Revised edition: 24.01.2014 1. 1. 1. Version: 1.0 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Shellac Wax 1. 2. Article No.: 60550 Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: Surface finish, binding agent, glue, food additive (coating, glazing, anti-sticking agent) 1. 3. Uses advised against: Details of the Supplier of the Safety Data Sheet 1. 4. 2. 2. 1. 2. 2. 2. 3. Company: Address: Tel./Fax.: Internet: EMail: Emergency No. Emergency No.: Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 Hazard designation: Signal word: Hazard designation: Safety designation: Hazardous components for labelling: Other Hazards Mon-Droguiste.Com 39 Bis Rue Du Moulin Rouge - 10150 CHARMONT SOUS BARBUISE Tel 03.25.41.04.05, Fax 03.25.41.06.16 www.mon-droguiste.com contact@mon-droguiste.com SAMU : 15 - Pompiers : 18 This product is not classified as hazardous according to the CLP/GHS Directive. The material is not subject to classification according to EC lists. This product does not require classification and labelling as hazardous according to CLP/GHS. Not applicable. 2
3. Composition/Information on Ingredients 3. 1. Substance 3. 2. Mixture Page 2 Chemical Characterization: CAS No. 9000-59-3, EINECS 232-549-9 Hazardous Ingredients: 4. 4. 1. Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Shellack complies with the definition of a polymer: exempted from the mandatory REACH Registration. Remove contaminated clothes. No special measures required. Remove contaminated clothing. Wash off immediately with plenty of water and soap. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. 4. 2. After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth with plenty of water and consult physician. Symptoms: No further information available. 4. 3. Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed 5. 5. 1. Treatment: Fire-Fighting Measures Extinguishing Media Suitable extinguishing media: Treat symptomatically. Foam, CO2, dry extinguishing powder. 5. 2. Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known. 5. 3. Special hazards: Advice for Firefighters In case of fire: formation of carbon oxides. Protective equipment: 3
No special measures required. Page 3 6. 6. 1. Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Cool exposed containers with water spray. Contaminated extinguishing water and debris should be disposed of according to local regulations. 6. 2. Personal precautions: Environmental Precautions Wear protective clothing. Avoid contact with skin, eyes and clothing. Avoid formation of dust. 6. 3. Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soil, drains and surface waters. 6. 4. 7. 7. 1. Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. See Section 13 for information on disposal. Protective clothing, see Section 8. Provide good ventilation and/or exhaust at the workplace. Ensure adequate ventilation. Handle and open container with care. Avoid contact with eyes and skin. Do not swallow or inhale. 7. 2. Hygienic measures: Conditions for Safe Storage, including any Incompatibilities Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Take off contaminated clothing immediately. Store working clothes separately. Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Store product in a cool, dry and well ventilated area. Store product below 15 C. Do not store together with: oxidants. No special measures necessary. Keep away from sources of ignition - do not smoke. 4
Storage class (VCI): Page 4 7. 3. 8. 8. 1. Further Information: Specific End Use(s) Further information: Exposure Controls/Personal Protection Parameters to be Controlled Parameters to be controlled (DE): none known Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): 8. 2. Additional Information: Exposure Controls Technical protective measures: Provide adequate ventilation. Personal Protection General protective measures: Respiratory protection: Hand protection: Protective glove material: Eye protection: Body protection: Keep away from foodstuffs and drinks. Do not eat, drink or smoke during work. Wash hands before breaks and at the end of work. Not required. Protective gloves (EN 374) Butyl rubber (480 min; 0.5 mm). Nitrile rubber (480 min, 0.35 mm) Neoprene. Safety glasses with protective shields (EN 166). Protective clothing. 9. 9. 1. Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Prevent contamination of open water ways and sewage system. Avoid contamination of ground water. Form: Color: solid yellow - brownish 5
Odor: weak Page 5 Odor threshold: ph-value: not available Melting temperature: 70-105 C Boiling temperature: not determined Flash point: > 300 C Evaporation rate: Flammability (solid, gas): 9. 2. Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: Coefficient of variation (n- Octanol/Water): Auto-ignition temperature: Decomposition temperature: Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information no information available no information available not determined insoluble not determined not available Product is not explosive; however, an explosive dust/air mixture can be formed. no information available ca. 400 kg/m3 Solubility in solvents: 6
Viscosity, kinematic Page 6 10. 10.1. 10.2. 10.3. 10.4. 10.5. 10.6. 10.7. 11. 11. 1. Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: Thermal decomposition: Imcompatible Materials Hazardous Decomposition Products Further Information Toxicological Information Information on Toxicological Effects Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: Primary effects Irritant effect on skin: Irritant effect on eyes: Inhalation: Ingestion: No further information. Stable if used according to specifications. Stable if used according to specifications. No further information available. Strong oxidizing agents. None if stored and handled according to specifications. > 5000 mg/kg (rat) > 10000 mg/kg (rabbit) The dust particles can cause mechanical irritation. Dust may cause irritation. Non irritating. No information available 7
Sensitization: Not known. Page 7 12. 12. 1. 12. 2. 12. 3. 12. 4. 12. 5. 12. 6. Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: Algae toxicity: Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: Further ecological effects: AOX Value: No health impairments known or expected when used according to specifications. Inhalation: Long-term overexposure can irritate the respiratory tract and cause coughing. EC50: > 500 mg/l (24h, Daphnia magna) no information available LC50: > 400 mg/l (24h) 34 % (28d); biodegradable (OECD 301E) Do not let product contaminate ground water, waterways or sewage system. 8
13. 13. 1. Disposal Considerations Waste Treatment Methods Page 8 Product does not contain any organically bound halogen. Product: If product cannot be reused or recycled, it has to be disposed of according to current local regulations. European Waste Code (EWC): Uncleaned packaging: Packaging may be disposed of in the same manner as the product. 14. 14. 1. 14. 2. Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: No hazardous goods according to ADR (land transportation). IMDG/IATA: No hazardous goods according to IMDG. 14. 3. Transport Hazard Classes ADR Class: Hazard no.: Classification code: Tunnel no.: IMDG Class (sea): Hazard no.: EmS No.: IATA Class: Hazard no.: 14. 4. Packaging Group ADR/RID: IMDG: IATA: 14. 5. Environmental Hazards Not classified as environmentally hazardous. 9
14. 6. 14. 7. 14. 8. 15. 15. 1. Special Precautions for User Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Page 9 Not classified as a dangerous good under transport regulations. Not classified as a dangerous good under transport regulations. Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water Not listed. 15. 2. 15. 3. 16. Employment restrictions: Restriction and prohibition of application: Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information Shellack complies with the definition of a polymer: exempted from the mandatory REACH Registration. This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.