MATERIAL SAFETY DATA SHEET 1 Product and Company Identification Product Name RESOLVE (formerly SPRAY 'N WASH ) All Stains Laundry Stain Remover - Dual Chamber - Colorless liquid (enzyme) and blue liquid (oxygen) CAS # Mixture Product use Stain remover Distributed by LEGEND HMIS/NFPA Severe Serious 4 3 Moderate 2 Slight 1 Minimal 0 Reckitt Benckiser Morris Corporate Center IV 399 Interpace Parkway PO Box 225 Parsippany, NJ 07054-0225 In Case of Emergency: 1-800-338-6167 Transportation Emergencies: 24 Hour Number: North America: CHEMTREC: 1-800-424-9300 Outside North America: 1-703-527-3887 Health / 2 Flammability 0 Physical Hazard 0 Personal Protection A 0 2 0 Emergency overview Potential short term health effects Routes of exposure Eyes Skin Inhalation Ingestion Target organs Chronic effects Signs and symptoms OSHA Regulatory Status Potential environmental effects 2 Hazards Identification CAUTION EYE AND SKIN IRRITANT HARMFUL IF SWALLOWED Do not get in eyes or on skin DO NOT ingest Wash hands immediately after use KEEP OUT OF REACH OF CHILDREN Eye, Skin contact, Inhalation, Ingestion None expected during normal conditions of use Corrosive to eyes Irritating to skin Not expected to be a skin sensitizer None expected during normal conditions of use May be harmful if swallowed Eyes Respiratory system Skin The finished product is not expected to have chronic health effects Symptoms may include redness, edema, drying, defatting and cracking of the skin Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19101200 Components of this product have been identified as having potential environmental concerns #22544 Page 1 of 7 Issue date 29-Mar-2012
3 Composition / Information on Ingredients Ingredient(s) CAS # Percent 68584-22-5 68551-12-2 7722-84-1 9014-01-1 25-10 10-20 1-25 0-01 First aid procedures Eye contact Skin contact Inhalation Ingestion Notes to physician General advice 4 First Aid Measures In case of eye contact, IMMEDIATELY rinse eyes with plenty of water Remove any contact lenses and continue rinsing eyes for at least 15 minutes If irritation persists, get medical attention In case of skin contact, wash with plenty of water If irritation persists, get medical attention For sensitive skin, the use of gloves is recommended Move to fresh air If swallowed, rinse mouth and drink a glass of water Call a physician or Poison Control Center IMMEDIATELY Treat patient symptomatically If you feel unwell, seek medical advice (show the label where possible) Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance Avoid contact with eyes and skin Keep out of reach of children 5 Fire Fighting Measures Flammable properties Extinguishing media Suitable extinguishing media Unsuitable extinguishing media Protection of firefighters Specific hazards arising from the chemical Protective equipment for firefighters Hazardous combustion products Explosion data Sensitivity to mechanical impact Sensitivity to static discharge Personal precautions Environmental precautions Methods for containment Methods for cleaning up Not flammable by OSHA criteria Treat for surrounding material Firefighters should wear full protective clothing including self contained breathing apparatus May include and are not limited to: Oxides of carbon 6 Accidental Release Measures Keep unnecessary personnel away Do not touch or walk through spilled material Do not touch damaged containers or spilled material unless wearing appropriate protective clothing Keep people away from and upwind of spill/leak Do not discharge into lakes, streams, ponds or public waters Stop leak if you can do so without risk Prevent entry into waterways, sewers, basements or confined areas This material is a water pollutant and should be prevented from contaminating soil or from entering sewage and drainage systems and bodies of water Before attempting clean up, refer to hazard data given above Small spills may be absorbed with non-reactive absorbent and placed in suitable, covered, labelled containers Prevent large spills from entering sewers or waterways Contact emergency services and supplier for advice Never return spills to original containers for re-use #22544 Page 2 of 7 Issue date 29-Mar-2012
