Page 1 of 14 The following sample(s) was/were submitted and identified by/on behalf of the applicant as Sample Description Sample Description Style/Item No. Color Sample Receiving Date Testing Period Sample Submitted By COPPER BONDING WIRE COPPER BONDING WIRE icu, DHF, MaxSoft, MaxSoft2, MaxSoftLD, RelCu and GXCu COPPER 2017/11/30 2017/11/30 TO 2017/12/08 HERAEUS MATERIALS TECHNOLOGY TAIWAN LTD. ============================================================================================ Test Requested Test Method Test Result(s) Conclusion As specified by client, with reference to RoHS 2011/65/EU Annex II and amending Directive (EU) 2015/863 to determine Cadmium, Lead, Mercury, Cr(VI), PBBs, PBDEs, DBP, BBP, DEHP, DIBP contents in the submitted sample(s). Please refer to following pages. Please refer to following pages. Based on the performed tests on submitted sample(s), the test results of Cadmium, Lead, Mercury, Cr(VI), PBBs, PBDEs, DBP, BBP, DEHP, DIBP comply with the limits as set by RoHS and amending Directive (EU) 2015/863.
Page 2 of 14 Test Result(s) PART NAME No.1 COPPER BONDING WIRE Test Item(s) Cadmium (Cd) Lead (Pb) Mercury (Hg) Hexavalent Chromium Cr(VI) Hexavalent Chromium Cr(VI) Hexavalent Chromium Cr(VI)(#2) Hexavalent Chromium Cr(VI) Unit With reference to IEC 62321-5 2013 and performed by ICP-AES. With reference to IEC 62321-5 2013 and performed by ICP-AES. With reference to IEC 62321-4 2013 and performed by ICP-AES. With reference to IEC 62321-7-22017 and performed by UV-VIS. Method With reference to US EPA Method 3060A & 7196A for Hexavalent Chromium. Analysis was performed by UV-Vis Spectrometry. µg/cm² With reference to IEC 62321-7-12015 and performed by by UV-VIS. µg/cm² With reference to BS EN ISO 36132010 for Hexavalent Chromium. Analysis was performed by UV-VIS Spectrometry. MDL Result No.1 Limit 2 n.d. 100 2 n.d. 1000 2 n.d. 1000 8 n.d. 1000 2 n.d. 1000 0.10 n.d. - 0.02 n.d. - Sum of PBBs Monobromobiphenyl Dibromobiphenyl Tribromobiphenyl Tetrabromobiphenyl Pentabromobiphenyl Hexabromobiphenyl Heptabromobiphenyl Octabromobiphenyl Nonabromobiphenyl Decabromobiphenyl With reference to IEC 62321-6 (2015) and performed by GC/MS. - n.d. 1000
Page 3 of 14 Sum of PBDEs Monobromodiphenyl ether Dibromodiphenyl ether Tribromodiphenyl ether Tetrabromodiphenyl ether Pentabromodiphenyl ether Hexabromodiphenyl ether Heptabromodiphenyl ether Octabromodiphenyl ether Nonabromodiphenyl ether Decabromodiphenyl ether Antimony (Sb) Test Item(s) Unit Method Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified (α- HBCDD, β- HBCDD, γ- HBCDD) (CAS No. 25637-99-4 and 3194-55-6 (134237-51-7, 134237-50-6, 134237-52-8)) Tetrabromobisphenol A (TBBP-A) (CAS No. 79-94-7) Perfluorooctane sulfonates (PFOS) PFOA (CAS No. 335-67-1) Halogen Halogen-Fluorine (F) (CAS No. 014762-94-8) Halogen-Chlorine (Cl) (CAS No. 022537-15-1) Halogen-Bromine (Br) (CAS No. 010097-32-2) Halogen-Iodine (I) (CAS No. 014362-44-8) With reference to US EPA Method 3052 for Antimony Content. Analysis was performed by ICP-AES. With reference to IEC 62321 2008 method. Analysis was performed by GC/MS. With reference to IEC 62321-6 (2015) and performed by GC/MS. With reference to RSTS-E&E-121. Analysis was performed by LC/MS. With reference to US EPA 3550C 2007. Analysis was performed by LC/MS. With reference to BS EN 145822016. Analysis was performed by IC. MDL Result No.1 Limit - n.d. 1000 2 n.d. - 10 n.d. - 10 n.d. - 10 n.d. -
Page 4 of 14 Phthalates BBP (Butyl Benzyl phthalate) (CAS No. 85-68-7) DBP (Dibutyl phthalate) (CAS No. 84-74-2) Result Test Item(s) Unit Method MDL Limit No.1 DEHP (Di- (2-ethylhexyl) phthalate) (CAS No. 117-81-7) DIDP (Di-isodecyl phthalate) (CAS No. 26761-40-0; 68515-49-1) DINP (Di-isononyl phthalate) (CAS No. 28553-12-0; 68515-48-0) DNOP (Di-n-octyl phthalate) (CAS No. 117-84-0) DIBP (Di-isobutyl phthalate) (CAS No. 84-69-5) DMEP (Bis (2-methoxyethyl) phthalate) (CAS No. 117-82-8) DNHP (Di-n-hexyl phthalate) (CAS No. 84-75-3) With reference to IEC 62321-82017. Analysis was performed by GC/MS.
