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COATING TECHNOLOGIES EMI shielding by means of CREASHIELD R vacuum coating technology Some outstanding features of EMI shielding as carried out by the CREASHIELD process are: Ecellent shielding efficiency Straight forward and economical production process Minimal thermal influence Environmentally friendly CREASHIELD shielding technology and the CREAMET equipment designed for this technology have all been developed by CREAAC.

A. Introduction PRINCIPLE The application of metallic coatings for EMI shielding, in accordance with CREASHIELD technology, is carried out by means of the PD (physical vapour deposition) process in a high vacuum environment by using of thermal evaporation equipment. Thus the material to be applied is heated and transferred in the gas phase. As a result of condensation, the evaporated material is deposit onto the substrate. Depending on which procedure is used, single as well as multiple layers can be applied. The applied coating thicknesses are generally, for this application, about 2 µm but can be greater in accordance with specific requirements. Substrate apour Evaporator coil acuum chamber CHARACTERISTICS Coating materials: Metals (copper, aluminium, gold, silver, tin etc.) Alloys (nickel-chrome, etc.) Reactive process possible (SiO 2) Substrate materials: Plastics (ABS, PC, ABS/PC, PBT, PA, etc.) Metals and glass Coating: EMI application: ariant A (CREASHIELD Cu process) Layer thickness 150 nm 2.0 μm Structure Material Nickel-chrome Copper (electrically conducting layer) Substrate (plastic)

EMI application: ariant B (CREASHIELD Al process) Layer thickness 1.5 5.0 μm 50 nm Structure Material Aluminium (electrically conducting layer) Priming Substrate (plastic) Solderable shielding (CREASHIELD solder process) Layer thickness 1.5 3.0 μm 150 nm 2.0 μm Structure Material Tin Nickel-chrome (optional) Copper (electrically conducting layer) Substrate (plastic) HIGH ACUUM COATING EQUIPMENT Pressure appro. 1 10-4 mbar Batching time appro. 30 mins Pumping operation acuum chamber Control cabinet Polycold Oil diffusion pump MF G Roots pump Q B Rotary vane pump DK B Shutter G Q Evaporator DK Rotary cage MF alve

Coating capacity (eamples): CREAMET 1200 high vacuum coating equipment (chamber diameter 1,200 mm): appro. 1,500 parts per hour ( mm 45 mm mobile telephone housings) CREAMET rapid EMI high vacuum coating equipment (only for CREASHIELD Cu and CREASHIELD solder): appro. 3,000 parts per hour ( mm 45 mm mobile telephone housings) PLASTICS DATA Maimum possible Coating behaviour Plastic temperature [ C] short period long period very good good problematic ABS Acrylnitril/Butadien/Styrol 95 85 ABS/PC Coplymere * ASA Acrylnitril/Styrol/Acrylester 90 75 COC Cycloolefin-Copolymere EA Ethylvinylacetat 55 55 LCP Liquid crystal polymere 200 130 PA-6 Polyamid 6 160 PA-6.6 Polyamid 6.6 190 120 PBT Polybutylenterephthalat 165 PC Polycarbonat 150 130 * PE/PP Polyolefine PEEK Polyetheretherketon 240 240 PEI Polyetherimid 200 180 PES Polyarylethersulfon 190 190 PET Polyethylenterephthalat 200 PI Polyimid 350 PMMA Polymethylmetharylat 95 85 * POM Polyoymethylen 130 PPA Polyphtalamid 185 180 * PPE Polyphenylenether 120 PPS Polyphenylensulfid 240 210 PS Polystyrol (Standard) 80 65 PSU Polysulfon 170 160 PTFE Polytetrafluorethylen 300 250 PU Polyurethane PC Polyvinylchlorid 75 65 SAN Styrol/Acrylnitril 95 85 SB Styrol/Butadien 70 60 S-PS syndiotaktisches Polystyrol (Questra) 260 150 * ) with additional treatment

