SECTION 1: Chemical Product and Company Identification Product/Chemical Name: Product name: Innospray Chemical Formula: NA CAS number: NA Other designations: Perfumed Liquid Product Use: Ready-to-use spray cleaner with alcohol, for use according to the instructions in the Technical Bulletin and the user instructions. Use against which is recommended: This product must not be used for other applications then that which are recommend without seeking advice of the supplier. Process categories (explanations see section 10): PROC 11 Manufacturer/Supplier: EMERGO Metal Treatment 7602 CV Almelo The Netherlands 9500 AH Stadskanaal The Netherlands Phone.: +31 (0)599 696 420 Fax.: +31 (0)599 696 425 E-mail: Web: info@emergometal.com www.emergometal.com Emergency telephone number Phone.: +31 (0)599 696420 SECTION 2: Composition/Information on ingredients The product is evaluated according to Directive 67/548/EEC (Dangerous Substances Directive [DSD]) and Directive 1999/45/EC (Dangerous Preparation Directive [DPD]) and not classified as dangerous. Ingredient name CAS number EG number % wt R-phrase H-statement Ethanol 64-17-5 200-578-6 15-30 % R11 H225 1-methoxy-2-propanoll 107-98-2 203-539-1 1-5% R10 H226 Perfumes - - - - - Auxiliary agents - - - - - Water soluble agents - - - - - The full texts of the mentioned Risk phrases (R) and Hazard statements (H) are listed in section 10. Last modified on: 2013 0610 Page 1 of 6
Toxicity data: LD50 (dermal, rat) > 2000 mg / kg LD50 (oral, rat) > 2000 mg / kg LD50 (inhalation, dust/mist, rat) > 20 mg/l/4h Irritation, corrosion, sensitization The product is not classified as dangerous. Repeated dose toxicity No data available Carcinogenicity, mutagenicity, toxicity for reproduction and ecotoxicity The product does not contain relevant concentrations of components with carcinogenic, mutagenic and / or toxic for reproduction properties. The product does not contain substances which are classified as persistent, bioaccumulative and toxic (PBT) or very persistent and very bioaccumulative (vpvb) according to 1907/2006/EU annex XIII. Foam formation after vomiting bears risk of suffocation. SECTION 3: Physical and chemical properties 3.1. Information on basic physical and chemical properties Appearance: liquid Odour: perfume ph-value: ca. 10 Melting point / melting range: ca. -5 C Boiling point / boiling range: > 85 C Flash point: 33 C Density (25 C): 0,97 Solubility in / miscibility with water: completely soluble Viscosity (25 C): < 10 mpas % Volatile (VOC) < 30% 3.2. Other information Other physical and chemical data have not been determined. SECTION 4: Fire fighting measures 4.1. Extinguishing media Suitable: water jet, alcohol-resistant foam, carbon dioxide, extinguishing powder. Not suitable: Heavy jet of water. 4.2. Special hazards arising from the substance or mixture Possible hazardous combustion products: carbon dioxide, carbon monoxide. 4.3. Advice for fire-fighters Cool containers with water spray. The product does not support combustion. It therefore needs not to be classified as flammable despite a flash point below 55 C. Last modified on: 2013 0610 Page 2 of 6
SECTION 5: Stability and reactivity 5.1. Reactivity No extraordinary reactivity known. 5.2. Chemical stability The product is stable under normal conditions (room temperature). 5.3. Possibility of hazardous reactions No hazardous reactions to be expected if used as intended. 5.4. Conditions to avoid Heating above the flashpoint and static charge. 5.5. Incompatible materials No hazardous incompatibilities known. 5.6. Hazardous decomposition products Possible development of combustible mixtures with air if heated above the flash point or when sprayed or vaporized. SECTION 6: Health Hazard Information 6.1 Potential Health Effects Primary Entry Routes Skin/Dermal, Inhalation. Target organs: Eyes. 6.2 Emergency and First Aid procedures: Inhalation: Supply fresh air. Skin contact: Wash affected areas with soap and water and rinse well. Take off all contaminated clothing. Eye contact: Rinse opened eyes several minutes under running water. Ingestion: Wash out mouth with water and drink plenty of water. Do not induce vomiting. After first aid: Get appropriate in-plant, paramedic, or medical support. 6.3. Special precautions/procedures: Although the product is not classified as hazardous, we recommend observing the safety advices. S 2 Keep out of the reach of children. S 46 If swallowed, seek medical advice immediately and show container or label. Last modified on: 2013 0610 Page 3 of 6
