MATERIAL SAFETY DATASHEET January 2013 Priming plaster coat to be applied under mineral and silicone renders 1. Identification of the mixture and of the company/undertaking 1.1 Product identifier Trade name: ROCKWOOL 1.2 Relevant identified uses of the substance or mixture and uses advised against 1.2.1 Identified uses: Ready-to-use, well coating priming plaster containing fine quartz particles to be applied under mineral, acrylic, oxosilane, silicone and silicate renders. Owing to its distinctive features, it is recommended for the priming of all kinds of concrete, ceramic and cement-lime surfaces which will be plastered. It can be applied indoors and outdoors. 1.2.2 The uses advised against: No data available Product type: Priming plaster coat to be applied under mineral and acrylic plasters 1.3 Details of the supplier of the safety data sheet ROCKWOOL, Pencoed, Bridgend, CF35 6NY REACH registration number 01-2119472313-44 ROCKWOOL Ltd Technical Support Department 9am-5pm Tel: +44 (0)871 222 1780 Em@il: SDS@rockwool.com 2. Hazards identification 2.1 Classification of the substance or mixture The classification is compliant with Directive 1999/45/EC. According to classification criteria for mixtures and manufacturer s data, the product is not classified as hazardous mixture (Section 15, item 4, 13, 25). 2.2 Label elements Labelled according to Directive 1999/45/EC. The product is not classified as hazardous mixture and does not require labelling indicating danger (Section 15, item 4, 13, 25). 2.3 Other hazards No data available 3. Compostion/information on ingredients 3.1 Substances No data available 3.2 Mixtures Composition: Suspension of pigments and fillers in styreneacrylic water dispersion and silicone emulsion with an addition of auxiliary agents. Hazardous components: Please see table below 4. First aid measures 4.1 Description of first aid measures General recommendations: the notes concerning safety and use provided on the label must be observed. Should the symptoms occur or if in doubt, consult a doctor. If unconscious, do not provide any liquids. Exposure through inhalation: remove to fresh air. Provide rest and warmth. Consult a physician. Ingestion: flush mouth with water, drink plenty of water. Do not induce vomiting! Call a physician, show packaging or label. Chemical name EC No CAS No % in the product Mixture of 5-chloro- 2-methyl-2Hisothiazol-3-on and 2- methyl-2hisothiazol-3-on (3:1) 55965-84-9 0,00015-0,00105 Substance classification T; R23/24/25; C; R34; R43 N; R50-53 Formaldehyde 200-001-8 50-00-0 <=0.0015 Carc.Cat. 3; R40 T;R23/24/25 C; R34; R43 Substance labelling T; N R: 23/24/25-34-43-50/53 S: (2-)-26-28-36/37/39-45-60-61 NOTE B; NOTE D; T; R: 23/24/25-34-40-43 S:(1/ 2-)26-36/37/39-45-51 N-formal 5395-50-6 0.03-0.0375 R43 R43 none product labelling depending on the concentration (except S-phrases) none none
MATERIAL SAFETY DATASHEET January 2013 4. First aid measures continued Contact with skin: IMMEDIATELY take a shower. Immediately remove contaminated clothing and shoes. Rinse affected skin areas with plenty of water and soap. Wash contaminated clothing before reuse. In case of irritation, seek medical advice. Contact with eyes: rinse abundantly with plenty of water (10-15 min). Protect the unaffected eye, remove contact lenses. Immediately call an ophthalmologist. 4.2 Most important symptoms and effects, both acute and delayed Undefined 4.3 Indication of any immediate medical attention and special treatment needed Undefined 5. Firefighting measures 5.1 Extinguishing media Suitable extinguishing media: dry powder, water, foam. Adjust extinguishing media to the surrounding materials. Unsuitable extinguishing media: water jet risk of fire spread. 5.2 Special hazards arising from the substance or mixture The product itself is not flammable, extinguish fire in the surrounding area with extinguishing media suitable for the cause of the fire. 5.3 Advice for firefighters Only well-trained and properly equipped personnel may take part in rescue operations. Bystanders should be immediately dismissed from the danger zone. Do not stay in the danger zone without adequate fire-resistant clothing to chemicals and self-contained breathing apparatus. Sprinkle the containers exposed to fire with water spray at a safe distance. Prevent fire-fighting water from entering into the surface or groundwater. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Use suitable protective clothing, gloves, eyes/face protection; avoid contact with eyes and skin. Unprotected personnel shall be removed from the endangered area. Follow local regulations concerning accident handling procedures. 6.2 Environmental precautions Do not allow concentrated product to enter surface or ground water. 