Handling Storage Exposure limits Ingredient(s) 7 Handling and Storage Ensure adequate ventilation Use good industrial hygiene practices in handling this material When using do not eat or drink Avoid contact with skin and clothing Avoid contact with eyes Avoid breathing vapors or mists of this product Keep container tightly closed Wash thoroughly after handling Keep out of reach of children Keep at temperatures below 40 C Store in a closed container away from incompatible materials 8 Exposure Controls / Personal Protection Exposure Limits TWA: 1 ppm TWA: 1 ppm Ceiling: 00001 mg/m3 Engineering controls General ventilation normally adequate Personal protective equipment Eye / face protection tightly fitting safety goggles Emergency responders should wear full eye and face protection Hand protection For sensitive skin or prolonged use, wear rubber gloves Emergency responders should wear impermeable gloves Skin and body protection Usual safety precautions while handling the product will provide adequate protection against injury or irritation Rubber apron recommended Emergency responders should wear impermeable clothing and footwear when responding to a situation where contact with the liquid is possible Respiratory protection Where exposure guideline levels may be exceeded, use an approved NIOSH respirator Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of vapours generated by this product during a spill or other clean-up operations General hygiene considerations Handle in accordance with good industrial hygiene and safety practice When using do not eat or drink Wash hands before breaks and immediately after handling the product 9 Physical and Chemical Properties Appearance Color Form Odor Liquid Blue and Colorless aqueous solution Characteristic #22544 Page 3 of 7 Issue date 29-Mar-2012
Odor threshold Physical state ph Freezing point Boiling point Pour point Evaporation rate Flash point Auto-ignition temperature Flammability limits in air, lower, % by volume Flammability limits in air, upper, % by volume Vapor pressure Vapor density Specific gravity Octanol/water coefficient Liquid 35 ± 03 (Blue), 85 ± 03 (Clear), 68 +/- 03 (50/50 mix) 102 ± 005 (Blue) 10 Stability and Reactivity Reactivity This product may react with oxidizing agents Possibility of hazardous reactions Hazardous polymerization does not occur Chemical stability Stable under recommended storage conditions Conditions to avoid DO NOT MIX WITH BLEACH or use in conjunction with other household products Incompatible materials Acids Oxidizers Hazardous decomposition products May include and are not limited to: Oxides of carbon Component analysis - LC50 Ingredient(s) 11 Toxicological Information LC50 Component analysis - Oral LD50 Ingredient(s) LD50 Effects of acute exposure Eye Skin Inhalation Ingestion Sensitization Chronic effects 1380 mg/kg rat 530 mg/kg rat 75 mg/kg rat; 2000 mg/kg mouse None expected during normal conditions of use Corrosive to eyes Irritating to skin Not expected to be a skin sensitizer None expected during normal conditions of use May be harmful if swallowed The finished product is not expected to have chronic health effects Non-hazardous by OSHA criteria The finished product is not expected to have chronic health effects #22544 Page 4 of 7 Issue date 29-Mar-2012
Carcinogenicity The finished product is not expected to have chronic health effects ACGIH - Threshold Limit Values - Carcinogens 7722-84-1 A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans IARC - Group 3 (Not Classifiable) 7722-84-1 Monograph 71 [1999]; Supplement 7 [1987]; Monograph 36 [1985] Mutagenicity The finished product is not expected to have chronic health effects Reproductive effects The finished product is not expected to have chronic health effects Teratogenicity The finished product is not expected to have chronic health effects Name of Toxicologically Synergistic Products Ecotoxicity 12 Ecological Information See below Ecotoxicity - Freshwater Algae - Acute Toxicity Data 7722-84-1 72 Hr EC50 Chlorella vulgaris: 25 mg/l Ecotoxicity - Freshwater Fish - Acute Toxicity Data Benzenesulfonic acid, 68584-22-5 96 Hr LC50 Oncorhynchus mykiss: 3 mg/l [static] C10-16-alkyl derivatives 7722-84-1 96 Hr LC50 Pimephales promelas: 164 mg/l; 96 Hr LC50 Lepomis macrochirus: 18-56 mg/l [static]; 96 Hr LC50 Oncorhynchus mykiss: 100-320 mg/l [static] Ecotoxicity - Water Flea - Acute Toxicity