The Growing CO 2 -EOR Oil Recovery and CO 2 Utilization Prize

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The Growing CO 2 -EOR Oil Recovery and CO 2 Prepared For: 2013 EOR Carbon Management Workshop Opening Keynote Address Prepared By: Vello A. Kuuskraa, President Advanced Resources International, Inc. Arlington, VA December 10, 2013 Midland, Texas 1

Introduction Utilizing and Storing CO 2 with EOR is Finally Gaining Traction. After nearly a decade of analyses and presentations, utilizing and storing anthropogenic (industrial) CO 2 with enhanced oil recovery is finally gaining traction. Overcoming the Niche Opportunity Mindset. However, many still believe that CO 2 utilization and storage will play only a small, niche role. Our view, based on detailed field-level studies, is that the size of the oil recovery and CO 2 storage potential offered by CO 2 -EOR is quite large and growing, particularly as we begin to recognize its full potential. The Billion Metric Ton CO 2 Anthropogenic Utilization and Storage Prize. Based on our latest research, the currently active and estimated to come on-line (by 2020) CO 2 -EOR projects would provide nearly a billion metric tons of anthropogenic CO 2 utilization and storage by year 2030. 2

Onshore, Lower-48 CO 2 -EOR and CO 2 Utilization Prize Last year, as part of my Size of the Prize talk, I discussed the oil recovery and CO 2 demand (utilization/storage) potential from applying CO 2 enhanced oil recovery (CO 2 -EOR) to Lower-48 onshore oil fields. A recent update to that analysis shows that the economically viable* oil recovery and CO 2 demand potentials remain large. CO 2 -EOR Technology Status Economic* Oil Recovery/CO 2 Demand - - Lower-48 Onshore Economic Oil Fields Crude Oil CO 2 Demand** (No. of Fields) (Billion Barrels) (Gt) Current Technology 458 19.0 7.5 Next Generation Technology*** 948 59.6 15.2 *At $90/B oil price, $40/mt CO 2 price, and 20% (BT) ROR. **Includes 2.7 Gt of natural CO 2 Supply. ***Detailed discussion of next generation CO 2 -EOR technology is available on http://www.netl.doe.gov/: (1) Improving Domestic Energy Security and Lowering CO 2 Emissions with Next Generation CO 2 -Enhanced Oil Recovery (CO 2 -EOR), DOE/NETL-2011/1504, report (June 2011) and (2) An In-Depth Look at "Next Generation" CO 2 EOR Technology, presentation, (September 2013). 3

Current CO 2 -EOR Operations and CO 2 Sources (2012) Dakota Coal Gasification Plant 2 6 1. Oil Production (2012) CO 2 -EOR Projects 117 Oil Production (MB/D) 282 2. CO 2 Supplies (2012) Riley Ridge LaBarge Gas Plant Sheep Mountain McElmo Dome/ Doe Canyon 2 Bravo Dome 1 3 9 Val Verde Gas Plants Greencore Pipeline 5 Conestoga Ethanol Plant 65 Enid Fertilizer Plant 4 Century Gas Plant 2 Agrium Nitrogen Plant Source: Advanced Resources International, Inc., based on Oil and Gas Journal, 2012 and other sources. 2 Jackson Dome 16 Denbury/Green Pipeline Number of Sources 12 Natural 5 Anthropogenic 7 CO 2 Supply (MMcfd) 3,100 117 Natural 2,520 Anthropogenic 580 Number of CO 2 -EOR Projects Natural CO 2 Source Industrial CO 2 Source CO 2 Pipeline CO 2 Proposed Pipeline 4

Projected CO 2 -EOR Operations and CO 2 Sources (2020) 2 1. Oil Production (2020) Lost Cabin Gas Plant Riley Ridge LaBarge Gas Plant 2 Sheep Mountain McElmo Dome/ Doe Canyon St Johns Dome Bravo Dome Dakota Coal Gasification Plant 1 3 1 10 Carbon Energy UCG Century Gas Plant TCEP IGCC Plant Val Verde Gas Plants Greencore Pipeline Linc Energy UCG DKRW 6 Conestoga Bonanza Conestoga Ethanol Plant 66 Enid Fertilizer Plant 8 Agrium Nitrogen Plant Shell GTL Plant NRG IGCC Plant 6 Air Products Hydrogen Plant Lake Charles Plant Coffeyville Fertilizer Plant Source: Advanced Resources International, Inc., based on Oil and Gas Journal, 2012 and other sources. 2 16 6 Jackson Dome Mississippi IGCC Plant Mississippi Gasification PCS Nitrogen Plant Ammonia Plant Chemical Plant Denbury/Green Pipeline Sasol GTL Plant CO 2 -EOR Projects 129 Oil Production (MB/D) 653 2. CO 2 Supplies (2020) Number of Sources 31 129 Natural 6 Anthropogenic 25 CO 2 Supply (MMcfd) 6,910 Natural 3,450 Anthropogenic 3,460 Number of CO 2 -EOR Projects Natural CO 2 Source Industrial CO 2 Source CO 2 Pipeline CO 2 Proposed Pipeline 5

