Material Safety Data Sheet Issuing Date 16-Jul-2013 Product Name Recommended Use Supplier Address JemPak 80 Doney Cres. Concord Ontario L4K 3P1 CA Phone:1-905-738-5656 Fax:1-905-738-1462 Contact:Elena Ferrante Email:eferrante@jempakgk.com Contact Phone1-905-709-5197 1. PRODUCT AND COMPANY IDENTIFICATION Greate Value Dishwasher Powder Pacs Dishwasher detergent. Revision Number 3 CAUTION! 2. HAZARDS IDENTIFICATION Emergency Overview Oxidizing agent May be harmful if swallowed May cause skin, eye, and respiratory tract irritation Product dust may be irritating to eyes, skin and respiratory system Appearance White Physical State Solid/Powder, Solid. Odor Lemon Potential Health Effects Principle Routes of Exposure Acute Toxicity Eyes Skin Inhalation Ingestion Chronic Effects Aggravated Medical Conditions Environmental Hazard Skin contact. Eye contact. Severely irritating to eyes. May cause irritation. t an expected route of exposure. Inhalation of dust in high concentration may cause irritation of respiratory system. t an expected route of exposure. May be harmful if swallowed. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Ingestion may cause irritation to mucous membranes. known effect based on information supplied. Skin disorders. See Section 12 for additional Ecological Information. Page 1 / 7
3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS- Weight % Sodium carbonate 497-19-8 40-70 Sodium sulfate 7727-73-3 15-40 Sodium Citrate 6132-04-3 10-30 Sodium percarbonate 15630-89-4 7-13 Sodium silicate 1344-09-8 5-10 Supplier Trade Secret Proprietary 3-7 Supplier Trade Secret Proprietary 1-5 4. FIRST AID MEASURES Eye Contact Skin Contact Inhalation Ingestion tes to Physician Protection of First-aiders Rinse thoroughly with plenty of water, also under the eyelids. Consult a physician. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Move to fresh air in case of accidental inhalation of vapors or decomposition products. If symptoms persist, call a physician. Call a physician or Poison Control Center immediately. Do NOT induce vomiting. Drink plenty of water. Never give anything by mouth to an unconscious person. Treat symptomatically. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. 5. FIRE-FIGHTING MEASURES Flammable Properties Flash Point Suitable Extinguishing Media t flammable. t applicable. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Uniform Fire Code Oxidizer: Class 1--Solid This product contains a Class 1 Oxidizer as defined by the Uniform Fire Code Hazardous Combustion Products Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge Carbon oxides... Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. NFPA Health Hazard 1 Flammability 0 Stability 1 Physical and Chemical Hazards OX Page 2 / 7
6. ACCIDENTAL RELEASE MEASURES Personal Precautions Avoid contact with skin, eyes and clothing. Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Pick up and transfer to properly labeled containers. Keep in suitable and closed containers for disposal. Use personal protective equipment. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Handling Storage Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wear personal protective equipment. Store in original container. Keep out of the reach of children. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines Engineering Measures Personal Protective Equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Hygiene Measures This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. For home use. special protective equipment required. special protective equipment required. protective equipment is needed under normal use conditions. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Odor Threshold ph Flash Point Decomposition Temperature Melting Point/Range Flammability Limits in Air White. Odor Lemon. Physical State Solid/Powder Solid t applicable. Autoignition Temperature Boiling Point/Range Explosion Limits Water Solubility Evaporation Rate Vapor Density Completely soluble data available Solubility Vapor Pressure Partition Coefficient: n- octanol/water data available Page 3 / 7
10. STABILITY AND REACTIVITY Stability Incompatible Products Conditions to Avoid Hazardous Decomposition Products Hazardous Polymerization Stable under recommended storage conditions. Strong oxidizing agents. Dust formation. Heat, flames and sparks. Carbon oxides. Hazardous polymerization does not occur. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Product Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium carbonate = 4090 mg/kg ( Rat ) - = 2300 mg/m 3 ( Rat ) 2 h Sodium sulfate > 10000 mg/kg ( Rat ) - - Sodium percarbonate = 1034 mg/kg ( Rat ) - - Sodium silicate = 1153 mg/kg ( Rat ) - - Chronic Toxicity Chronic Toxicity known effect based on information supplied. Target Organ Effects ne known. 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Sodium carbonate EC50: 242 mg/l (120 h ) Nitzschia LC50: 300 mg/l (96 h static) Lepomis macrochirus LC50: 310-1220 mg/l (96 h EC50: 265 mg/l (48 h ) Sodium sulfate static) Pimephales promelas LC50: 3040-4380 mg/l (96 h static) Lepomis macrochirus LC50: 13500 mg/l (96 h ) Lepomis macrochirus LC50: 13500-14500 mg/l (96 h ) Pimephales promelas LC50: > 6800 mg/l (96 h static) Pimephales promelas Sodium Citrate EC50: 18000-32000 mg/l (96 h ) Chlorella vulgaris LC50: 18000-32000 mg/l (96 h ) Poecilia reticulata Sodium percarbonate EC50: 70 mg/l (240 h ) LC50: 70.7 mg/l (96 h static) Chlorella emersonii Pimephales promelas Sodium silicate LC50: 301-478 mg/l (96 h ) Lepomis macrochirus LC50: 3185 mg/l (96 h semistatic) Brachydanio rerio EC50: 2564 mg/l (48 h ) EC50: 630 mg/l (96 h ) EC50: 5600-10000 mg/l (48 h ) EC50: 4.9 mg/l (48 h ) Daphnia pulex EC50: 216 mg/l (96 h ) Page 4 / 7
13. DISPOSAL CONSIDERATIONS Waste Disposal Methods Contaminated Packaging This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Dispose of in accordance with local regulations. California Hazardous Waste Codes 561 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California EHW California Carc California Hazardous Waste California Waste - Part 2 Sodium carbonate Corrosive Sodium percarbonate Ignitable 14. TRANSPORT INFORMATION DOT TDG MEX ICAO IATA IMDG/IMO NOT REGULATED Page 5 / 7
15. REGULATORY INFORMATION International Inventories TSCA DSL Complies t determined U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of 1990. CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name Massachusetts New Jersey Pennsylvania Illinois Rhode Island Sodium sulfate X X International Regulations Mexico - Grade Moderate risk, Grade 2 Canada This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. WHMIS Hazard Class D2B Toxic materials Page 6 / 7
16. OTHER INFORMATION Prepared By Issuing Date Revision Date Revision te Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 16-Jul-2013 15-Jul-2013 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet Page 7 / 7