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The innovation challenge of carbon capture and storage technologies Kelly Thambimuthu, Chairman, IEA Greenhouse Gas R&D Programme and Chief Executive officer Centre for Low Emission Technology, Queensland, Australia. Presentation to 2 nd CEEM Annual Conference, UNSW, Sydney, 26 October 2006 kelly.thambimuthu@csiro.au Outline of this presentation Climate change and energy the challenges Energy technology pathways to reduce emissions - role of CO 2 capture and storage (CCS) technologies Status, cost and the global economic potential of CCS Challenges and opportunities for CCS Conclusion 1

IEA GHG current membership Centre for low emission technology - clet The State of Queensland through the Department of State Development, Trade and Innovation Australian Coal Association Research Limited Stanwell Corporation Limited CSIRO through CSIRO Energy Technology and its Energy Transformed Flagship Program Tarong Energy Corporation Limited The University of Queensland.progressing the development of enabling technologies for the low emission production of electricity and hydrogen from coal. 2

IPCC projections of CO 2 emissions Emissions in billion tonnes of C/y 20.0 15.0 10.0 5.0 0.0 350 ppm Business as usual 750 ppm 550 ppm -5.0 1990 2015 2040 2065 2090 2115 2140 2165 2190 2215 2240 2265 2290 Pre-industrial concentrations in the atmosphere 275 ppm Today s concentration in the atmosphere ~380 ppm A 550 ppm stabilisation scenario would require the removal of over 100 years of the current energy related CO 2 emissions into the atmosphere Source IPCC TAR The main influences on CO 2 emissions CO 2 = Emissions. Energy. GDP. Population Energy GDP Popn. Technology Energy use Wealth 3

World primary energy demand, IEA 2005 18 000 16 000 Mtoe 14 000 12 000 10 000 8 000 6 000 4 000 Oil Gas Coal 2 000 0 Other renewables Nuclear Hydro 1970 1971 1980 1990 2000 2010 2020 2030 Oil, gas and coal together account for 83% of the growth in energy demand between now and 2030 in the Reference Scenario Source IEA world energy outlook, 2005 Energy-related CO 2 emissions by region 2003 2030 India 4% Other 11% MENA 6% India 6% Other 16% MENA 8% China 16% China 19% Transition economies 11% OECD 52% Transition economies 9% OECD 42% 24 Gt 37 Gt Global emissions grow by just over half between now and 2030, with the bulk of the increase coming from developing countries Source IEA world energy outlook, 2005 4

The carbon lock in New and replacement fossil fuel power generation capacity (GWe) 2010 2020 2030 World 520 967 1205 OECD 160 309 363 Developing Countries 343 587 750 Transition Economies 16 72 90 European Union (25) 39 105 132 North America 83 141 171 China 162 210 260 India 24 66 97 Russia 5 27 34 A rapid anticipated growth in power generation to 2030, with the bulk of the increase coming from developing countries Source IEA Clean Coal Centre Primary energy growth in Australia 2004 Total Consumption: 5,345 PJ Renewables 4.79% 2030 Total Consumption: 8,728 PJ Renewables 5.80% Natural Gas 19.61% Black Coal 29.37% Natural Gas 24.47% Black Coal 25.76% Brown Coal 9.82% Oil 33.53% Brown Coal 12.70% Oil 34.15% In 2030 Australian primary energy consumption increases by more than 60% Source ABARE 2005 5

Options to reduce CO 2 emissions Reducing energy use Energy conservation Improving efficiency of production and end use Increasing the use of alternative energy technologies Renewables: wind, solar, hydro, biomass, geothermal Nuclear New lower emission fossil fuel technologies Clean coal with carbon capture and storage (CCS) Natural gas with carbon capture and storage The options in a carbon constrained future Carbon Neutral Energy H 2 Economy (?), De-carbonised electricity (?) Nuclear fission & Fusion? Conservation, efficiency and lower carbon fuels CO 2 capture & storage Renewables Fossil Fuels 2003 to 2030 >50% increase; 85% fossil fuel, 10% renewables, 5% nuclear 6

The pathway for CO 2 capture & storage (CCS) SOURCE Fossil fuels Energy, Electricity or H 2 (with zeroing emissions) CO 2 capture Greener Fossil Fuels (Enhanced oil and coal seam methane recovery) Utilisation SINK Storage Spent oil/gas fields Saline reservoirs The vision for low emissions technology or Coal Coal With CO 2 capture & storage, will this be a bridge to our energy future? Source: Adapted from Olav Karstaad, Statoil 7