Rapidly Increasing Utilization and Storage of Anthropogenic CO 2 with EOR CO 2 Supply by Source Type (MMcfd) As part of a recent study for U.S. DOE/NETL, Advanced Resources tabulated the announced new sources of CO 2 supply scheduled to come on-line by 2020. Expansion of natural sources (St. Johns, Doe Canyon, Jackson Dome, etc.) Installation of CO 2 capture on industrial plants (Air Products hydrogen, Coffeyville fertilizer, Lost Cabin gas processing, Kemper Co. IGCC, etc.) As such, we envision significant growth in CO 2 supplies for EOR: 4.4 Bcfd by 2015 6.8 Bcfd by 2020 6

Near-Term Outlook for Oil Production from CO 2 -EOR CO 2 EOR Production by Region (MB/D) Increased CO 2 supplies are enabling industry to launch new CO 2 -EOR projects and expand existing CO 2 floods: Bell Creek, Montana Burbank and NE Hardesty, Oklahoma Seminole ROZ Stages 1-3, Goldsmith, West TX Webster, Conroe, Thompson, East TX These and other announced new/expanded CO 2 floods will drive significant growth in near-term CO 2 - EOR based oil production: 430,000 B/D by 2015 650,000 B/D by 2020 7

The Billion Metric Ton Anthropogenic CO 2 Utilization and Storage Prize The availability and utilization of new/expanded industrial sources of CO 2 by the EOR industry would provide: Storage of at least a billion metric tons of anthropogenic CO 2 by year 2030 (from existing and announced projects only). This is a conservative estimate as it does not include the numerous new announced petrochemical plants not yet linked to CO 2 -EOR. The billion metric tons of anthropogenic CO 2 utilized (stored) by 2030 is only a small fraction (+10%) of the economically viable long-term, Lower-48 onshore EOR demand for CO 2. 8

New CO 2 -EOR Opportunities and Challenges In addition to Lower-48 onshore conventional oil fields, numerous other reservoir settings and unconventional resources have demand for CO 2 : CO 2 -EOR for Offshore Gulf of Mexico and Alaska CO 2 -EOR for Residual Oil Zones and Shale Oil These other reservoir settings and resources offer opportunities for significantly increasing oil recovery and CO 2 utilization. However, they also present major technical challenges that need to be addressed, if we are to realize these opportunities. 9

Offshore CO 2 -EOR Offers Significant Benefits Use of CO 2 -EOR in GOM OCS would provide numerous benefits:* Increased domestic oil production; Market for CO 2 emissions captured from Gulf Coast power and industrial plants; Access and secure locations for storing CO 2, away from populated areas; Clear surface and mineral rights for storage sites; Reduced risks to underground sources of drinking water; Utilization of existing corridors and oil and gas infrastructure; and Potentially more favorable regulations and incentives. *J.T. Litynski et al., (2011); citing extensively Schrag, D., Storage of Carbon Dioxide in Offshore Sediments. Science 325, 1658, DOE: 10.1126/science.1175770, 2009. 10

Offshore Gulf of Mexico Recently completed work by Advanced Resources for U.S. DOE/NETL shows that significant volumes of oil are stranded in maturing shallow and deep water oil fields in the Gulf of Mexico. In addition, a host of newly discovered, large deep water oil fields are coming on-line, steadily increasing the size of the offshore oil resource base. CO 2 -EOR Technology Status Economic* Oil Recovery/CO 2 Demand - - Offshore Gulf of Mexico Economic Fields** Crude Oil CO 2 Demand (No. of Fields) (Billion Barrels) (Gt) Current Technology 18 0.8 0.3 Next Generation Technology*** 81 14.9 3.9 *At $90/B oil price, $50/mt CO 2 price, and 20% (BT) ROR. **The offshore oil fields hold multiple oil reservoirs. ***Discussion of next generation offshore CO 2 -EOR technologies is available in the Advanced Resources October, 2013 report prepared for U.S. DOE/NETL entitled CO 2 -EOR Offshore Resource Assessment (due for publication).. 11

