Public Workshops on Carbon Capture and Sequestration

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Carbon Capture & Sequestration Economics Public Workshops on Carbon Capture and Sequestration Howard Herzog MIT February 13-14, 14, 2008 Overview Capture primer Costs CCS as part of a mitigation portfolio 1

CO 2 Capture Majority of costs associated with CO 2 capture CO 2 capture refers to the separation of CO 2 from the flue gas its subsequent compression to a supercritical or liquid state. Why capture? CO 2 is too dilute in flue gas of power plants to economically transport and inject underground. Some industrial processes produce a relatively pure CO 2 stream resulting in low capture costs these are high priority targets for CCS Post-Combustion Capture Stack Gas Flue Gas Gas Clean-up CO 2 Capture CO 2 Air Coal Boiler oe Steam Steam Cycle Electricity 2

CO 2 Capture at a Power Plant Source: ABB Lummus Capture and Compression Capital Costs Power Plant SCPC Capture Technology Post- Combustion Capital Investment Power Output $/kw +23% -24% +62% Two approaches to lower cost of capture: (1) Improved capture processes (2) Modify power plant to facilitate capture 3

Change Power Generation Process to Facilitate CO 2 Capture Power Plant PC NGCC IGCC P (atm) 1 1 40 Fract CO 2 0.15 0.05 0.40 PCO 2 (atm) 0.15 0.05 16 Capture Process Chemical Chemical Physical Absorption Absorption Absorption PCO 2 indicates the difficulty of capture. IGCC Power Plant Air Air Sep Unit (ASU) Oxygen Flue Gas Coal Gasifier Syngas Gas Cleanup CO/H 2 Combined Cycle Electricity 4

Pre-Combustion Capture Air Air Sep Unit (ASU) Oxygen Flue Gas Coal Gasifier Syngas Gas Cleanup Combined Cycle Electricity CO/H 2 H 2 Shift CO 2 /H 2 CO 2 Capture CO 2 CCS Costs Current cost estimates are significantly higher h than 2 years ago due to recent run-up up in commodity prices Considerable uncertainty in cost estimates Volatility in markets Recent data sparse Dealing with first-of-a-kind technology 5

Estimated CCS Costs for Coal Estimated CCS Costs for coal additional $35-45 per MWh to cost of generation $50-65/tonne CO 2 avoided This cost assumes: 2007$ 90% capture CA conditions includes transport and storage ($10/tonne CO 2 avoided) Today s technology (i.e., no technological breakthroughs required) Regulatory issues resolved without imposing significant new burdens Operations at scale CO 2 Sources in California # of Facilities Capacity 2004 CO 2 Emissions (Mt/yr) Gas Power 221 39,000 MW 58 Oil Power 3 32 MW 0 Coal Power 8 440 MW 3 Cement 11 15 Mt/yr 12 * Ethanol 4 68x10 6 gal/yr 0.4 * Gas Processing 31 1x10 9 CFD? Refineries 15 2x10 6 bbl/d 18 * Total 293 - ~90 *Estimated 6

Estimated CCS Costs Estimated CCS Costs for coal additional $35-45 per MWh to cost of generation $50-65/tonne CO 2 avoided Estimated CCS Costs for gas additional $30 per MWh to cost of generation $85/tonne CO 2 avoided Estimated CCS Costs for processes with a pure CO 2 stream $20-30/tonne CO 2 avoided EOR credit can offset about $20/tonne CO 2 Important Issues for Economics Quality and Quantity of the CO 2 Source Proximity of Sources to Sinks Boundary Issues - Regional vs. In-state Existing vs. New Sources 7

Existing vs. New Sources In general, applying CCS to a new source has advantages over retrofits Lower costs» Optimized designs» Higher efficiencies» Fewer constraints Siting flexibility Adding capacity vs. subtracting capacity Exception: Existing facilities that produce a concentrated CO 2 stream are best near-term prospects McKinsey& Company December 2007 Estimate 3.5-5.25.2 Gt/yr required by 2030. 8

Carbon-Constrained Constrained Scenario High CO 2 Prices - Limited Nuclear from MIT Coal Study Closing Thoughts Almost universal agreement of top-down and bottom-up economic models that CCS is potentially a cost-effective mitigation technology Investments and learning need to start immediately to get desired results by mid-century CCS varies regionally each state/region has its unique set of sources and geological reservoirs An interesting analogy for California is Norway Partial capture from coal may be interesting to meet SB1368 standard of 1100 lb/mwh 9

Contact Information Howard Herzog Massachusetts Institute of Technology (MIT) Energy Initiative Room E40-447447 Cambridge, MA 02139 Phone: 617-253-0688 E-mail: hjherzog@mit.edu Web Site: sequestration.mit.edu 10