Electricity energy carrier Coal Natural gas Renewables Electricity and gas Transport CO 2 capture for coal X X CO 2 storage Industry Residential Hydrogen energy carrier Coal / gas Renewables Hydrogen CO 2 capture for coal and gas Transport CO 2 storage Industry Residential 8

Where best to capture CO 2? 18 000 16 000 million tonnes of CO 2 14 000 12 000 10 000 8 000 6 000 4 000 2 000 0 1990 2002 2010 2020 2030 Power Generation Other Transform ation Industry Transport Other Sectors Significant emissions growth in power generation and transport sectors - large power generation and industrial plants represent over 60% of 2030 emissions Source IEA world energy outlook, 2004 Can we store CO 2 - global storage capacity Unminable Coal Seams 30 Gt CO2 Able to store <2 Years of 2030 Emissions Depleted Oil & Gas Fields 930 Gt CO2 Able to Store 50 Years of 2030 Emissions Deep Saline Aquifers 400-10 000 Gt CO2 Able to store 20-530 Years of 2030 Emissions Note: Economical CO 2 Storage potential at a storage cost of 20 US $ per tonne of CO 2 Source: IEA GHG studies 9

The options for low emissions plants with CCS Centralised power and industrial plants Coal or Combustion Gasification Natural gas or Reforming Biomass for carbon offset CO 2 to storage CO 2 capture Chemicals Hydrogen Liquid Fuels Power Generation Distributed energy & products Chemical products Distributed heat & power Transport vehicles Industrial products Heating or cooling Electricity Technology maturity of CCS components Oxyfuel combustion Post-combustion Pre-combustion Industrial separation Mineral carbonation Ocean storage Research phase Source IPCC 2005 Enhanced Coal Bed Methane Demonstration phase Gas and oil fields Saline formations Economically feasible under specific conditions Transport Industrial utilization Enhanced Oil Recovery Mature market 10

Technology maturity - capture in power plants Power generation with post combustion capture SC/USC pulverised coal and NGCC power plants are reliable and proven Scale up of solvent capture units/integration with power cycle is unproven. Power generation with pre-combustion capture IGCC for coal (1 GWe) is near commercial and proving reliability, better experience with 3 GWe of IGCC capacity on oil and petcoke. No experience to date with reforming/pox/atr based natural gas power plants Solvent capture units for CO 2 available at scale, integration and power block hydrogen utilisation issues Power generation with oxyfuel combustion No proven experience of operation of pulverised coal power plants in an oxyfuel combustion mode the issue is confidence building Large scale ASU s for O 2 production proven and reliable. Some development issues with tail end CO 2 purification CO 2 or hybrid turbines do not exist for oxyfuel combined cycles The cost of CO 2 capture and storage Natural gas CC Pulverised coal IGCC Hydrogen Plant % increase in cost of electricity or hydrogen with capture and geosequestration 38-54 46-90 34-49 17-44 Cost of CO 2 avoided with geosequestration, US$/t 38-91 30-71 14-53 3-75 % increase in cost of electricity or hydrogen with capture and EOR 19-40 14-56 0-23 0-29 Cost of CO 2 avoided with EOR US$/t 19-68 9-44 (-7)-31 (-14)-49 11

Power generation efficiency with capture today Efficiency, % LHV 60 50 40 30 20 10 0 IGCC slurry Coal IGCC dry Oxyfuel Postcomb Postcomb Oxyfuel Natural gas Without capture With capture Source: IEA GHG studies Increase in electricity costs Increase in costs due to capture, % 90 80 70 60 50 40 30 20 10 0 Postcomb IGCC slurry Coal IGCC dry Oxyfuel Postcomb Fuel Capital Electricity Oxyfuel Natural gas Assumptions: 10% DCF, Coal $1.5/GJ, Gas $3/GJ; Relative to same base plant without capture Source: IEA GHG studies 12

