MATERIAL SAFETY DATA SHEET MSDS. Omni Breakout Extra

Similar documents
MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET MSDS. Calcium Hypochlorite Tablets

MATERIAL SAFETY DATA SHEET MSDS. Refresh Dry Chlorinating Granular for Swimming Pools

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET MSDS. Sun Non-Foaming Algaecide 60

MATERIAL SAFETY DATA SHEET MSDS. Spa Essentials Brominating Concentrate

MATERIAL SAFETY DATA SHEET MSDS. Omni Super Algae Destroyer

MATERIAL SAFETY DATA SHEET MSDS. Omni Brominating Tablets for Pools

MATERIAL SAFETY DATA SHEET MSDS

MATERIAL SAFETY DATA SHEET MSDS. Sun Winter Algaecide 40

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET MSDS. Pro Care Granular Chlorinator

MATERIAL SAFETY DATA SHEET MSDS. Aqua Chem Balanced For Clean Pools Shock Xtra Blue

MATERIAL SAFETY DATA SHEET MSDS. Omni Stabilized Chlorinating Granules

MATERIAL SAFETY DATA SHEET MSDS

MATERIAL SAFETY DATA SHEET MSDS. Regal Chlorinated Tablets 3"

MATERIAL SAFETY DATA SHEET MSDS. Sun Super Quest

Safety Data Sheet. 1,3-dichloro-5,5-dimethylhydantoin. Spa and hot tub sanitizer

MATERIAL SAFETY DATA SHEET MSDS. Omni Breakout 35

Material Safety Data Sheet OMNI ALGAE TERMINATOR

MATERIAL SAFETY DATA SHEET

ProGuard Granular Calcium Hypochlorite

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET MSDS. Omni Spa Shock Treatment

BioGuard Inhibit Optimizer Plus

BioGuard Softswim Filter Aid

MATERIAL SAFETY DATA SHEET MSDS. Omni Crystal Clear Multi-Shock

MATERIAL SAFETY DATA SHEET MSDS. Sun Sun-Brite Non-Chlorine Shock Treatment

MATERIAL SAFETY DATA SHEET

CAUTION! Form: liquid. BioGuard Remedy Banish SECTION 1. PRODUCT AND COMPANY IDENTIFICATION. BioGuard Remedy Banish

SIMPLICITY SALINE WEEKLY. Recreational Water Product. Asepsis, Inc. Simplicity P.O. Box 1788 Suwanee, GA

Spa Essentials Brominating Tablets for Spas & Hot Tubs

SAFETY DATA SHEET. Blue Wave Sanitizing Granules

Material Safety Data Sheet BIOGUARD OFF SEASON ARCTIC BLUE ALGAE PROTECTOR

Version: 1.1 Revision Date: 01/17/2014 Print Date: 03/21/2014 BIOGUARD INHIBIT SMART ALGICIDE

Version: 1.1 Revision Date: 01/01/2014 Print Date: 03/29/2014 BIOGUARD SALTSCAPES CELL CLEANER

Version: 1.3 Revision Date: 07/15/2011 Print Date: 10/14/2011 POOL TIME SHOCK TREATMENT

Spa Essentials Stain & Scale Control

ProGuard Brominating Tablets

Material Safety Data Sheet

Material Safety Data Sheet OMNI SYNERGY INITIATOR

Version: 1.1 Revision Date: 01/01/2014 Print Date: 03/05/2014 BIOGUARD SOFTSWIM FILTER AID

DANGER! Form: clear liquid GREASED LIGHTNING POWER TOILET BOWL CLNR SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

PoolTime Shock. Recreational Water Product. Recreational Water Products Pool Time PO Box 1449 Buford, GA

Material Safety Data Sheet THE WORKS AUTOMATIC TOILET TABLETS

DANGER! Form: granular. Omni Break Out 35 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION. Product name: Omni Break Out 35 Product Use Description:

ProGuard Stain & Scale Protector

SAFETY DATA SHEET. Fleet Brite. DISTRIBUTOR 24 HR. EMERGENCY TELEPHONE NUMBERS Truck Pro Inc

