Latest Developments In R&D Support for Forest Biorefinery Development In Canada 2017 BIO World Congress

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Latest Developments In R&D Support for Forest Biorefinery Development In Canada 2017 BIO World Congress July 24 th 2017, Montréal, Canada Eric Soucy Director, Industrial Systems Optimization Her Majesty the Queen in Right of Canada, as represented by the Minister of Natural Resources, 2017

CanmetENERGY Three Scientific Laboratories across Canada 2 CanmetENERGY is the principal performer of federal nonnuclear energy science & technology (S&T): Fossil fuels (oil sands and heavy oil processing; tight oil and gas); Energy efficiency and improved industrial processes; Clean electricity; Buildings and Communities; and Bioenergy and renewables. Areas of Focus: Buildings energy efficiency Industrial processes Integration of renewable & distributed energy resources RETScreen International Varennes Areas of Focus: Oil sands & heavy oil processes Tight oil & gas Oil spill recovery & response Devon Areas of Focus: Buildings & Communities Industrial processes Clean fossil fuels Bioenergy Renewables Ottawa

Industrial Systems Optimization Program What we do? CanmetENERGY s ISO Program focuses on innovative facility-wide optimization techniques (i.e. systems approach): Improve plants design and operation Effective introduction of new technologies (e.g. Hx, CO 2 capture, biorefinery, CHP) Four main R&D areas: Heat Management Cogeneration Optimization Advanced Data Analytics Biorefinery Energy, water and materials savings of 10 to 35% are typical Energy-intensive industries: pulp and paper, refining, petrochemicals, oil sands 3

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Data Source: IEA Statistics, 2014 Bioenergy: Place of Canada in the World 6 As compared to 2012, Canada increases its bioenergy shares by 9%. Combustible renewables and waste (% of total energy use) Combustible renewables and waste (% of total energy use) 0% 0% 5% 10% 15% 20% 25% 5% 10% 15% 20% 25% Her Majesty the Queen in Right of Canada, as represented by the Minister of Natural Resources, 2016 Her Majesty the Queen in Right of Canada, as represented by the Minister of Natural Resources, 2016 30% 30%

7 Forest Pulp and paper Industry Context Pulp and paper industry is in an on-going transformation to increase profitability: Lower production costs Energy efficiency projects, reduce cost of GHG emissions, reduce losses, improve operations Increase annual revenues Install new turbines and produce additional "green" power; tackle new markets Diversify production Change grade of commodity products; develop innovative new bio-products Optimizing energy integration is essential to reduce operating costs, lower GHG emissions, add new revenues and prepare pulp and paper mills for the low-carbon economy. Pulp mills are perfect host site for biorefinery technology integration!

Process Optimization in Pulp and Paper Industry Approach combining several systems analysis tools 8 Innovation Through Integrated Solutions EXPLORE I-BIOREF INTEGRATION COGEN

Process Optimization in Pulp and Paper Industry Advanced Data Analytics 9 Valuable process knowledge is hidden in historical database Large amount of data is available in mills Difficult to fully understand the links and interactions between data Data analytic techniques can help extract this knowledge Statistical analysis to explain process variability and improve operation Statistical models to maintain performance over time

Process Optimization in Pulp and Paper Industry Utility Systems 10 Most cogeneration systems are not used in an optimal way

Process Optimization in Pulp and Paper Industry Utility Systems (cont d) A detailed model of the utility system is used and the optimal steam path that minimizes the total operating cost is determined: optimize existing system and maximize economic benefits from steam savings COGEN 11 Benefits will be maximized year-round by considering contractual, operational and environmental constraints on different time periods

12 Process Optimization in Pulp & Paper mills FPInnovations CanmetENERGY CFS Successful Partnership Results obtained by combining Heat management, Cogeneration optimization and Data analytics: $50M+ in cost-effective annual savings and additional revenues identified

Forest Biorefinery R&D Program 13 General Objectives Develop and deploy science and technology of emerging biorefinery concepts in close collaboration with Canadian forest industry and manufacturers, and national and international research institutions. Specific Objectives Develop updated biorefinery and bioenergy technology map, as well as current and emerging market trends of bioenergy, biofuels, biochemicals, and biomaterials Develop systems engineering models and decision-making tools to evaluate the most promising biorefinery products/technologies that, when optimally integrated to an existing industrial site, will result in radically improved economic performance and environmental footprint Develop state-of-the-art retrofit and design solutions to enable the transformation of traditional forest markets through incremental implementation of biorefineries

Biorefinery R&D Program: Focus Areas 14 Bioenergy Biofuels Biochemicals Advanced Biomaterials Technological intelligence Data analysis Cogeneration Markets Bioenergy La Tuque Markets Rich-Sugar streams Biobutanol Organic acids Markets Tannins Lignin-based polyols Carbon fiber CFS, FPInnovations, pulp and paper mills CFS, BELT, UQTR, FPInnovations, Polytechnique Montréal, Université Laval, VTT CÉPROCQ, CRIBIQ, UQTR, Forestry COOPs NRC, CRIBIQ, Forest COOPs, Domtar, Enerlab, Pure Lignin Environment Technology Ltd.