6.3 Methods and material for containment and cleaning up In case of large spills, collect with adsorbent material (e.g. sand, diatomaceous earth, sawdust) into labelled container for disposal. Flush residues with plenty of water, then collect water and transfer for disposal do not discharge into drains. 7. Handling and Storage 7.1 Precautions for safe handling Comply with the occupational safety and health regulations. Avoid contact with skin and eyes, use according to recommendations, do not eat or drink when using this product. Wash hands during breaks and after work. It is recommended to use general room ventilation. Detailed information on application of the product is provided in technical data sheet. 7.2 Conditions for safe storage, including any incompatibilities Keep in a separate, well-ventilated room, in original, tightly closed containers; keep container in upright position; store at room temperature. Prevent freezing and overheating it may affect stability and application characteristics of the product. 7.3 Specific end use(s) 8. Exposure controls/personal protection 8.1 Control parameters Monitoring procedures for concentrations of hazardous components in the air and the procedures for air purity control at workplace should be used if available and reasonable at a particular workplace in accordance with appropriate Polish or European Standards considering conditions at the exposure site and appropriate measurement methods adapted to the working conditions. The procedure, type and frequency of tests and measurements should meet the requirements of Regulation of the Ministry of Health of 2 February 2011 (Journal of Laws Dz.U No. 33, item 166). Methods for the assessment of exposure to chemical agents by respiratory track are specified in European Standard PN-EN: Workplace atmospheres guidance for the assessment of exposure to chemical agents for comparison with limit values and measurement strategy. Hygienic standards for work environment are presented in Regulation of Minister of Labour and Social Policy of 29 November 2002 on occupational exposure limit values (Journal of Laws Dz.U. No. 217, item 1833, with further amendments). Chemical name CAS No. NDS mg/m 3 Mixture of 5-chloro- 2-methyl-2H-isothiazol-3-on and 2-methyl -2H-isothiazol-3-on (3:1) 8.2 Exposure controls observe health and hygiene regulations at workplace, do not eat or drink at workplace. After finishing work, each time wash your hands. Personal protective equipment: NDSCh mg/m 3 559565-84-9 n/a n/a n/a Formaldehyde 50-00-0 0.5 1.0 n/a NDSP mg/m 3 N-formal 5395-50-6 n/a n/a n/a 6.4 Reference to other sections No references
MATERIAL SAFETY DATASHEET January 2013 8. Exposure controls continued Respiratory protection: The product is not hazardous to health if it is handled properly no special protective measures are required. If dust concentrations at workplace exceed permissible exposure limits, use respiratory protection, such as a face mask or halfmask with dust cartridge; in emergency situations use selfcontained breathing apparatus independent of surrounding air. Eye protection: close-fitting safety glasses (goggles) or face shield. Hand protection: protective gloves. The gloves should be made of an impermeable material resistant to the product. The glove material should be selected considering the breakthrough time, permeation rate and degradation. Furthermore, the selection of the suitable gloves does not only depend on the material, but also on other quality parameters and depends on the specific manufacturer. The exact breakthrough time has to be determined by the manufacturer of the protective gloves and should be observed. Individual protection measures used should meet the requirements of the Regulation of the Minister of Economy of 21 December 2005 (Dz.U. Journal of Laws No 259, item 2173) and Directive 89/686/EC (as amended). The employer is obliged to provide protective measures adequate for the performed activities meeting all quality requirements, including maintenance and cleaning. Environmental exposure controls: Do not allow the product to enter sewage or drainage system or waste water. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: Thick liquid Odour: Characteristic, acrylic ph (25 O C): 8.5-8.9 Boiling point/range ( O C): ca. 100 Flash point: Non-flammable Flammability: Non-flammable Auto-ignition temperature: Explosive properties: Oxidising properties: Vapour pressure (20 O C): Specific gravity (g/dm 3 ): ca. 1.8 Water dilutability (25 O C): Dilutable 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid Protect against overheating, direct sunlight and freezing. Avoid strong alkalies. Application temperature: 5 o C 25 o. 10.5 Incompatible materials Lack of data 10.6 Hazardous decomposition products No hazardous reactions and hazardous decomposition products are expected when the product is used as intended. 