WARNING! Form: Viscous liquid SIMPLICITY POOL SURFACE CLEANER SECTION 1. PRODUCT AND COMPANY IDENTIFICATION SIMPLICITY POOL SURFACE CLEANER

Material Safety Data Sheet OMNI CHLORINATING STIX

Version: 1.2 Revision Date: 02/14/2012 Print Date: 05/21/2012 AQUA CHEM ALGAE FREE WATER ALGAE CONTROL

MATERIAL SAFETY DATA SHEET

Version: 1.1 Revision Date: 01/01/2014 Print Date: 03/05/2014 BIOGUARD OFF THE WALL

Material Safety Data Sheet BIOGUARD MAINTAIN SILK STICKS

MATERIALSAFETYDATASHEET

Material Safety Data Sheet SPA ESSENTIALS SPA SHOCK

Material Safety Data Sheet OMNI CONCENTRATED ALGAE KILL II

Material Safety Data Sheet BIOGUARD REMEDY SPOT KILL

Material Safety Data Sheet AQUA CHEM ALGAE ELIMINATOR

MATERIAL SAFETY DATA SHEET MSDS DATE: 7/5/11

Material Safety Data Sheet PROGUARD 3" TABLETS

Material Safety Data Sheet

MATERIAL SAFETY DATA SHEET MSDS DATE: 1/5/10

MATERIAL SAFETY DATA SHEET MSDS DATE: 1/31/12 YARDAGE TM

MATERIAL SAFETY DATA SHEET FractureÔ Fungicide

Bayer Environmental Science

Version: 1.0 Revision Date: 08/07/2013 Print Date: 08/07/2013 BIOGUARD CLC CLASSIC

BioGuard Maintain Silk Sticks

GREASED LIGHTNING POWER TOILET

MATERIAL SAFETY DATA SHEET MSDS DATE: 1/5/10

Page 1 of 5 Fine Replenish US GHS SAFETY DATA SHEET. Not Hazardous as defined by OSHA 29 CFR (GHS)

MATERIAL SAFETY DATA SHEET MSDS DATE: 1/29/13

STABILIZED CHLORINATING CONCENTRATED GRANULES FOR SPAS & HOT TUBS

SAFETY DATA SHEET TACKY TAPE SM5142BY. MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS ITW Polymers Sealants North America

Page 1 of 6 AdcoEco Laundry Detergent US GHS SAFETY DATA SHEET

SAFETY DATA SHEET TACKY TAPE SM5144. MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS ITW Polymers Sealants North America

Material Safety Data Sheet ANGRY EGG WHO PEED IN MY POOL?

Issue Date: 29-May-2015 Revision Date 24-May-2015 Version IDENTIFICATION BC.HS-1041 UN1759. Built Laundry Detergent

Version: 1.3 Revision Date: 08/01/2012 Print Date: 07/23/2013 OMNI BROMINATING TABLETS

SAFETY DATA SHEET. ERSystems Fabric Faced Butyl Tape. MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS ITW Polymers Sealants North America

Omni Chlorinating Stix

Material Safety Data Sheet WF1001C Coolant Additives

MATERIAL SAFETY DATA SHEET

SAFETY DATA SHEET. Shimmer. DISTRIBUTOR 24 HR. EMERGENCY TELEPHONE NUMBERS Pro Link, Inc.

Product: Calcium Hydroxide mixture

SAFETY DATA SHEET. Eco Pool & Spa Solutions Foam Out

SAFETY DATA SHEET. Robelle Industries 3-Month Algaecide. Page 1 of 5 1. PRODUCT AND COMPANY IDENTIFICATION

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET ADEPT ADEPT. Product name : Diflubenzuron. Chemical name: Insect Growth Regulator. Use of substance/preparation:

Material Safety Data Sheet

SAFETY DATA SHEET GHS LABEL ELEMENTS. Symbol(s): Signal Word: Warning

EARTH OPTIONS BY RAID - GRASS & WEED KILLER

SAFETY DATA SHEET. Veteran Miracle Finish. DISTRIBUTOR 24 HR. EMERGENCY TELEPHONE NUMBERS Cavalier Inc.