I-BIOREF: A Biorefinery Pre-Feasibility Analysis Software 15

I-BIOREF: Why such tool? 16 How can a company succeed in identifying a strategy to enter the bioeconomy that is robust for future market scenarios, and at the same time, yields high margins? What are the benefits of integrating a biorefinery technology into an existing mill? In an integrated biorefinery, what are the impacts on the existing mill? Under what conditions does a biorefinery project becomes economically and environmentally viable? Make the analysis easier, faster and cheaper!

Approach 17 Market assessment and technological intelligence Mapping of resources utilization in pulp and paper mills Data on available biomass and competitive pricing strategy Market data on bioenergy, biochemicals and biomaterials Critical review of Canadian bioenergy and biorefinery demonstration projects Extensive technological intelligence on biorefinery processes and innovations Modeling, algorithms development, simulation, and experiments Experiments Extractives Pre-treatment/fractionation Detoxification of cellulosic hydrolysates Sugar extraction and fermentation Lignin recovery from black liquor Full characterization of lignin properties from various sources (up to 90 samples) ASPEN Plus Modeling Pre-treatment/fractionation Lignin recovery Sugar extraction and fermentation Separation/purification Multi-criteria analysis Technical performance Economic viability Environmental footprint Risk assessment Computer Modeling, Simulation & Optimization of Integrated and Standalone Biorefineries Outputs: Prefeasibility scenarios for integrated and standalone biorefineries Industrial case studies Guidelines, engineering rules and expert tips for designing and implementing biorefineries Knowledge, know-how and technology transfer

I-BIOREF Software: What it does? 18 I-BIOREF supports decision-makers in selecting viable biorefinery solutions I-BIOREF evaluates the benefits of integrating commercially available biorefinery processes I-BIOREF provides several criteria to assess the biorefinery project from different perspectives I-BIOREF performs sensitivity analysis to evaluate the impacts on resources utilization Comprehensive mass and energy balance, and chemical balance 6 economic metrics (PBP, IRR, NPV, ROCE, ROI, EBIDTA) 2 competitiveness metrics (CAB, RTMU) Competitive access to biomass Resistance to market uncertainties 17 LCA-based metrics Mid-point impact category (carcinogens, respiratory inorganics, land occupation, etc.) Damage category (climate change, human health, ecosystem quality, etc.) Pulp and paper processes: Kraft and TMP Biomass pretreatment processes: Steam explosion; Liquid hot water; Acid hydrolysis; Alkaline hydrolysis; Instant controlled pressure; Organosolv; Torrefaction Pre-extraction processes Supercritical fluids (e. g. CO 2 ); Hot water;, Enzymatic Lignin recovery processes: LignoBoost TM ; LignoForce TM Sugar streams conversion processes: Detoxification; Fermentation; Separation/Purification Thermochemical processes: Gasification; Pyrolysis; Catalysis I-BIOREF is not a process simulation software!

CanmetENERGY-Varennes Industrial Systems Optimization (ISO) Program 19 SYSTEM ANALYSIS SOFTWARE SERVICES Research Knowledge Industrial projects INTEGRATION Identify heat recovery opportunties in your plant EXPLORE Discover the power of data to improve operation TRAINING Attend workshops with world class experts Knowledge Transfer COGEN Maximize revenues from cogeneration systems I-BIOREF Evaluate biorefinery strategies KNOWLEDGE Access to publications and industrial case studies

Support for Forest Biorefinery Development Concluding Remarks 20 Process optimization is key to design highly-efficient Biorefinery pulp mills Leveraging on existing assets is key in supporting the transformation In retrofit situations, steam and water savings of 10 to 20% are possible cost-effectively. Increased power generation is also typical. Develop a long term vision for implementing energy saving projects and robust biorefinery technologies: Permits a gradual implementation that mitigate the implication of short-term modifications over long-term high impact solutions Analysis of biorefinery pathways for integration at existing mills Analysis of biorefinery pathways and how mill existing assets can evolve to reduce implementation costs, notably by debottlenecking key process equipments Assessment of economic and environmental impacts of biorefinery technology integration into existing or new industrial facilities Decision support system includes knowledge-based systems and emphasizes flexibility and adaptability to accommodate changes in the environment and the decision-making approach of the forest industry

Thank you for your time and attention! For further information, please contact: Eric Soucy, Director Industry Program, CanmetENERGY Varennes Tel.: +1 450 652 4299 Email: eric.soucy@canada.ca Marzouk Benali, Senior Research Scientist Forest Biorefinery Manager, CanmetENERGY Varennes Tel.: 1 450 652 5533 Email: marzouk.benali@canada.ca / Her Majesty the Queen in Right of Canada, as represented by the Minister of Natural Resources, 2017