11. Toxicological information 11.1 Information on toxicological effects The product shows slightly alkaline reaction. Long-term skin contact may cause temporary redness. It may cause eye irritation. When swallowed, the product may cause irritation of mouth, throat and stomach. In case of inhalation, the product may cause irritation of respiratory tract. Chemical name Test Value mg/kg Mixture of 5-chloro-2- methyl-2h-isothiazol-3- on and 2-methyl-2Hisothiazol-3-on (3:1) 12. Ecological information 12.1 Toxicity Non-toxic 12.2 Persistence and degradability Stable in normal conditions. 12.3 Bioaccumulative potential Lack of data 12.4 Mobility in soil The product is not mobile LD50 LD50 >2000 1096 12.5 Result of PBT and vpvb Assessment No data available Routes of exposure dermal oral Species 12.6 Other adverse effects Do not allow large product quantities to enter the ground water, drains, sewage or soil. rat rat 9.2 Other information Lack of data 10. Stability and reactivity 10.1 Reactivity 10.2 Chemical stability
January 2013 13. Disposal considerations 13.1 Waste treatment methods Product: Must be subject to special treatment according to official regulations the product must be transferred to an authorized hazardous waste collector. The material can be disposed by controlled incineration in accordance with local, national law, in systems intended for this particular purpose. Do not allow the product to enter sewage system or other water waste and open tanks. Packaging: Disposal in compliance with current regulations. Completely emptied and dried plastic packaging may be transferred to recovery; it can be reused after thorough cleaning. Recommended cleaner: water, if necessary with addition of cleaning agents. Waste product code: 08 01 waste from the manufacture, formulation, supply, use (MFSU) and removal of paint and varnish 08 01 18 waste from paint or varnish removal containing organic solvents or other dangerous substances Waste code-packaging: 15 01 02 plastic packaging 15 01 04 metallic packaging 14. Transport information 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) 14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code The product is not classified as dangerous as per transport regulations; it is not subject to transport classification and labelling. The product does not present any hazard to transport when shipped in the original packaging. Transport temperature above +5 C. 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture 1. Regulation (EC) No. 1907/2006 of the European Parliament and of the Council of 18th December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), foundation of European Chemicals Agency, amending Directive 1999/45/EC and establishing a European Chemicals Agency, amending Directive 1999/45/ EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/ EEC, 93/67/EEC, 93/105/EC and 2000/21/EC [1] (The Official Journal of EU L396/1 of 30.12.2006) with amendments (The Official Journal of EU L268/14 of 09.10.2008; The Official Journal of EU L46/3 of 17.02.2009; The Official Journal of EU L164/7 of 26.06.2009; The Official Journal of EU L86/7 of 01.04.2010; The Official Journal of EU L133/1 of 31.05.2010; The Official Journal of EU L44/2 of 18.02.2011; The Official Journal of EU L134/2 of 21.05.2011. 2. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/ EC, and amending Regulation (EC) No 1907/2006 (Text with EEA relevance) (The Official Journal of EU L353/1 of 31.12.2008). 3. Commission Regulation (EU) No 453/2010 of 20 May 2010 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). 4. Directive 1999/45/EC of the European Parliament and of the Council of 31 May 1999 concerning the approximation of the laws, regulations and administrative provisions of the Member States relating to the classification, packaging and labelling of dangerous preparations. 5. Council Directive 94/55/EC of 21.07.1994 on the approximation of the laws of the Member States with regard to the transport of dangerous goods by road (The Official Journal of EU L319 of 12.12.1994) amended by Commission Directive 2004/111/EC (The Official Journal of EU L365 of 10.12.2004). 6. Council Directive 91/689/ on hazardous waste, amended by Council Directive 94/31EC and extended by Council Decision 94/904/CE establishing a list of hazardous waste. 7. Act of 20 April 2004 related to change of some acts as result of European Union membership gained by the Republic of Poland (Dz.U. Journal of Laws of 2004, No 96, item 959). 8. Act of 27 April 2007 on waste materials (Dz. U. Journal of Laws of 2001, No 62, item 628); Announcement of the Speaker of Parliament of 14 September 2010 on the publication of unanimous text of Act on waste materials (Dz. U Journal of Laws of 2010, No 185, item 1243). 9. Law on packaging and packaging waste of 11 May 2001 (Dz. U. Journal of Laws No 63 item 638), (Dz. U. Journal of Law of 2003 No. 7, item 78), (Dz. U. Journal of Laws No. 11, item 97), (Dz. U. Journal of Laws of 2004, No. 96, item 959), (Dz. U. Journal of Laws of 2005, No. 175, item 1458).