B. EMI theory Incoming signal Nickel/chrome Copper (elektrically conducting layer) Substrate (plastic) Direct reflection Zig-zag Reflection Reflected signal: Signal passing trough Absorption Sender (source) Shielding layer Receiver (test point) Because of the multitude of electronic equipment in our environment and the associated emission of electronic signals, it is important that, on the one hand, no disruptive signals enter an electronic device, and on the other hand, the sending out of a signal is minimal. For EMI (Electromagnetic Interference) the electronic tuning between the sender and the receiver of a signal will be syncronised without influencing the other component parts. There is built in sufficient immunity as also a reduced disruptive emitted signal. An attenuation of electromagnetic signals is achieved by so-called shielding, or by a metallic coating, which is applied to the surface of the plastic housing. The shielding effect of this coating is based on the interaction with the electromagnetic signal, a part of the radiation is absorbed and a part is reflected (see diagram). Thus the electrical shielding is easier to manage than the magnetic shielding. The shielding efficiency depends on the conductivity of the coating i.e. on the coating thickness and the specific conductivity of the coating material, on the housing geometry and additionally, in the case of shielding of magnetic fields, on the use of magnetic materials. It is dependent on the frequency. Thus, higher frequencies in the same coating thickness are, as a rule, absorbed more effectively. A shielding efficiency of 60 to 80 db (good to very good) requires a coating resistance of between 400 and 20 mω (linear space interval of mm). Shielding efficiency of copper and aluminium (calculated): Coating Specific electrical Layer Layer Shielding efficiency material resistance μ cm thickness μm resistance m by frequency db Copper 1.7 1.0 17 MHz 1 GHz 75 81 Copper 1.7 2.0 8.5 MHz 1 GHz 82 87 Aluminium 2.7 2.0 27 MHz 1 GHz 77 83 Aluminium 2.7 3.5 13.5 MHz 1 GHz 82 88

C. Process flow diagram Production of EMI shielding using the CREAMET 1 200 PD high vacuum coating equipment, in accordance with the CREASHIELD process: 1 Goods in Evacuation of up to ~ 10-2 mbar Checking receipt goods Glowing discharging process (activation with plasma) Mounting on the holder and masking Evacuation of up to ~ 1 10-4 mbar Cleaning with ionised air Evapouration of coating material (for eample CREASHIELD Cu) all parts ecept PC and PC-ABS PC and PC-ABS parts entilation of the chamber Primer coating station Demounting from the holder and markers Insertion of rotary cage in the H coating plant Quality control - conductivity/adhesion - optical specification Programming of the CREAMET 1 200 coating equipment Packaging 1 Dispatch

D. Quality parameters Testing for Test Test requirements Adhesion Electrical resistance Tape test, including temperature cycling test Temperature and humidity test Electrical resistance between 2 points Layer resistance in accordance with ASTM D3359-93 and UL746C 60 C and 95% relative humidity, duration: 1 week mostly < 0,5 Ω or < 1 Ω < 30 mω E. Comparison of various EMI coating technologies Technology Substrate Coating Thermal Layer material influence thickness Shielding efficiency Estimation Thermal evaporation Nearly all plastics Metals and alloys minimal 1.0 3.0 μm good - low cost - minimal thermal influence - ease of production - good shielding effect - no environmental problems Sputtering Nearly all plastics Metals and alloys high < 1.0 μm medium - high cost - strong thermal influence - ease of production - medium shielding effect - no environmental problems Plating Limited choice Limited choice minimal > 10 μm good - high cost - minimal thermal influence - ease of production - good shielding effect - necessary precautions for reduction of ecological damage Conductive lacquer coating Limited choice Limited choice minimal > 10 μm medium - low cost - minimal thermal influence - ease of production - restricted reproducability - medium shielding effect - necessary precautions for reduction of ecological damage Metal cap Nearly all plastics Aluminium or zinc-plated iron > 10 μm good - medium cost - no thermal influence - production is time consuming - only for simple designs - good shielding effect - necessary precautions for reduction of ecological damage

F. Eamples of coatings 120 Copper, Nickel/chrome Shielding effect [db] 80 60 40 20 0-20 -40 20 30 40 50 70 200 300 400 600 0 Frequency [MHz] Copper, tin Gold Aluminium Shielding effect [db] 90 80 70 60 50 40 30 20 10 0 5 μm 10 μm 2,5 μm 30 40 60 80 200 400 600 0 Frequency [MHz] CREAAC Creative akuumbeschichtung GmbH Löbtauer Straße 65 71 D-01159 Dresden Germany Phone +49(0)351 21838-0 Fa +49(0)351 21838-19 e-mail: info@creavac.de www.creavac.de