Capital cost US $/kw 2000 1800 1600 1400 1200 1000 800 600 400 200 0 Post Fluor Post MHI IGCC slurry Coal IGCC dry Oxyfuel Post Fluor Post MHI Natural gas Oxyfuel Without capture With capture Based on 1 US $/Euro Source: IEA GHG studies Options for application of low emission plants Retrofit equipment for CO2 capture in existing plants drawbacks include site limitations, poor system integration and significantly reduced energy efficiency Replace all equipment at a given site to upgrade process efficiency and with process integrated capture plant benefit of high efficiency base equipment with lower energy penalties and costs for capture. Also reduces other environmental emissions New build capture ready or capture plants the former providing opportunities for conversion at a later date when emission reduction incentives apply 13

The global economic potential of CCS Capacity to remove 220-2,200 GtCO 2 cumulatively up to 2100, depending on the baseline scenario stabilisation level (450-750 ppmv) cost assumptions 15 to 55% of the cumulative mitigation effort worldwide until 2100 Substantial application above CO 2 abatement cost of 25-30 US$/tCO 2 Cost reduction of climate change stabilisation: 30% or more Most scenario studies: role of CCS increases over the course of the century Source IPCC 2005 Path to improved low emission coal-fired, IGCC Now 2005-10 2010-15 Increasing efficiency, lower emissions, lower costs 2015 on Commercial non-co 2 Capture IGCC plants IGCC commercial scale demos ~38-44 %LHV Dry cleaning options: Particulates, Sulphur, Nitrogen, trace elements NOx activities: reduce emissions Early full scale IGCC with CO 2 capture ~32-35 %LHV Hydrogen Turbines CO 2 capture activities: physical scrubbing demo CO 2 capture activities: Gas separation & reactor membranes New Oxygen production plants commercial Advanced IGCC low emission plants various technologies multi-products ~42-44 %LHV Beyond 2020; stationary fuel cells (IGFC) 50 58 %LHV? An example of technology improvements that can reduce costs by at least 20-30% or more over the next decade 14

Commercial demonstration projects today Sleipner In-Salah Weyburn 3 million tonnes per year of CO 2 stored Images Courtesy of BP, Statoil and PTRC, Canada Monitored CO 2 storage experience - today 40 Millions of tonnes of CO 2 35 30 25 20 15 10 5 One 500MW coal-fired power station In Salah (2005) Weyburn (2000) Sleipner (1996) 0 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 Year 15

Other planned commercial-scale projects Statoil, Snøhvit, Norway (start-up 2006/7) Gorgon, Australia (planned start 2008-2010) BP, Miller-Peterhead DF1, Scotland (operation start 2009) BP, Carson - DF2, California (operation start 2009) Statoil and Shell, Draugen, Norway (operation start 2010) Total anticipated CO 2 storage arising from these projects is an additional 12.5 million tonnes per year Proposals for coal based power plant demos Zerogen, Stanwell, Australia (proposed) SaskPower, Canada (operation start 2012) Hypogen/Dynamis, European Union (operation start after 2012) FutureGen, USA (operation start 2012) RWE Germany - IGCC UK post-combustion / oxyfuel E.ON, UK 16

Challenges pipelines and source/sinks CO 2 pipeline transmission is well but not widely established There are significant investment and infrastructure development issues to be addressed also in need of source/sink matching However: Large CO 2 pipelines have been in use since the 1970s CO 2 supplied for enhanced oil recovery (mostly natural) About 4000 km of pipeline in use today Most pipelines are in the USA (Texas/New Mexico) Individual pipeline capacities up to 20 Mt/y Good source/sink matching in some regions e.g. USA Example - Source/sink matching North America Top 500 sources emit 3.3 Gt CO2/y Sources overlay storage formations 3.1 Gt CO2/y can be stored in formations within 150km of each source Some areas may already have existing pipelines/wells Not always the case in several regions of the world 17

Challenges - legal and regulatory Rules and standards Current regulatory practises relevant to CCS Experience in related industries Natural gas storage/ Acid Gas injection/ EOR Other underground injection control programs Permitting/Licensing issues Long term liability Environmental Impact Assessment Monitoring requirements Remediation practices Challenges - public awareness Acceptance of CCS as a GHG mitigation option A solution amongst a balanced portfolio of energy technology options not a silver bullet Potential for deep reduction in emissions whilst meeting energy demand Allows orderly transformation of existing energy technology infrastructure Address the safety and security of storage Vision as a bridge to a new energy technology future Seeds the development of a decarbonised electricity and hydrogen energy infrastructure With prospects for greater integration with renewables 18

Thank You More information can be found at: www.ieagreen.org.uk www.co2captureandstorage.info 19