Page 1 of 6 Company Ivoclar Vivadent AG, Bendererstrasse 2, FL - 9494 Schaan Principality of Liechtenstein 1 1.1 Commercial product name and supplier Commercial product name / Designation 1.2 1.3 1.4 Application / Use Producer Supplier TOX emergency number Public Ivoclar Vivadent AG, Bendererstrasse 2, FL - 9494 Schaan Fürstentum Liechtenstein Emergency-Call: +423 / 235 35 35 or 373 40 40 Ivoclar Vivadent AG, FL-9494 Schaan, Liechtenstein 2 Hazards identification Irritating to eyes, respiratory system and skin. Dust generation 3 3.1 3.2 3.3 Composition Chemical characterization Hazardous components CAS No. 497-19-8 Powder of calcium carbonate and sodium carbonate 50 % Sodium carbonate EINECS/ELINCS No.: 207-838-8 Xi: Irritant. R36: Irritating to eyes. 4 First aid measures 4.1 4.2 4.3 4.4 4.5 Eye contact Skin contact Ingestion Inhalation Flush eyes with plenty of water (10-15 min.). Call a physician. Wash thoroughly with water. After ingestion call a physician immediately and show packaging or label. Give large amounts of water. Take into fresh air.
Page 2 of 6 5 5.1 5.2 5.3 Fire-fighting measures Suitable extinguishing media Extinguishing media to avoid Water fog. Carbon dioxide. Extinguishing powder. Do not use direct water stream. 6 Accidental release measures Clean up mechanically. Dispose of according to local and national regulations. 7 7.1 7.2 7.3 7.4 7.5 Handling and storage Handling Industrial hygiene Storage Place of storage Fire- and explosion-protection Only adequately trained personnel should handle this product. Avoid dust build-up. Keep out of reach of children. Usual hygienic measures for dental practice. Avoid breathing dust. When using, do not eat, drink or smoke. Store at 2-28 C / 36-82 F Store in a dry place. 8 Exposure controls / Personal protection 8.1 8.2 8.3 8.3.1 8.3.2 8.3.3 8.3.4 Exposure controls Exposure limit values Occupational exposure controls Respiratory protection Hand protection Eye protection Other Provide adequate local ventilation. Producer Industry recommends an exposure limit of 10 mg/m3. Avoid breathing dust. In dusty atmospheres, use an approved dust respirator. Gloves. Safety goggles. Use only with adequate ventilation. 8.4 Environmental exposure controls
Page 3 of 6 9 9.1 9.2 9.3 Physical and chemical properties Appearance Colour Odour powder white odourless 9.4 Change of physical state Test method: 9.5 9.6 9.7 9.8 Density Vapour pressure Viscosity Solubility Solubility in water not determined partially miscible 9.9 ph > 8 9.10 9.11 9.12 9.13 Flash point Ignition temperature Explosion limits Part. coeff. n-octanol/water Evaporat. rate not flammable Lower: Upper: 10 10.1 Stability and reactivity Thermal decomposition 10.2 Hazardous decomposition products None, if used in accordance to instructions. 10.3 10.4 Conditions / materials to avoid None known.
Page 4 of 6 11 11.1 11.2 Toxicological information Acute toxicity Subacute / Chronic toxicity Oral LD50 for rats: > 5000 mg/kg Excessive exposure may cause eye and respiratory irritation. 11.3 12 12.1 12.2 12.3 12.4 12.5 Ecological information Ecotoxicity Mobility Persistence and degradability Bioaccumulative potential No data available. No specific ecological effects. No data available. No data available. partially miscible No ecological problems to be anticipated if properly handled and used. German 'Wassergefaehrdungs Klasse (WGK)': 0 13 Disposal considerations Take to an approved landfill or a waste incineration plant, under conditions approved by the local authority. 13.1 EU waste key 18 01 06 14 Transport information 14.1 Transport at land ADR RID UN Number Kemler Number Packing Group Proper shipping name 14.2 Transport at sea ADNR IMDG UN Number EMS MFAG Packing Group Proper shipping name Marine pollutant
Page 5 of 6 14.3 Air transport ICAO / IATA-DGR UN Number Proper shipping name Passenger airplane Cargo Airplane Subsidiary Risk Labels Packing Group Packing Instructions max. Packing Instructions max. 14.4 Product is not classified as a dangerous good for transport. 15 Regulatory information This product requires classification according to the criteria of the "Gefahrstoffverordnung". 15.1 15.2 UN number National regulations 15.3 15.4 EINECS/ELINCS number Hazard symbols Xi 15.5 Hazard designation Xi: Irritant. Contains Sodium carbonate. 15.6 15.7 Risk phrases Safety phrases 15.8 MAK value ml/m³ (ppm) 15.9 15.10 15.11 BVD classification (CH) VbF (D) R: 36/37/38 36/37/38 S: 2-26-36 Irritating to eyes, respiratory system and skin. 2 Keep out of the reach of children. 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advise. 36 Wear suitable protective clothing.
Page 6 of 6 16 Other information The above mentioned data correspond to our present state of knowledge and experience. The safety data sheet serves as description of the products in regard to necessary safety measures. The indications do not have the meaning of guarantees on properties. This safety data sheet has been generated with the safety database 'ChemManager', ASSiST Applied Software Solutions in Science and Technology AG, Weiherweg 3, CH-4104 Oberwil, Switzerland Regulation (EC) No 1907/2006 (REACH)