Resistant Bed Bug Powder

Material Safety Data Sheet. Calcium Hypochlorite Granular. NAPCO HTH, Cal Shock, Calcium oxychloride

Sturbridge Metallurgical Rev Date: Jan 2016

MATERIAL SAFETY DATA SHEET

SAFETY DATA SHEET GHS LABEL ELEMENTS. Symbol(s): Signal Word: Warning

SAFETY DATA SHEET. High Solids High Gloss Floor Finish. DISTRIBUTOR 24 HR. EMERGENCY TELEPHONE NUMBERS Hillyard Connecticut

Transcription:

Page 1 of 5 MATERIAL SAFETY DATA SHEET MSDS Omni Breakout Extra Date-Issued: 08/11/2004 MSDS Ref. No: AOMN22170 Date-Revised: 09/15/2004 Revision No: 3 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Omni Breakout Extra GENERAL USE: Swimming pool shock, oxidizer, and clarifier MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS Asepsis, Inc. Omni P.O. Box 1788 Suwanee, GA 30024-0973 Customer SERVICE: (800) 959-7946 COMMENTS: EPA Registration Number: 5185-496-10305 Poison Control Center (Medical) : (877) 800-5553 CHEMTREC (US Transportation) : (800) 424-9300 2. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name CAS# Wt.% Calcium Hypochlorite 7778-54-3 47 Calcium Hydroxide 1305-62-0 1-5 Calcium Carbonate 471-34-1 0-2 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW PHYSICAL APPEARANCE: White, granular material IMMEDIATE CONCERNS: DANGER: Corrosive: Causes irreversible eye damage and skin burns. Harmful if swallowed. Harmful if absorbed through skin. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Avoid contact with skin, eyes or clothing. Wear protective eyewear (goggles or safety glasses). Wear protective clothing and rubber gloves when handling this product. Irritating to nose and throat. Avoid breathing dust and fumes. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum or using tobacco. Remove contaminated clothing and wash contaminated clothing before reuse. POTENTIAL HEALTH EFFECTS EYES: Corrosive. Causes irreversible eye damage. Do not get in eyes. SKIN: Causes skin burns. Do not get on skin. SKIN ABSORPTION: Harmful if absorbed through skin. INGESTION: Harmful if swallowed. INHALATION: Irritating to nose and throat. Avoid breathing dust or fumes. CHRONIC: There are no known chronic hazards. MEDICAL CONDITIONS AGGRAVATED: Persons with preexisting skin disorders are more susceptible to the effects of this product. ROUTES OF ENTRY: Skin Contact, Inhalation, Ingestion, Eye Contact. SENSITIZATION: Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. 4. FIRST AID MEASURES

