Thermal Energy Storage in industrial processes

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Thermal Energy Storage in industrial processes Contribution to energy efficiency, energy flexibility and increasing the share of renewable energy R. de Boer June 2016 ECN-L--16-034

Thermal Energy Storage in industrial processes contribution to energy efficiency, energy flexibility and increasing the share of renewable energy Robert de Boer May 24, 2016 www.ecn.nl

Recent advice to EU policy makers Energy saving as first fuel for Europe Energy saving should compete on equal terms with generation capacity

Recent news in NL Dutch government threatens to enforce energy saving measures in energy intensive industries, in order to reach the targets of the Dutch national energy agreement Speed up the implementation of energy saving measures Source: Volkskrant 18 May 2016

Vision on thermal energy The demand for heat has a large share in the total energy demand. This means that reducing the heat demand as well as supplying thermal energy from renewable sources is crucial to achieve the transition towards a renewable energy system in 2050..

Thermal energy in NL Primary energy use for heating: 1200 PJ Renew Saving Energy-saving potential for 2020 260 PJ of which 166 PJ is cost competitive Renewable heat sources 2020 282 PJ of which 86 PJ is cost competitive Implementing the cost competitive options CO 2 -emissions share renewable Saving: - 14% 4% Renew: - 7% 10% Both: - 21% 12%

Reuse of waste heat What makes heat to be designated as waste heat? Problem Heat at wrong temperature Heat at wrong moment Heat at wrong place Solution Convert it to the right temperature -> heat pump technology Store it for use at the right moment -> heat storage technology Transport it to the right place -> heat transport technology

Applications for thermal energy storage Increase energy efficiency of industrial processes through the re-use of waste heat Increase the share of renewable energy based on Solar thermal Create new energy flexibility options for Combined Heat and Power and connect the electricity system to the heat system (power2heat) Transport of heat

LOCOSTO project RVO - Joint Industry Project (JIP) Stakeholders in the value chain involved Objective: development of techno-economic feasible PCM heat storage solutions for industrial applications Innovation Development of novel PCM, high energy storage density, T-range 100-250 C New methods for integration of PCM s and heat exchangers, to obtain high thermal power PCM heat storage systems.

Approach and targeted results applications PCM thermal model economics 2017 PCM lab prototype PCM materials

Enthalpy Energy storage in Phase Change Materials Latent H melt Sensible T heat supply T heat demand T melt Temperature

Storage System Complexity Conversion losses Thermal storage technologies Thermo chemical Thermo chemical PCM Sensible PCM Sensible Energy storage density (MJ/m3) Stand still losses

PCM heat storage: charge-discharge thermal powers Heat transfer rate in PCM systems is low Low thermal conductivity of PCM s Slow charge-discharge rates Solutions Large heat transfer surface areas short distances for heat transfer Increase the thermal conductivity of PCM

Matlab tool LOCOSTO Goal: performance calculations for a multi-tube PCM heat storage system Characteristics: - Enthalpy based model - Fixed 3 dimensional grid, variable time step - Using software tool Matlab Elements of model: - Defining layout (tubes), PCM, heat transfer medium, initial conditions, - Calculating grid /mesh of tubes and PCM - Dynamic calculations - Visualization: design, grid, time plots, mesh plots, video

Grid definition Selection quarter of tube: Approach area of segment i with cake slice: Define segments k = 1 : z (tube length) k = 1 k = 2 k = z Split triangle in x segments: Split each segment i in y parts of same length: Define wall conditions = point mirror symmetric: i = 2 i = 1 j = y j = 2 j = 1 i = x

Visualization grid / design

Heat transfer in PCM lab-prototype of Shell & Tube PCM test system Study of melting behaviour of a PCM storage concept, experiment + model

Heat transfer in PCM Design and construction of shell & tube concept for PCM heat storage

Summary Thermal energy has a substantial share in the overall energy system Re-use of waste heat has a large potential to enable thermal energy savings Heat storage technology contributes to: energy saving Providing flexibility to the energy system Incorporate renewable heat sources (solar, geothermal) High thermal power density storage systems needed for industry applications: rapid charge and discharge Challenge to develop cost-efficient, high performance, robust and reliable thermal storage solutions

Outlook for PCM thermal energy storage Development of cost effective, stable PCM materials for T > 100 C Validate modelling tools with lab scale experiments Development of flexible storage concepts that match storage capacity and thermal power requirements as well as economic constraints Upscaling of HT-PCM storage concepts and test + demonstration in practical situations Storage system integration Econo- mics Heat storage concept Storage materials

Robert de Boer Westerduinweg 3 P.O. Box 1 1755 LE Petten 1755 ZG Petten The Netherlands The Netherlands T +31 88 515 4949 F +31 88 515 4480 info@ecn.nl www.ecn.nl Acknowledgement: The LOCOSTO project is partially subsidized by the industrial energy savings program (EBI) of the Topsector Energy, nr. TEEI314008. The Netherlands Enterprise Agency (RVO.nl) is executing this program for the Institute for Sustainable Process Technology (TKI-ISPT).

ECN Westerduinweg 3 P.O. Box 1 1755 LE Petten 1755 LG Petten The Netherlands The Netherlands T +31 88 515 4949 F +31 88 515 8338 info@ ecn.nl www.ecn.nl 8