Version 1.6 Print Date 10/10/2012 Revision Date 07/13/2010. Component CAS-No. Weight percent. Sodium Hydroxide

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Transcription:

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name : MSDS Number : REL_200155 Company : Chemetall US, Inc. 675 Central Avenue New Providence, NJ 07974 Telephone : +18005264473 Telefax : +19084644658 Emergency telephone no : CHEMTREC - 800-424-9300 SECTION 2. HAZARDOUS COMPONENTS INFORMATION Component CAS-No. Weight percent Sodium Hydroxide 1310-73-2 50.00-55.00 Unidentified ingredients are considered not hazardous under Federal Hazard Communication Standard (29CFR 1910.1200). SECTION 3. HAZARDS IDENTIFICATION Emergency Overview Form Colour Odour Hazard Summary : powder : white : none : Causes severe burns.harmful by inhalation and if swallowed. Route(s) of Entry : Inhalation Skin Ingestion yes yes yes Carcinogenicity: NTP IARC OSHA No substance in this product is listed by NTP as a carcinogen No substance in this product is listed by IARC as a carcinogen No substance in this product is regulated by OSHA as a carcinogen SECTION 4. FIRST AID MEASURES Inhalation : Remove to fresh air. If symptoms persist, call a physician. If breathing is irregular or stopped, administer artificial respiration. Skin contact : Wash off immediately with plenty of water for at least 15 minutes.take off contaminated clothing and shoes N.D. - Not Determined 1/5 N.A. - Not Applicable

immediately.get medical attention immediately if irritation develops and persists Eye contact : Rinse immediately with plenty of water for at least 15 minutes.keep eye wide open while rinsing.get medical attention immediately Ingestion : Rinse mouth.drink plenty of water.never give anything by mouth to an unconscious person.get medical attention immediately SECTION 5. FIRE-FIGHTING MEASURES Flash point : Note: does not flash Lower explosion limit : Note: not applicable Upper explosion limit : Note: not applicable TDG Flammability Class : NONE Suitable extinguishing media Special protective equipment for fire-fighters : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. : Wear self contained breathing apparatus for fire fighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use personal protective equipment. Ventilate the area. Methods for cleaning up : Ventilate area. Clean up with inert absorbant material. Keep in suitable, closed containers for disposal. Flush with plenty of water. Additional advice : Never return spills in original containers for re-use. SECTION 7. HANDLING AND STORAGE Handling Handling : Add this product to surface of solution slowly to avoid spattering Do not add large amounts of product to solution at any one N.D. - Not Determined 2/5 N.A. - Not Applicable

time. Do not add to hot water warmer than 43 degrees to 49 degrees C (110 degrees to 120 degrees F). Never add liquids to product Storage Requirements for storage areas and containers : Keep containers dry and tightly closed to avoid moisture absorption and contamination. Store indoors in a cool, well-ventilated place Protect from direct contact with water or excessive moisture. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Component Sodium Hydroxide ACGIH TLV (TWA) 2 mg/m3 ceilingn.d. OSHA PEL (TWA) 2 mg/m3 N.D. Eye protection : Safety glasses with side-shields Face-shield Hand protection : Impervious gloves Skin and body protection : Apron Respiratory protection : If the occupational exposure limits cannot be met, in exceptional cases suitable respiratory equipment should be worn only for a short period of time. Hygiene measures : Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wash hands before breaks and immediately after handling the product. Provide adequate ventilation. Avoid breathing dust or vapor. Keep away from food and drink. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES ph : > 13 Melting point/range Boiling point/boiling range Vapour pressure : Note: not applicable : Note: not applicable : Note: no data available N.D. - Not Determined 3/5 N.A. - Not Applicable

Bulk density Water solubility : 5.80 lb/gal : Note: completely soluble Partition coefficient: n- octanol/water : Note: no data available Percent of Volatile by Weight excluding water : Note: no data available Relative density : 0.70 Evaporation rate : Note: (Water =1) Less than 1 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid Hazardous decomposition products : Exposure to moisture. : Acids : Carbon oxides Hydrogen when reacts with certain metal. SECTION 11. TOXICOLOGICAL INFORMATION Toxicity: : Mixture; Not Determined. Acute oral toxicity Sodium Hydroxide : LDlo, rabbit Dose: 500 mg/kg SECTION 12. ECOLOGICAL INFORMATION Not Available SECTION 13. DISPOSAL CONSIDERATIONS Advice on Disposal : Refer to all federal, provincial,state and local regulation prior to disposition of container and unused contents by reuse, recycle or disposal. N.D. - Not Determined 4/5 N.A. - Not Applicable

SECTION 14. TRANSPORT INFORMATION Refer to Bill of Lading. SECTION 15. REGULATORY INFORMATION TSCA Status : All components of this material comply with US TSCA requirements. SARA 313 Components : N.D. CERCLA Reportable Quantity : Sodium Hydroxide 1,000 Pounds California Prop. 65 : N.D NFPA : 3 0 1 Corrosive Alkaline HMIS : 3 0 1 J WHMIS : E: Corrosive Material D2B: Toxic Material Causing Other Toxic Effects SECTION 16. OTHER INFORMATION Further information Chemetall US, Inc. warrants that the products described herein will conform with its published specifications. The products supplied by Chemetall and information related to them are intended for use by buyers having necessary industrial skill and knowledge. Buyers should undertake sufficient verification and testing to determine the suitability of the Chemetall materials for their own particular purpose. Since buyer's conditions of use of products are beyond Chemetall's control, Chemetall does not warrant any recommendations and information for the use of such products. CHEMETALL DISCLAIMS ALL OTHER WARRANTIES INCLUDING THE IMPLIED WARRANTY OF MERCHANTABILITY AND FITNESS FOR ANY PARTICULAR PURPOSE IN CONNECTION WITH THE USE OF ITS PRODUCTS. N.D. - Not Determined 5/5 N.A. - Not Applicable