Omni Breakout Extra Page 2 of 5 EYES: If in eyes: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN: If on skin or clothing: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advise. INGESTION: If swallowed: Call poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by the poison control center or doctor. Do not give anything by mouth to an unconscious person. INHALATION: If inhaled: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth, if possible. Call poison control center or doctor for treatment advice. NOTES TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not Flammable GENERAL HAZARD: Calcium Hypochlorite is a strong oxidizing agent. May form explosive mixtures with combustible, organic or other oxidizable materials. EXTINGUISHING MEDIA: In case of fire or smoke, call the fire department. Do not attempt to extinguish the fire without a self-contained breathing apparatus (SCBA). Do not let the fire burn. Flood with copious amounts of water. DO NOT use ABC or other dry chemical extinguishers since there is the potential for a violent reaction. Water in contact with hot Calcium Hypochlorite can release hydrochloric acid or chlorine gas. HAZARDOUS COMBUSTION PRODUCTS: Chlorine, oxygen and chlorine monoxide at higher temperature. FIRE FIGHTING PROCEDURES: Firefighters should wear full protective clothing and self-contained breathing apparatus (SCBA). Using a 10% solution of sodium carbonate, thoroughly decontaminate fire fighting equipment including all fire fighting apparel after the incident. 6. ACCIDENTAL RELEASE MEASURES GENERAL PROCEDURES: Using appropriate protective clothing and safety equipment, contain spilled material. Do not add water to spilled material. Using clean dedicated equipment, sweep and scoop all spilled material, contaminated soil, and other contaminated material and place into clean dry containers for disposal. Do not use floor sweeping compounds to clean up spills. Do not close containers containing wet or damp material. They should be left open to disperse any hazardous gases that may form. Do not transport wet or damp material. Keep product out of sewers, watersheds and water systems. Do not contaminate water, food, or feed by storage or disposal or cleaning of equipment. Dispose of according to local, state and federal regulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: Avoid contact with eyes, skin or clothing. Avoid breathing dust or fumes. HANDLING: Contains a Strong Oxidizing Agent. Do not mix with other chemicals. Mix only with water. Never add water to product. Always add product to large quantities of water. Use clean dry utensils. Do not add this product to any dispensing device containing remnants of any other product. Such use may cause a violent reaction leading to fire or explosion. Contamination with moisture, organic matter or other chemicals may start a chemical reaction and generate heat, hazardous gas, possible fire and explosion. In case of contamination or decomposition, do not reseal container. If possible, isolate container in open air or well ventilated area. Flood area with large volumes of water. STORAGE: Keep this product dry in original tightly closed container when not in use. Store in a cool, dry, well ventilated area away from heat or open flame. Moisture may decompose this product and cause a violent reaction leading to fire and explosion. In case of decomposition, isolate container if possible and flood area with large amounts of water to dissolve all material before discarding this container. Do not contaminate food or feed by storage or disposal. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200)

Omni Breakout Extra Page 3 of 5 Calcium Hypochlorite TWA N/E [1] N/E EXPOSURE LIMITS OSHA PEL ACGIH TLV SUPPLIER OEL ppm mg/m 3 ppm mg/m 3 ppm mg/m 3 Calcium Hydroxide TWA 5 5 Calcium Carbonate TWA 15 10 OSHA TABLE COMMENTS: 1. N/E = Not Established ENGINEERING CONTROLS: General room ventilation plus local exhaust should be used to maintain exposure below TLV. PERSONAL PROTECTIVE EQUIPMENT: EYES AND FACE: Wear goggles or safety glasses with side shields when handling this product. SKIN: Wear rubber gloves when handling this product. Avoid contact with skin. RESPIRATORY: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. WORK HYGIENIC PRACTICES: Remove and wash contaminated clothing before reuse. OTHER USE PRECAUTIONS: Facilities storing or utilizing this material should be equipped with an eyewash and safety shower. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Solid ODOR: Chlorine APPEARANCE: Granules COLOR: White ph: 8.95(5% solution) VAPOR PRESSURE: Not Established VAPOR DENSITY: Not Established BOILING POINT: Not Applicable FREEZING POINT: Not Applicable MELTING POINT: Not Established THERMAL DECOMPOSITION: >100 C SOLUBILITY IN WATER: 18g / 100g water SPECIFIC GRAVITY: 2.35 (water=1) at 20 C ODOR THRESHOLD: 0.02-0.35 ppm based on chlorine. COMMENTS: DENSITY: Bulk Density (granules) = 0.97 g/cc 10. STABILITY AND REACTIVITY CONDITIONS TO AVOID: High temperature. Poor ventilation. Contamination. Moisture/high humidity. STABILITY: This product is stable under normal conditions. POLYMERIZATION: Hazardous polymerization will not occur under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: Chlorine, oxygen and chlorine monoxide at higher temperatures. INCOMPATIBLE MATERIALS: This product contains a strong oxidizing agent. Avoid contact with water on concentrated material in the container. Keep away from household soap, suntan lotion, paint products, solvents, acids, beverages, lighted cigarettes, combustible materials, garbage, dirt, dirty rags, organic materials and other swimming pool/spa chemicals in their concentrated forms. Mixing with any of the above materials can initiate a hazardous decomposition. Contact with acids or moisture evolves chlorine gas. Reacts with ammonia, urea and amines (can form reactive and toxic chloramines). Metal oxides can cause decomposition.