Data Benzenesulfonic acid, C10-16-alkyl derivatives 68584-22-5 48 Hr EC50 Daphnia magna: 29 mg/l 7722-84-1 24 Hr EC50 Daphnia magna: 77 mg/l; 48 Hr EC50 Daphnia magna: 18-32 mg/l [Static] Persistence / degradability Bioaccumulation / accumulation Mobility in environmental media Environmental effects Aquatic toxicity Partition coefficient Chemical fate information Disposal instructions Waste from residues / unused products Contaminated packaging 13 Disposal Considerations Dispose in accordance with all applicable regulations 14 Transport Information UN/ID No US Department of Transportation (DOT): Classification: Not regulated Proper shipping name US DOT Hazard Class Subsidiary Risk Packing group DOT RQ (lbs) ERG NO #22544 Page 5 of 7 Issue date 29-Mar-2012
Transportation of Dangerous Goods (TDG - Canada): Classification: Not regulated Proper shipping name Status Packing group IMDG (Marine Transport): Classification: Not regulated Proper shipping name Class Subsidiary Risk Packing group IMDG Page Marine pollutant EMS MFAG Maximum Quantity IATA/ICAO (Air): Classification: Not regulated Proper shipping name Class Subsidiary Risk: Packing group Maximum Quantity 15 Regulatory Information Occupational Safety and Health Administration (OSHA) 29 CFR 19101200 hazardous Yes chemical US Federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 19101200 Product Registration: Product is compliant with CPSC regulatory guidelines; a specific registration is not required for this product US - CERCLA/SARA - Section 302 Extremely Hazardous Substances EPCRA RQs 7722-84-1 1000 Lb EPCRA RQ (concentration >52%) US - CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs 7722-84-1 1000 Lb TPQ (concentration >52%) #22544 Page 6 of 7 Issue date 29-Mar-2012
Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories Section 302 extremely hazardous substance Immediate Hazard - Yes Delayed Hazard - No Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No No Section 311 hazardous chemical Yes Clean Air Act (CAA) Clean Water Act (CWA) Hazardous substance State regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm US - California - 8 CCR Section 339 - Director's List of Hazardous Substances 7722-84-1 Present 9014-01-1 Present US - Massachusetts - Right To Know List 7722-84-1 Extraordinarily hazardous US - Minnesota - Hazardous Substance List 7722-84-1 Present (including [90%]) US - New Jersey - Right to Know Hazardous Substance List 7722-84-1 sn 1015 US - New York - Reporting of Releases Part 597 - List of Hazardous Substances 7722-84-1 1 Lb RQ (air); 1 lb RQ (land/water) US - Ohio - Extremely Hazardous Substances - Threshold Quantities 7722-84-1 500 Lb TQ (concentration >52%) US - Pennsylvania - RTK (Right to Know) List 7722-84-1 Environmental hazard (concentration >52%); Present US - Rhode Island - Hazardous Substance List 7722-84-1 Toxic; Flammable US - Texas - Tier II Chemical Reporting - Extremely Hazardous Substances - Reportable Quantities 7722-84-1 1000 Lb RQ US - Texas - Tier II Chemical Reporting - Extremely Hazardous Substances - Threshold Planning Quantities 7722-84-1 1000 Lb TPQ (concentration >52%) Inventory status Country(s) or region Inventory name On inventory (yes/no)* United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) 16 Other Information Disclaimer Further information This product should only be used as directed on the label and for the purpose intended To the best of our knowledge, the information contained herein is accurate However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein Final determination of suitability of any material is the sole responsibility of the user All materials may present unknown hazards and should be used with caution Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist RESOLVE (formerly SPRAY 'N WASH ) All Stains Laundry Stain Remover - Dual Chamber - Colorless liquid (enzyme) and blue liquid (oxygen) - 22 fl oz (1 pt 6 fl oz) (650 ml) - 0315038 v10, 0315031 v10 29-Mar-2012 Issue date Effective date 31-Mar-2012 Prepared by Reckitt Benckiser Regulatory Department 800-333-3899 Other information For an updated MSDS, please contact the supplier/manufacturer listed on the first page of the document This MSDS conforms to the ANSI Z4001/Z1291-2010 Standard #22544 Page 7 of 7 Issue date 29-Mar-2012