January 2013 15. Regulatory information continued 10. Environment protection law of 27 April 2001 (Dz. U. of 2008, No 25, item 150). 11. Act of 19 August 2011 on carriage of dangerous goods by rail (Dz. U. Journal of Laws No. 227, item 1367). 12. Regulation of Minister of Health of 20 April 2012 on labelling of packages of hazardous substances and preparations and on the transfer of hazardous mixtures and some other mixtures (Dz. U Journal of Laws of 2012, No. 79, item 445). 13. Regulation of Minister of Health of 10.08.2012 on criteria and methods of classification of chemical substances and mixtures (Dz.U. Journal of Laws of 2012, item 1018). 14. Labour Code Act of 26 June 1974 (unanimous text: Dz. U. Journal of Laws of 1998, No. 21, item 94, with further amendments). 15. Regulation of Minister of Labour and Social Policy of 27 November 2002 on maximum admissible concentrations and intensities for agents harmful to health at workplace (Dz. U. Journal of Laws No 217, item 1833) as amended (Dz.U. Journal of Laws Dz.U. of 2002, No 212, item 1769), (Dz. U. Journal of Laws of 2007 No. 161, item 1142), (Dz. U. Journal of Laws of 2009 No. 105, item 873), (Dz. U. Journal of Laws of 2010 No. 141, item 950), Dz. U. Journal of Laws of 2011 No. 274, item 1621). 16. Regulation of Minister of Health of 2 February 2011 on tests and measurements of agents harmful to health in the working environment (Dz. U. Journal of Laws of 2011, No. 33, item 166). 17. Regulation of Minister of Economy of 21 December 2005 on essential requirements for personal protection means (Dz. U. Journal of Laws of 2005, No. 259, item 2173). 18. Statement of Government of 16.01.2009 on entering into force amendments to Attachments A and B to Agreement concerning the International Carriage of Dangerous Goods by Road (ADR), concluded at Geneva on 30 September 1957 (Dz. U. Journal of Laws of 2007 No. 99, item 667), (Dz. U. Journal of Laws of 2009 No. 27, item 162). 19. Regulation of the Minister of Labour and Social Policy of 26 September 1997 on general occupational health and safety provisions (Dz.U. Journal of Laws of 2003 No 169. item 1650 of 2003), with further amendments (Dz. U. Journal of Laws of 2007 No 49, item 330), (Dz. U. Journal of Laws of 2008 No. 108, item 690), (Dz. U. Journal of Laws of 2011 No. 173, item 1034). 20. Regulation of the Minister of Environment of 27 September 2001 on Waste Catalogue (Dz.U. Journal of Laws of 2001 No 112, item 1206). 21. Regulation of the Council of Ministers of 10.09.1996 on certain occupations prohibited to women (Dz. U. Journal of Laws of 1996 No. 114, item 545), with further amendments (Dz. U. Journal of Laws of 2002 No. 127, item 1092). 22. Regulation of Minister of Health and Social Welfare of 30 May 1996 on executing medical tests of employees, occupational health on employees and medical certifications issued for the purposes specified in the Labour Code (Dz. U. Journal of Laws of 1996 No. 69, item 32), with further amendments (Dz. U. Journal of Laws of 1997 No. 60, item 375), (Dz. U. Journal of Laws of 1998 No. 159, item 1057), (Dz. U. Journal of Laws of 2001 No. 37, item 451), (Dz. U. Journal of Laws of 2001 No. 128, item 1405), (Dz. U. Journal of Laws of 2010 No. 240, item 1611). 23. Regulation of Council of Ministers of 24.08.2004 on list of occupations prohibited to juveniles and conditions of employment for some occupations (Dz. U. Journal of Laws of 2004 No. 200, item 2047) with further amendments: (Dz. U. Journal of Laws of 2006 No. 107, item 724), (Dz. U. Journal of Laws of 2005 No. 136, item 1145). 24. Act of 29 July 2005 on prevention of drug abuse (Dz. U. Journal of Laws of 2012, item 124) with further amendments; Regulation of European Parliament and of the Council of 11 February 2004 on drug precursors (Journal of Laws L047 of 18.02.2005) and Commission Regulation (EC) and the Council 111/2005 of 22.12.2004 laying down rules for the monitoring of trade between the Community and third countries in drug precursors (The Official Journal of EU L22 of 26.01.200, page 1; The Official Journal of EU Polish special edition of 2005, vol. 48, page 1), and further amendments (Dz. U. Journal of Laws of 2011 No. 63, item 322). 