Omni Breakout Extra Page 4 of 5 11. TOXICOLOGICAL INFORMATION ACUTE DERMAL LD 50 : >2000 mg/kg of body weight in rabbits. Primary Irritation Study (rabbit) = 7.3 (corrosive) ORAL LD 50 : 1195 mg/kg of body weight in rats EYE EFFECTS: This product is corrosive to eyes. SKIN EFFECTS: This product is corrosive to skin. SENSITIZATION: This product is a potential skin sensitizer. CARCINOGENICITY: This product is not listed as a carcinogen by IARC. This product is not listed as a carcinogen by NTP. This product is not listed as a carcinogen by OSHA. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: This pesticide is toxic to fish and aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: Pesticide wastes are toxic. Improper disposal of excess pesticide or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions, contact your State Pesticide or Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. Do not contaminate water, food, or feed by storage or disposal or cleaning of equipment. Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. Contact with incompatible materials could cause a reaction or fire. EMPTY CONTAINER: Do not reuse container, but place in trash collection. Rinse thoroughly before discarding in trash. GENERAL COMMENTS: Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. Contact with incompatible materials could cause a reaction or fire. Do not reuse container. Rinse throughly before discarding in trash. Disposal of unused, uncontaminated product is regulated according to local, state and federal regulations. 14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Corrosive Solids, N.O.S. (calcium hypochlorite mixture) PRIMARY HAZARD CLASS/DIVISION: 8 (Corrosive) UN/NA NUMBER: UN1759 PACKING GROUP: II OTHER SHIPPING INFORMATION: This mixture is not an oxidizer based on UN/DOT Test 0.1 and EU A-17 (standard tests for oxidizing solids). 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: FIRE: NO PRESSURE GENERATING: NO REACTIVITY: YES ACUTE: YES CHRONIC: NO 313 REPORTABLE INGREDIENTS: This product or its components are not listed. CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT)

Omni Breakout Extra Page 5 of 5 CERCLA REGULATORY: This product is listed as a CERCLA Hazardous Substance. CERCLA RQ: Calcium hypochlorite RQ is 10 lb. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: This product or its components are not subject to export notification. TSCA STATUS: This product or its components are listed on the TSCA Inventory. OSHA HAZARD COMM. RULE: Product is hazardous by definition of the Hazardous Communication Standard. CLEAN WATER ACT: This product is listed as a hazardous substance under the Clean Water Act. FIFRA (FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT): This product is a registered pesticide. SDWA (SAFE DRINKING WATER ACT): Not listed. 16. OTHER INFORMATION PREPARED BY: Regulatory Affairs Department REVISION SUMMARY Revision #: 3 This MSDS replaces the September 03, 2004 MSDS. Any changes in information are as follows: In Section 16 Section 16 Footnotes NFPA Classification HMIS RATING HEALTH: 3 FLAMMABILITY: 0 PHYSICAL HAZARD: 1 PERSONAL PROTECTION: B NFPA RATING HEALTH: 3 FIRE: 0 REACTIVITY: 1 Key 4 = Severe 3 = Serious 2 = Moderate 1 = Slight 0 = Minimal NFPA STORAGE CLASSIFICATION: NFPA Oxidizer Class 1 Note:Based on third party testing results, for storage this product exhibits the characteristics of a National Fire Protection Association (NFPA) Class 1 Oxidizer per NFPA 430. MANUFACTURER DISCLAIMER: IMPORTANT: This information is given without a warranty or guarantee. No suggestions for use are intended or shall be construed as a recommendation to infringe any existing patents or violate any Federal, State or local laws. Safe handling and use is the responsibility of the customer. Read the label before using this product. This information is true and accurate to the best of our knowledge. COMMENTS: The contents and format of this MSDS are in accordance with OSHA Hazard Communication Standard, National Fire Protection Association (NFPA), and Hazardous Materials Identification System (HMIS).