Higher Oil Prices Would Significantly Expand Offshore Gulf of Mexico s s CO 2 Utilization/Storage Potential Current Technology "Next Generation" Technology Technical CO 2 Demand/Storage Capacity Economic CO 2 Demand/Storage Capacity Technical CO 2 Demand/Storage Capacity Economic CO 2 Demand/Storage Capacity Source: Advanced Resources October 2013 report prepared for U.S. DOE NETL entitled CO 2 -EOR Offshore Resource Assessment (due for publication). * @ $90/B Oil Price and $50/mt CO 2 Cost; ** @ $135/B Oil Price and $70/mt CO 2 Cost. 12

Alaska With the approval of LNG exports from Alaska, significant volumes of by-product CO 2 supplies will become available from the Prudhoe Bay oil field s gas cap. As such, the potential for applying CO 2 enhanced oil recovery in Alaska s oil field would become viable. Our recent study shows that Alaska s oil fields offer attractive CO 2 - EOR and CO 2 utilization potential. CO 2 -EOR Technology Status Economic* Oil Recovery/CO 2 Demand - - Alaska Economic Fields Crude Oil CO 2 Demand (No. of Fields) (Billion Barrels) (Gt) Current Technology 14 5.1 3.1 Next Generation Technology *At $90/B oil price, $40/mt CO 2 price, and 20% (BT) ROR... 23 10.9 4.4 13

The Residual Oil Zone In a series of reports and presentations, Steve Melzer convincingly articulates the origins and presence of oil in residual oil zones:* Below existing oil fields in ROZ intervals, Beyond existing oil fields in numerous ROZ fairways. My task today is to take the next step in assessing the ROZ resource by addressing two questions: How much of the ROZ resource below existing oil fields is recoverable? What do we know about the size of the ROZ fairway resource? *SP2 102964, The Origin and Resource Potential of Residual Oil Zones, L.S. Melzer, G.J. Koperna, and V.A. Kuuskraa, 2006. 14

Technically Recoverable ROZ Resources Below Existing Oil Fields Advanced Resources estimates that 16 billion barrels of the 42 billion barrel ROZ resource below 88 large existing oil fields is technically recoverable, creating a market for about 7 Gt of CO 2. Technically Recoverable ROZ Oil/CO 2 Demand - - Below Existing Oil Fields Basin Assessed Fields ROZ OIP Technically Recoverable* Crude Oil CO 2 Demand (No. of Fields) (Billion Barrels) (Billion Barrels) (Gt) Permian 1 55 30.7 11.9 ~5 Big Horn 2 13 4.4 1.1 0.5 Williston 3 20 6.8 3.3 1.5 *With current CO 2 -EOR technology. Sources: 1. Technical Oil Recovery Potential From Residual Oil Zones: Permian Basin report prepared by Advanced Resources International for U.S. Department of Energy, Office of Fossil Energy, Office of Oil and Natural Gas, February 2006. 2. Technical Oil Recovery Potential From Residual Oil Zones: Big Horn Basin report prepared by Advanced Resources International for U.S. Department of Energy, Office of Fossil Energy, Office of Oil and Natural Gas, February 2006. 3. Technical Oil Recovery Potential From Residual Oil Zones: Williston Basin report prepared by Advanced Resources International for U.S. Department of Energy, Office of Fossil Energy, Office of Oil and Natural Gas, February 2006. 15

Residual Oil Zone Fairways The ROZ Fairway Prize The Permian Basin ROZ Fairway map was prepared by Steve Melzer. Our quick look indicates that ROZ fairways cover an area at least three times larger than the area covered by the 55 Permian Basin oil fields with below main pay zone ROZ resources. However, additional work is required to establish the size, recoverability, economic feasibility and CO 2 requirements of producing ROZ Fairway resources with EOR. 16

The Tight Oil Resource The recent and rapid development of tight oil (liquids rich tight sand and shale formations) has enabled the U.S. to set modern day production records for crude oil production. The resource plays include the Bakken, Eagle Ford and Wolfcamp shales and the Sprayberry and Granite Wash tight sands. However, the oil recovery efficiencies of tight oil resource plays are low - - ranging generally from 3% to 7% of OOIP. Advanced Resources estimates an in-place tight oil resource on the order of 1,000 billion barrels, with 48 billion barrels technically recoverable (from 45 distinct tight oil resource plays) using today s technology and development practices. 17