Page 5 of 14 Note 1. = ppm;0.1wt% = 1000ppm 2. n.d. = Not Detected 3. MDL = Method Detection Limit 4. " - " = Not Regulated 5. (#2) = a. The sample is positive for Cr(VI) if the Cr(VI) concentration is greater than 0.13 µg/cm². The sample coating is considered to contain Cr(VI). b. The sample is negative for Cr(VI) if Cr(VI) is n.d. (concentration less than 0.10 µg/cm²). The coating is considered a non-cr(vi) based coating. c. The result between 0.10 µg/cm² and 0.13 µg/cm² is considered to be inconclusive - unavoidable coating variations may influence the determination. PFOS Reference Information POPs - (EU) 757/2010 Outlawing PFOS as substances or preparations in concentrations above 0.001% (10ppm), in semi-finished products or articles or parts at a level above 0.1%(1000ppm), in textiles or other coated materials above 1µg/m². PFOS refer to Perfluorooctanesulfonic acid and its derivatives including Perfluoroctanesulfonic acid, Perfluoroctane sulfonamide, N-Methylperfluoroctane sulfonamide, N-Ethylperfluoroctane sulfonamide, N-Methylperfluoroctane sulfonamidoethanol and N-Ethylperfluoroctane sulfonamidoethanol.
Page 6 of 14 #FLOW Analytical flow chart of Heavy Metal These samples were dissolved totally by pre-conditioning method according to below flow chart. (Cr 6+ test method excluded) Technician Jony Liu Supervisor Ray Chang Cutting Preparation Sample Measurement Pb/Cd/Hg Cr 6+ Microwave digestion / Hotplate digestion Non-metal Metal Solution Filtration Residue 1) Alkali fusion 2) HCl to dissolve ABS / PC / PVC Dissolving by ultrasonication Digesting at 60 by ultrasonication Others Digesting at 150~160 Separating to get aqueous phase Boiling water extraction Cool, filter digestate through filter Filtration ICP-AES ph adjustment Add diphenyl-carbazide for color development Add diphenylcarbazide for color development Measure the absorbance at 540 nm by UV-VIS Measure the absorbance at 540 nm by UV-VIS
Page 7 of 14 PBB/PBDE analytical FLOW CHART 1) Name of the person who made measurement Dorothy Chen 2) Name of the person in charge of measurement Ray Chang Sample Sample pretreatment Sample extraction/ Soxhlet method Concentrate/Dilute Extracted solution Filter Analysis by GC/MS Issue Report
Page 8 of 14 1) These samples were dissolved totally by pre-conditioning method according to below flow chart. 2) Name of the person who made measurement Jony Liu 3) Name of the person in charge of measurement Ray Chang Flow Chart of digestion for the elements analysis performed by ICP-AES Cutting Preparation Sample Measurement Acid digestion by suitable acid depended on different sample material (as below table) Filtration Solution Residue ICP-AES 1) Alkali Fusion 2) HCl to dissolve Steel, copper, aluminum, solder Glass Gold, platinum, palladium, ceramic Silver Plastic Others Aqua regia, HNO3, HCl, HF, H2O2 HNO3/HF Aqua regia HNO3 H2SO4, H2O2, HNO3, HCl Any acid to total digestion
Page 9 of 14 HBCDD analytical flow chart 1) Name of the person who made measurement Dorothy Chen 2) Name of the person in charge of measurement Ray Chang Sample pretreatment Sample extraction / Ultrasonic method Concentrate/Dilute Extracted solution Filter Analysis was performed by GC/MS Data
Page 10 of 14 TBBP-A analytical flow chart Name of the person who made measurement Ginny Huang Name of the person in charge of measurement Ray Chang Sample pretreatment Sample extraction by Ultrasonic extraction Concentrate/Dilute Extracted solution Analysis was performed by LC/MS Data
Page 11 of 14 Analytical flow chart of PFOA/PFOS content 1) Name of the person who made measurement Ginny Huang 2) Name of the person in charge of measurement Ray Chang Sample pretreatment Sample extraction by ultrasonic method (Reference method US EPA 3550) Concentrate/Dilute Extracted solution Analysis was performed by LC/MS Data
Page 12 of 14 Analytical flow chart of halogen content 1) Name of the person who made measurement Jean Hung 2) Name of the person in charge of measurement Ray Chang Sample picture and report number Sample pretreatment/separation Weighting and putting sample in cell Oxygen Bomb Combustion /Absorption Dilution to fixed volume Analysis was performed by IC
Page 13 of 14 Analytical flow chart of phthalate content Name of the person who made measurement Dorothy Chen Name of the person in charge of measurement Ray Chang Test method IEC 62321-8 Sample pretreatment/separation Sample dissolved/extracted by THF Dilute Extracted solution Analysis was performed by GC/MS Data
Page 14 of 14 #PIC * The tested sample / part is marked by an arrow if it's shown on the photo. * ** End of Report **