SOIL ACIDIFICATION. Clain Jones ) Rick Engel )

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SOIL ACIDIFICATION CAUSES and CONCERNS Montana Association of Conservation Districts Convention November 14, 2017 Clain Jones (clainj@montana.edu, 994-6076) Rick Engel (rengel@montana.edu, 994-5295) Montana SWCD and MSU Extension

Questions for you How many think you have seen yield losses from acidic soils? How many of you have soil ph levels below 5.5? How many have observed decreasing ph levels on your soil test reports? Suggestions for determining how widespread this problem is?

Objectives Show how number of acidic soils have been increasing in Montana Present natural and agronomic conditions that lead to acidic soils and some negative impacts Depict low-ph soil affected crops Present management options to slow acidification and increase productivity of acidic soil

Acidic soil samples (ph<6.5) are increasing in MT (though still rare) Unpub data Agvise

2017 MT counties with surface soil ph < 5.5 Sampled by MSU, low ph and/or high Al Reported by CCA or Ext Agent

Durum wheat aluminum toxicity due to low ph

Low soil ph is generally only in upper 6 inches Soil surface Engel, unpub data.

Natural reasons for low soil ph Soils with low buffering capacity (low soil organic matter, coarse texture), granitic > calcareous Historical forest vegetation > historical grassland, which developed greater buffering capacity

Agronomic reasons for low soil ph Ammonium-based N fertilizer above plant needs due to Nitrification: ammonium or urea fertilizer + air + H 2 O nitrate (NO 3- ) + acid (H + ) Leaching loss of nitrate prevents plants from buffering soil with basic anions (OH - and HCO 3- ) Crop residue removal removes Ca, Mg, K ( base cations) No-till concentrates acidity where N fertilizer applied Legumes acidify their rooting zone through N-fixation. Perennial legumes (e.g., alfalfa) more so than annuals (e.g., pea).

Soil ph and nutrient availability At low soil ph: Plants go hungry for some nutrients Nutrients can be lost to environment Al and Mn reach toxic levels Gov. W. Australia, Dept. Ag. and Food

Low ph increases soil Al to toxic levels 300 250 ph where yield declines occur Extractable Al (ppm) 200 150 100 50 0-3" 3-6" 6-12" Witches broom roots 0 Toxicity starts around 5 ppm -50 3.5 4.5 5.5 6.5 7.5 8.5 Soil ph Engel unpub. data, 2016, 5 farms near Highwood, MT

9 years of differing N rates on soil Mn levels in SK Bouman et al., 1995, Scott, SK. Mn toxic level from Moroni et al., 1991

Acid soils have many additional negative impacts Herbicide persistence (Raeder et al., 2015) Damage to rhizobia (N-fixing by legumes) Increase in fungal diseases Toxic H + levels (Kidd and Proctor, 2001) Images from Creative Commons

What to look for. Unexplained poor health in low or mid-slope areas Al toxicity stubby club roots (similar to nematode damage) small leaves, short thick internodes yellow along margin near tip on older leaves purple or brown lesions in chlorotic regions, indentations leaf withering and collapse in center Image KS State Research and Extension Field pea. A. Robson, https://agric.wa.gov.au/n/4487 Information and photo source: CIMMYT.org

What to look for. Unexplained poor health in low or mid-slope areas Mn toxicity cupping and crinkling chlorotic and reddening spots to necrosis starting on older leaves at tips and margins Image R. Norton, IPNI Information and photo source: CIMMYT.org

What to do if suspect low ph soil? 1. Soil test top 6 ph < 6 likely have spots with decreased yields (go to 2 below) 6 < ph < 7 don t assume you have no areas with low ph ph > 7, likely don t have problem (skip 2-4). 2. On top 3 where have low ph symptoms: Use ph color strips on a soil/water slurry or send sample to lab for ph (<5?) and KCl-extractable Al (> 5 ppm). Test 3-6 if might till. 3. OR: Compare Al and Mn tissue analysis from good and bad crop areas.

Managing low ph Remediate Use lime amendments (sugarbeet or Ag Lime) Consider occasional tillage (once in 5 years?) Plant acidtolerant perennial crops Adapt Plant Al-tolerant crops or varieties (e.g. Judee, Alum. See CARC webpage for variety trial data) Seed deeper? Fertilize after vulnerable seedling stage Prevent Optimize N use efficiency no left-over N Consider different N sources Retain crop residue

Steps to minimize and prevent soil acidification due to fertilizer N Increase efficiency of N use Base nitrogen rate on spring soil test and realistic yield potential Split nitrogen applications Reduce nitrate loss Use slow-release nitrogen sources Use nitrogen sources with nitrification inhibitors Recrop Plant deep or plant rooted deep crops rooted to catch crops deep to catch nitrate deep nitrate Consider using nitrogen sources other than urea, UAN, anhydrous, ammonium phosphate, or ammonium sulfate Legume rotations, manure Calcium ammonium nitrate (27-0-0)

Summary Cropland soils are becoming more acidic, largely due to N fertilization This reduces yields for several reasons Sound N fertilizer, crop, and residue management can slow or prevent soil acidification Crop and variety selection can help adapt to acid soils Liming, perhaps tilling, or planting perennials can mitigate acidification

Questions? Limed Not limed Image from Oregon State University, Lane County, OR 1926. For more information see the 2 Soil Scoops on soil acidification at MSU Soil Fertility website: http://landresources.montana.edu/soilfertility/soilscoop.html Eastern Oregon Liming Guide OSU EM9060, Soil Acidity in Oregon: Understanding and Using Concepts for Crop Production OSU EM9061 https://catalog.extension.oregonstate.edu/