ADDITIVE MANUFACTURING OF TITANIUM ALLOYS

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ADDITIVE MANUFACTURING OF TITANIUM ALLOYS F.H. (Sam) Froes Consultant to the Titanium Industry Based on a paper by B. Dutta and F.H. (Sam) Froes which appeared in AM&P Feb. 2014 pp. 18-23

OUTLINE Cost of Titanium Components Cost Breakdown of Titanium Components Overview of Additive Manufacturing (AM) Part Building Technology Comparisons of Technologies Titanium Applications Remanufacturing Microstructure and Mechanical Properties Economics of (AM) Developing Techniques Conclusions

Cost of Titanium/ Comparisons Item Material ($/pound) Steel Aluminum Titanuim 0.02 0.01 0.22 (rutile) Metal 0.10 1.10 5.44 Ingot 0.15 1.15 9.07 Sheet 0.30-0.60 1.00-5.00 15.00-50.00

Metal Consumption Structural Metals Consumption/year ( 10 3 metric tons ) Ti 50 Steel 700,000 Stainless steel 13,000 Al 25,000

Cost of titanium at various stages of a component fabrication.

Boeing 787 side-of body chord, manufacturing cost breakdown (courtesy Boeing).

Left: CAD model of the part and process head. Right: Simulated toolpath for 5-axis deposition using DMDCAM software. Courtesy: DM3D Technology.

Part Building Technology Direct Energy Deposition (DED) Large Build Envelopes Add (Different) Material Powder Bed Fusion (PBF) Complex Features Hollow Cooling Passages

Heat Source Atmospheres Laser Inert Electron Beam Vacuum

AM Category Technology Company Description Directed Energy Deposition Direct Metal Deposition (DMD) DM3D Technology LLC (formerly POM Group) Laser and metal powder used for melting and depositing with a (DED) patented closed loop process. Laser Engineered Net Optomec Inc. Laser and metal powder used for Shaping (LENS) melting and depositing. Direct Manufacturing (DM) Sciaky Inc. Electron beam and metal wire used for melting and depositing. Powder Bed Fusion Selective Laser 3D Systems Corp. (acquired Laser and metal powder used for (PBF) Sintering (SLS) Phoenix Systems) sintering and bonding. Direct Metal Laser EOS GmbH Laser and metal powder used for Sintering (DMLS) sintering, melting, and bonding. Laser Melting (LM) Renishaw Inc. Laser and metal powder used for melting and bonding. Laser Melting (SLM) SLM Solutions GmbH Laser and metal powder used for melting and bonding. LaserCUSING Concept Laser GmbH Laser and metal powder used for melting and bonding. Electron Beam Melting (EBM) Arcam AB Electron beam and metal powder used for melting and bonding.

Schematic showing powder bed fusion technology.

Schematic showing Direct Metal Deposition (DMD) technology

Comparison of Various Technologies Item Laser based PBF (Ex: DMLS) Electron beam based PBF (Ex: EBM) Laser based Directed Energy Deposition (Ex: DMD) Build envelop Limited Limited Large & flexible Beam size Small, 0.1-0.5 mm Small, 0.2-1 mm Large, can vary from 2-4 mm Layer thickness Small, 50-100 m Small, 100 m Large, 500-1000 m Build rate Low, cc/h Low, 55-80 cc/h High, 16-320 cc/h Surface finish Very good, Ra 9/12 m, Rz 35/40 m Good, Ra 25/35 m Coarse, Ra 20-50 m, Rz 150-300 m, Depends on beam size Residual stress High Minimal High

Comparison of Various Technologies Cont d Heat treatment Chemistry Build capability Repair/Remanufac ture Feature/metal addition on existing parts Multi-material build or hard coating Stress relieve required, HIP ing preferred ELI grade possible, negligible loss of elements Complex geometry possible with very high resolution. Capable of building hollow channels. Possible only in limited applications (requires horizontal plane to begin remanufacturing) Stress relieve not required, HIP ing may/ may not be performed ELI grade possible, loss of Al need to be compensated in powder chemistry Complex geometry possible with good resolution. Capable of building hollow channels. Not possible Stress relieve required, HIP ing preferred ELI grade possible, negligible loss of elements Relatively simpler geometry with less resolution. Limited capability for hollow channels etc. Possible (capable of adding metal on 3D surfaces under 5+1-axis configuration making repair solutions attractive) Not possible Not possible Possible. Depending on dimensions ID cladding is also possible Not possible Not possible Possible

Comparison of Techniques PBF Better Surface Finish Slower Deposition DED Rougher Surface Higher Build Rate

Deposition Rate (cc/h) Comparison of PBF and DED Technologies in terms of layer thickness and deposition rate 10000 1000 100 10 1 10 100 1000 10000 Layer thickness (μm)

Hydraulic manifold built using EBM technology (Courtesy ONRL) PBF Allows Complex Part Good Surface Finish Reduced Machining

Medical implant application using DMLS technology (courtesy: Jim Sears) (Left- Biomedical implant/ Right- Tibial knee stem

Fan case produced by adding features with AM (laser aided directed energy deposition) to a forged perform. (courtesy: Jim Sears ) DED Part Repair

DMD Repair of turbine components; left: repaired vane, middle: macro crosssection, and right: microstructures (top to bottom shows the clad, interface and base material). (courtesy: DM3D Technology).

Microstructure of DMD built Ti6Al4V before and after HIP ing (courtesy: DM3D Technology).

Mechanical Properties Similar or Better Than Cast and Wrought Tensile S-N Fatigue

Tensile strength, yield strength and elongation of Ti-6Al-4V alloy built using various AM processes. DMD-Direct Metal Deposition, LENS-Laser Engineered Net Shaping, DMLS-Direct Metal Laser sintering, EB-Electron Beam Melting, HIP-Hot Isostatic pressing, HT-Heat treatment.

Comparison of Room Temperature fatigue properties of AM fabricated Ti-6Al-4V and conventionally fabricated Ti-6Al-4V., and represent properties in the 3 orthogonal directions, x, y and z respectively. (courtesy: EADS/Jim Sears).

Economics AM is good for small throughput AM is not as attractive for high volume manufacturing

Typical cost breakdown of various steps involved in AM of Titanium 20% 10% 18% Engineering AM processing cost Raw material (Powder) 10% 42% Secondary processing Others (includes inspection)

Seat buckle produced using DMLS technology. PBF Used Lower weight by 55% Lower cost manufacturing and cost of ownership (Fuel)

BALD bracket for Joint Strike Fighter (JSF) built using EBM technology (courtesy: ORNL, TN) Reduce buy-to-fly Ratio (1:1, compared to 33:1) Savings of 50%

Advances Addition of Different Material Surfaces (E.G. Rene 88 on Ti-6Al-4V)

Conclusions Additive Manufacturing is Here Monolithic complex parts and Bi-material components Creative design Adding features Damage repair Cost saving possible Mechanical Properties as Good as Ingot Metallurgy Parts