.pl/temperatura-stagnacji/ [8] instalreporter.pl, 9/2015 [9] http://www.globenergia.pl/dzialy-tematyczne/kolektory-sloneczne/159-kolektory-1/2087/stagnacja-wkolektorach-slonecznych [10]http://www.environmental-expert.com/companies/tyforop-chemie-gmbh-48328 [11] http://www.transport.gov.pl [12] http://www.solarpolska.com [13] Tadeusz Hobler, Ruch ciepła i wymienniki, Wydawnictwa Naukowo-Techniczne, Warszawa,1986