25. Act of 25 February 2011 on chemical substances and their mixtures (Dz. U. Journal of Laws of 2011 No. 63, item 322). 26. Act of 17 October 2003 on amending the act on chemical substances and preparations and on amendments to some acts (Dz. U. Journal of Laws of 2003 No. 189, item 1852), (Dz. U. Journal of Laws of 2009 No. 20, item 106). 27. Regulation of Minister of Health of 30 December 2004 on safety and hygiene standards applicable to chemical agents at working environment (Dz. U. Journal of Laws of 2005 No. 11, item 86). 28. Regulation of the Minister of Environment of 26 January 2010 on reference values for certain substances in the air (Dz. U. Journal of Laws of 2010 No. 16, item 87). 29. Regulation of Minister of Environment of 24 July 2006 on conditions to be met for the introduction of sewage into the water or soil, and on substances particularly harmful to the aquatic environment (Dz.U. Journal of Laws of 2006 No. 137, item 984). 30. Act of 24 August 1991 on fire protection. Announcement of the Speaker of Parliament of 15 October 2009 on the publication of unanimous text of Fire Protection Act. 31. Regulation of Minister of Inferior and Administration of 7 June 2010 on fire protection of buildings, other objects and areas (Dz. U. Journal of Laws of 2010 No. 109, item 719). 32. Commission Regulation (EU) No 252/2011 of 15 March 2011 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards chemicals. 33. Commission Regulation (EU) No 286/2011 of 10 March 2011 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures. 34. Commission Regulation (EU) No 253/2011 of 15 March 2011 amending Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH) as regards Annex XIII.
January 2013 15. Regulatory information continued 35. PN-Z-04008-7:2002: Principles for collecting air samples in working environment and interpretation of results. 15.2 Chemical safety assessment Not available for the mixture 16. Other information Names of hazardous components as presented on label: none Hazardous abbreviations: not applicable Safety phrases (S-Phrases): S1/2 Keep locked up and out of the reach of children. S2 Keep out of the reach of children. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of water. S29 Do not empty into drains. S36/37/38 Wear suitable protective clothing. Wear suitable gloves. In case of insufficient ventilation, wear suitable respiratory equipment. S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S51 Use only in well-ventilated areas. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Statement of manufacturer This Safety Data Sheet has been prepared in accordance with European Commission Regulation (EU) No 453/2010 (REACH). This data sheet does not constitute a workplace assessment. The information provided represents the state of our knowledge regarding this material at the date of its publication. The information provided does not constitute a product specification and no warranty expressed or implied is hereby made. The information relates only to the specific material designated when used in applications it has been designed for. This information may not be valid for such material used in combination with any other materials or in any other processes, unless specified in the text. Other labels: none Risk phrases (R-Phrases): R23/24/25 Toxic by inhalation, in contact with skin and if swallowed R34 Causes burns R40 Limited evidence of a carcinogenic effect R43 May cause sensitization by skin contact R50 Very toxic to aquatic organisms R53 May cause long-term adverse effects in the aquatic environment R50/53 Very toxic to aquatic organisms, may cause longterm adverse effects in the aquatic environment Other indications: Xi Irritant N Dangerous to the environment C Corrosive T Toxic Other information: this issue of the MSDS cancels all previous issues. Scope of amendment: this issue includes the amendment of legal grounds, graphical layout and some substantive amendments.