Rapid Growth of U.S. Tight Oil Production Total Crude Oil Production Tight Oil Has Enabled U.S. Oil Production to Reach Modern Day Peak Source Annual U.S. Crude Oil and Liquids Fuel Supply 2012 2013 Crude Oil (MM B/D) (MM B/D) Shale/Tight 1.8 2.5 Conventional 4.7 5.0 -- L-48 Onshore 2.9 3.2 -- Offshore 1.3 1.3 -- Alaska 0.5 0.5 Total 6.5 7.5 JAF2013_055.XLS 18

Pursuing Improved Recovery Efficiencies from Tight Oil One option for increasing oil recovery efficiency from tight oil resources would be to inject CO 2 : Given its light oil and favorable depth, injection of CO 2 (as a miscible gas) would be favorable for many of the tight oil reservoirs. (Water injection into these oil wet, low permeability formations appear to be unfavorable.) Reservoir modeling by numerous investigators indicates that CO 2 flooding using Hz wells would significantly improve oil recovery at favorable CO 2 to oil ratios. 19

Reservoir Simulation of CO 2 -EOR in Bakken Shale, North Dakota A reservoir modeling study (Eclipse) by C. Dong (CSM)* was conducted in 2013 for a Masters Degree in Petroleum Engineering: Four section area of Bakken Shale in Sanish Field, North Dakota: 42 o API light oil 10,000 depth Primary recovery efficiency: 5.4% of 36 MM barrels of OOIP. EOR project consists of: 3 existing 10,000 Hz production wells 4 new long Hz injection wells CO 2 -EOR performance: Increased oil recovery of ~10 MMB (24% of OOIP) 1.1 PV of CO 2 injection (96 Bcf) The study examined a variety of CO 2 injection schemes and well patterns. *Cuiyu Dong Modeling Gas Injection into Shale Oil Reservoirs of the Sanish Field, North Dakota. 20

Reservoir Simulation of CO 2 -EOR in Bakken Shale, Montana Reservoir modeling work (Eclipse) by B. Todd Hoffman (CSM)* in 2012 (as follow on to earlier work by Shoaib and Hoffman, 2009)**, evaluated the feasibility of injecting CO 2 to enhance oil recovery from tight oil reservoirs Four section area of Bakken Shale in Elm Coulee Field, Montana: 42 o API light oil 7,500 depth (sub-sea) Primary recovery efficiency: 6% of 20 MM barrels of OOIP. EOR project consists of: 6 existing 5,000 Hz production wells 4 new Hz CO 2 injection wells CO 2 -EOR performance: ~4 MM barrels (~20% of OOIP) of increased oil recovery ~15 MMcfd (0.3 HCPV) of CO2 injection Optimization of well patterns improves oil recovery and CO 2 injectivity. *SPE 154329, Comparison of Various Gases for Enhanced Recovery from Shale Oil Reserves ; April, 2012. **SPE 123176, CO2 Flooding the Elm Coulee Field, April, 2009. 21

Size of the CO 2 Utilization/Storage Prize? CO 2 -EOR already offers a large market for utilization and storage of anthropogenic CO 2. Adding CO 2 demand for ROZ Fairways and tight oil would further increase the size of the prize. Current "Next Generation" CO2-EOR Technology CO2-EOR Technology Anthropogenic GW Size Anthropogenic GW Size CO2 Demand Coal-Fired Plants** CO2 Demand Coal-Fired Plants** (Gt) (#) (Gt) (#) Lower-48 Onshore* 4.8 40 12.5 104 Lower-48 Offshore 0.3 2 3.9 32 Alaska 3.1 26 4.4 37 Residual Oil Zone Below Oil Fields 7.0 58 7.0 58 TOTAL 15.2 126 27.8 231 JAF2013_064.XLS Existing Markets *Excludes 2.7 Gt of natural CO2 supply. **Assuming the 1,100 pounds per MWh standard for existing coal-fired power plants require capture of 120 MMmt of CO2 (over 40 years) per GW of capacity. Note: Current coal-fired power generation capacity is about 300 GWs. 22

Advanced Resources International www.adv-res.com Office Locations Washington, DC 4501 Fairfax Drive, Suite 910 Arlington, VA 22203 Phone: (703) 528-8420 Fax: (703) 528-0439 Houston, Texas 11931 Wickchester Ln., Suite 200 Houston, TX 77043-4574 Phone: (281) 558-6569 Fax: (281) 558-9202 23