Copper (II) Sulphide CAS No 1317-40-4 MATERIAL SAFETY DATA SHEET SDS/MSDS SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifiers Product name : Copper (II) Sulphide CAS-No. : 1317-40-4 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Industrial & for professional use only. 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New Delhi-10002 INDIA Telephone : +91 11 49404040 Email : care@cdhfinechemical.com 1.4 Emergency telephone number Emergency Phone # : +91 11 49404040 (9:00am - 6:00 pm) [Office hours] SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. 2.2 Label elements Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher. SECTION 3: Composition/information on ingredients 3.1 Substances Formula : CuS Molecular weight : 95.61 g/mol CAS-No. : 1317-40-4 EC-No. : 215-271-2 No components need to be disclosed according to the applicable regulations. Page 1 of 6
SECTION 4: First aid measures 4.1 Description of first aid measures If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. In case of skin contact Wash off with soap and plenty of water. In case of eye contact Flush eyes with water as a precaution. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Sulphur oxides, Copper oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. Avoid breathing vapours, mist or gas. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Sweep up and shovel. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13. SECTION 7: Handling and storage 7.1 Precautions for safe handling Provide appropriate exhaust ventilation at places where dust is formed.normal measures for preventive fire protection. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Handle and store under inert gas. Moisture sensitive. Storage class (TRGS 510): Combustible Solids Page 2 of 6
7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated SECTION 8: Exposure controls/personal protection 8.1 Control parameters 8.2 Exposure controls Appropriate engineering controls General industrial hygiene practice. Personal protective equipment Eye/face protection Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. Body Protection Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Respiratory protection is not required. Where protection from nuisance le (EN 143) dust masks. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Do not let product enter drains. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties a) Appearance Form: powder b) Odour c) Odour Threshold d) ph e) Melting point/freezing Melting point/range: 220 C - dec. point f) Initial boiling point and boiling range g) Flash point Not applicable h) Evaporation rate i) Flammability (solid, gas) j) Upper/lower flammability or explosive limits k) Vapour pressure l) Vapour density Page 3 of 6
m) Relative density 4.6 g/ml at 25 C n) Water solubility o) Partition coefficient: n- octanol/water p) Auto-ignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties 9.2 Other safety information SECTION 10: Stability and reactivity 10.1 Reactivity 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials Strong oxidizing agents, Strong acids 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Sulphur oxides, Copper oxides Other decomposition products - In the event of fire: see section 5 SECTION 11: Toxicological information 11.1 Information on toxicological effects Acute toxicity Copper sulphide Skin corrosion/irritation (Copper sulphide) Serious eye damage/eye irritation (Copper sulphide) Respiratory or skin sensitisation (Copper sulphide) Germ cell mutagenicity Hamster(Copper sulphide) ovary DNA damage Hamster(Copper sulphide) Embryo Morphological transformation. Page 4 of 6
Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity (Copper sulphide) Specific target organ toxicity - single exposure (Copper sulphide) Specific target organ toxicity - repeated exposure Aspiration hazard (Copper sulphide) Additional Information RTECS: GL8912000 Symptoms of systemic copper poisoning may include: capillary damage, heada central nervous system excitation followed by depression, jaundice, convu renal failure. Chronic copper poisoning is typified by hepatic cirrhosis, copper deposition in the cornea as exemplified by humans with Wilson's di lead to hemolytic anemia and accelerates arteriosclerosis., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.(copper sulphide) SECTION 12: Ecological information 12.1 Toxicity 12.2 Persistence and degradability 12.3 Bioaccumulative potential 12.4 Mobility in soil (Copper sulphide) 12.5 Results of PBT and vpvb assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vpvb) at levels of 0.1% or higher. 12.6 Other adverse effects SECTION 13: Disposal considerations 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. SECTION 14: Transport information 14.1 UN number ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods Page 5 of 6
IATA: Not dangerous goods 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: - 14.4 Packaging group ADR/RID: - IMDG: - IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out SECTION 16: Other information Further information The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. Central Drug House (P) Ltd and its Affiliates shall not be held liable for any damage resulting from handling or from contact with the above product. See www.cdhfinechemical.com for additional terms and conditions of sale. Page 6 of 6