DYNAMIS Towards Hydrogen Production with CO Management

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DYNAMIS Towards Hydrogen Production with CO 2 Management CSLF Meetings in Al Khobar, Daudi Arabia 27-29th January 2008 Nils A. Røkke Co-ordinator - SINTEF 1

DYNAMIS Scheme Coal Natural Gas Chemical conversion C x H y H 2 + CO 2 Integration? Thermal conversion C x H y Power + CO 2 H 2 Power CO 2 2

EU-DYNAMIS/HYPOGEN Overall Timeline & Budget Phase 0 Feasibility Study by JRC (2004) Phase 1 Measures within FP6, DYNAMIS (2006-2008) 7.5 M Phase 2 Pilot Scale Demonstrations (2008-2010) 290 M Phase 3 Demonstration Plant Construction (2008 2012) 800 M Phase 4 Operation and validation (2012-2015) 200 M SUM ~1300 M Pic. Siemens Pic. Vattenfall Ill. Statoil 3

Consortium - 32 partners from 12 countries Co-ordinator: SINTEF Energy Research Partners: ALSTOM (Schweiz) AG ALSTOM Power Centrales ALSTOM Power Environment ECS France BP International Ltd Bundesanstalt für Geowissenschaften und Rohstoffe E.ON UK plc Ecofys b.v. ENDESA Generación S.A. ENEL Produzione S.p.a. Etudes et Productions Schlumberger European Commission - DG JRC Institute for Energy Fraunhofer Institute for Systems and Innovation Research Geological survey of Denmark and Greenland IEA Greenhouse Gas R&D Programme Institut Français du Pétrole L AIR LIQUIDE Natural Environment Research Council (British Geological Survey) Netherlands Organisation for applied Scientific Research (TNO) Norsk Hydro ASA Norwegian University of Science and Technology Progressive Energy Ltd Siemens Aktiengesellschaft SINTEF SINTEF Energy Research SINTEF Petroleumsforskning AS Société Générale London Branch Statoil Store Norske Spitsbergen Kulkompani AS Technical University of Sofia Vattenfall AB Vattenfall Research and Development AB Shell Hydrogen BV 4

DYNAMIS IP SP1 Project management and administration Co-ordinator: SINTEF-ER DYNAMIS Structure WP 1.1 Project management and co-ordination WPL: SINTEF-ER WP 1.2 Lead project workshops WPL: SINTEF-ER SP2 Power plant & capture technology SPL: SINTEF-ER SP3 Product gas handling (H2 and CO2) SPL: SINTEF-ER SP4 Storage of CO2 SPL: IFP SP5 Planning and pre-engineering of plants SPL: Progressive Energy Ltd. SP6 Societal anchorage of a HYPOGEN demonstration SPL: Fraunhofer ISI WP 2.1 Natural-gas based hydrogen and electricity production systems WP 3.1 CO2 conditioning and transport WP 4.1 Technology screening and selection of CO2 storage sites WP 5.1 Concept plant selection WP 6.1 Strategic issues of HYPOGEN WPL: Fraunhofer ISI WPL: NTNU WPL: ECOFYS WPL: GEUS WPL: Statoil WP 2.2 Coal-based hydrogen and electricity production systems WPL: Joint Research Center WP 3.2 H2 conditioning for export WPL: SINTEF-ER WP 4.2 Conceptual models of generic CO2 storage site performances and risk analysis WPL: IFP WP 5.2 Pre-engineering studies WPL: Progressive Energy Ltd. WP 6.2 Financial structure for a HYPOGEN demonstration facility WPL: Progressive Energy Ltd. WP 2.3 New technologies for clean fossil hydrogen and power production WPL: TNO WP 5.3 Recommendations for the HYPOGEN initiative WPL: Vattenfall WP 6.3 Legal implications of a HYPOGEN demonstration facility including CO2 transport and storage activities WPL: ECOFYS WP 2.4 Technology benchmarking, qualification and recommendations WPL: Alstom WP 6.4 Professional and public acceptance for carbon capture and storage activities WPL: Fraunhofer ISI 5