6.4. Other hazards Irritating to respiratory system after inhalation of spray / aerosol. Symptomatic treatment. No specific antidote known. Administration of defoaming agent (Dimeticon) in case of ingestion of large quantities. SECTION 7: Spill, Leak and Disposal Procedures 7.1. Methods and materials for containment and cleaning up Take up with suitable absorbent material (e. g. sand, diatomite, universal binding agent). Flush small amounts (up to ca. 10 l ) with plenty of water into the sewerage. 7.2. Disposal/Waste treatment methods After rinsing with plenty of water, empty containers may be recycled, landfilled or burned. Waste code according to 2000/532/EC (product): 070604 Waste code according to 2000/532/EC (package): 150102 7.3. Ecological Information Surfactants: LC50 (fish, daphnia) 1-10 mg / l. Other organic components: LC50 (fish, daphnia) >10 mg / l Environmental precautions: Do not allow to enter surface or ground waters. Persistence and degradability Surfactants: The surfactants contained in this product comply with the biodegradability criteria as laid down in regulation 648/2004/EC on detergents. Other organic components: The biodegradability of the organic ingredients present in this product complies at least with the criteria of OECD 302 B. Bioaccumulative potential The product does not contain relevant concentrations of bioaccumulative components. Mobility in soil No data available. Other adverse effects A Certificate of Ecology (statement on environmental compatibility) with detailed information on the ecological properties of the product is available on request. Last modified on: 2013 0610 Page 4 of 6
SECTION 8: Exposure controls / personal protection 8.1. Control parameters See section 2. 8.2. Exposure controls Personal protection: - Respiratory protection: Not required if used according to the instructions in the Technical Bulletin. Hand protection: Protective gloves, category III according to EN 374. A survey of suitable brands with detailed information on breakthrough times is available upon request. Eye protection: Not required. 8.3. Personal precautions, protective equipment and emergency procedures Avoid contact with eyes and skin. 8.4. Chemical safety assessment No chemical safety assessment according to 1907/2006/EC, annex I has been carried out for the product.. SECTION 9: Special Precautions and Comments 9.1. Precautions for safe handling Use only in accordance with the instructions in the Technical Bulletin. Avoid contact with skin and eyes. Use only in well-ventilated areas. Do not breath vapours. Keep away from sources of ignition - no smoking. Take precautionary measures against static discharges. Do not mix with other products. Wear personal protection equipment (see section 8). Do not eat, drink and smoke in work areas. Wash hands after use. Remove contaminated clothing and protective equipment before entering eating areas. 9.2. Conditions for safe storage, including any incompatibilities Keep away from heat and direct sunlight. Keep container tightly closed. Storage class (VCI): 12. 9.3. Specific end uses See section 1.2. GISBAU product code: CGL 10. Last modified on: 2013 0610 Page 5 of 6
9.4 DOT transportation UN number --- UN proper shipping name --- Transport hazard class Not classified according to ADR. Packing group --- Environmental hazards Not hazardous according to 2.2.9.1.10 ADR. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is not intended for transport in bulk. SECTION 10: Regulatory information / Disclaimer Prepared By: Emergo Metal Treatment Regulatory information: The MSDS is based on the format of REGULATION (EU) 1907/2006 and (EU) 453/2010 annex 1. 10.1 Text of R-Phrases, H-Statements: Only the R-Phrases and H-Statements of the dangerous substances of the mixture are mentioned here: R 10 Flammable. R 11 Highly flammable. H 225 Highly flammable liquid and vapour. H 226 Flammable liquid and vapour. 10.2 Process categories according to ECHA guidance (REACH EU 1907/20060:. PROC 11 (Spraying outside industrial settings): Processing with large-scale spraying (e. g. high pressure cleaning, foam gun). Normal precautions: Good industrial practice requires adequate ventilation of the workplace. During machining, dust must be removed adequately by ventilation etc. Use of a local exhaust system will remove safely all fumes and dust during processing and secondary operations. Disclaimer: As the conditions of methods of use are beyond our control, we, as Emergo Metal Treatment, do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, expressed or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state, and local laws and regulations remains the responsibility of the users. Last modified on: 2013 0610 Page 6 of 6