Overall Project Schedule Year 1 Year 2 Year 3 SP1: Project management and administration Lead project milestones SP2: Power plant & capture technology SP3: Product gas handling SP4:Storage of CO2 SP5: Planning and pre-engineering of plants Project Launch Mid-term review Final workshop Support to SP5 Support to SP5 Support to SP5 Support/ limited activity SP6: Societal anchorage of a HYPOGEN demo 6

Criteria for Selection Geographic Aspects Site specifics Fuels availability Power and heat sales CO 2 conditioning and storage Hydrogen demand Technical Issues Overall 90% CO 2 extraction, 400 MW e and 0-50 MW H 2 export Methane/Coal reforming/gasiifcation technology Syngas Separation and Conditioning GT s and train configuration(siemens V94.2K, ALSTOM GT13E) Financial Issues CAPEX, OPEX Financial risk(technical, Financial (loans and interest, bankability),eib role) Political & Legal Framework Concensus and joint undertakings Storage risk and acceptance 7

Critical Criterion - CO 2 Storage Viable Capacity (SP 5) Realistic Capacity (WP 4.2) Theoretical Capacity (WP 4.1) Bradshaw et al, 2006 8

Criteria List Depth > 800 m or P-init > 80 bar or Supercritical CO 2 Total storage capacity > 60 Mt CO2 Injectivity > 2.0 Mt CO 2 per year or permeability > 200 md Integrity of seal in terms of thickness, faults etc. Location of site compared to Power/Hydrogen Market Geographical representation of sites Availability of geological data Availability of site by 2012 Variety of geological conditions Variety of storage types 9

Power Plant and Capture Technologies Cases Studied 6 NG cases 6 Coal cases x Lignite cases 3 NG cases 3 Coal cases 3 Lignite cases GT26, Post-C, SMR, Pre-C integration GT13E2, ASU, ATR, Pre-C integration GT13E2, ATR, Pre-C - integration Shell gasifier Siemens/Future Energy gasifier GE/Texaco gasifier All cases: GT13E2, Selexol TBD in progress 3 cases initially HTW gasifier included, instead of GE/Texaco 10

Technology Selection Natural Gas with Pre-C capture Natural Gas with Post-C capture and NG reforming of H2 Coal and/or lignite with Pre-C (ZE)IGCC 1. Coal/lignite with parallell H 2 production and CO 2 capture (oxy-fu or Post-C) not pursued due to efficiency and thus cost issues 11

Site Decision Recommendations Using the DYNAMIS requirements of cost efficient production of H2, electricity and CO2 storage, 4 sites are recommended for further studies in the second phase of DYNAMIS: Mongstad, Norway, suggested by Statoil: Natural gas based plant with offshore CO 2 storage. Hamburg region, Germany, suggested by Vattenfall; Bituminous coal based plant with onshore or offshore CO 2 storage East Midlands, England, suggested by E.ON UK; Bituminous coal based plant with offshore CO 2 storage North East UK, suggested by PEL; Bituminous coal based plant with offshore CO 2 storage These plants represent a reasonable spread of fuel types, storage types and location and hydrogen utilisation/export possibilities. 12

Summary and Conclusions 4 sites have been identified as candidate plants for the HYPOGEN initiative- these have all been proposed by an industrial partner. Further work will involve to further develop these cases with pre-engineering studies and preparatory measures (EIAS,..) Target is to have developed these cases to ready for project launch by the end of DYNAMIS, i.e. March 2009. Much is now dependent upon the industrial commitment and support of the specific sites. 13

DYNAMIS Towards Hydrogen Production with CO 2 Management CSLF Meetings in Al Khobar, Daudi Arabia 27-29th January 2008 Nils A. Røkke Co-ordinator - SINTEF 14