Managing Contraction and Stress in an Ambient Pressure Insulated 9%Ni Subsea Cryogenic Pipeline

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Rice Global E&C Forum, Houston, Texas Managing Contraction and Stress in an Ambient Pressure Insulated 9%Ni Subsea Cryogenic Pipeline C. Neal Prescott, Jeff Zhang Fluor Offshore Solutions, USA 14 November 2008

Acknowledgements Fluor Client Fluor Management Fluor Subsea LNG Pipeline Team Cabot Corporation Eisenbau Krämer Corus Tubes Brück Astro Technology Southwest Ocean Services / Sampson Rope Det Norske Veritas (DNV) American Bureau of Shipping (ABS) 14 November 2008 Rice Global E&C Forum - Houston 2

Presentation Outline Offshore Transfer of LNG Options Ambient Pressure Insulated 9% Ni Steel Subsea LNG Pipeline Technology Key Technology Issues Case Study Conclusions 14 November 2008 Rice Global E&C Forum - Houston 3

Typical Dock, Trestle & Pipelines Dredged Turning Basin Dredged 9-km Ships Channel 1..2-km Rock Groin Breakwater Onshore Gas Liquefaction Facility Cryogenic Pipelines on 6-km trestle Offshore Loading Terminal 14 November 2008 Rice Global E&C Forum - Houston 4

Offshore Trestles / Causeways (Fluor Case History) Aramco Ju Aymah LPG Terminal Saudi Arabia 10-km trestle Mid-1970 s Original trestle cost estimate $68 million Final installed cost $268 million Problems with pile driving and construction schedule. 14 November 2008 Rice Global E&C Forum - Houston 5

Typical Dock, Subsea Pipelines Dredged Turning Basin Dredged 9-km Ships Channel Onshore Gas Liquefaction Facility 6-km Cryogenic Pipelines Offshore Loading Terminal 1..2-km Rock Groin Breakwater 14 November 2008 Rice Global E&C Forum - Houston 6

Ambient Pressure Insulated 9% Ni Steel Subsea LNG Pipeline Aerogel Insulation (Cabot Nanogel TM Expansion Pack TM ) ASTM A 553 Type 1 (9% Ni Steel) Product Pipe Fluor Patent Pending Design Concrete Weight Coating (if required) External Carbon Steel Casing Pipe (or 9% Ni Steel if required) 14 November 2008 Rice Global E&C Forum - Houston 7

Contraction Reduction Bulkheads 14 November 2008 Rice Global E&C Forum - Houston 8

Ambient Pressure Insulated 9% Ni Steel Subsea LNG Pipeline Configuration 9% Ni Steel for Product Line 9% Ni Steel Bulkheads at Ends Ambient Pressure in Annular Space Nitrogen filled, slight overpressure Vent tubes Aerogel Insulation Monitoring System Simple Fabrication and Assembly, Proven Installation Techniques Fluor Patent Pending Design 14 November 2008 Rice Global E&C Forum - Houston 9

Comparison of Pipe Material Costs Material Relative Yield Stress Yield Stress Cost (MPa) @ 0 o C (MPa) @ -196 o C Invar TM 36% Ni 14 270 650 9% Ni Steel 6 585 847 316L Stainless Steel 5 250 400 API X52 Carbon Steel 1 359 14 November 2008 Rice Global E&C Forum - Houston 10

Comparison of Costs (7 km LNG Pipeline Fluor and 3 rd Party Studies) Not to Scale Trestle + Polyfoam Subsea Competitors 25% - 45% Fluor 60% 14 November 2008 Rice Global E&C Forum - Houston 11

Key Technical Issues 9% Ni Steel Welding Procedure Weld Mechanical Properties CTE Mismatch between Weld and Pipe Bulkhead Fabrication Procedure Mechanical Integrity Stress and thermal load on connecting systems Contraction Fatigue Life Brittle Fracture Insulation Material Recent Technology Developments Have Resolved All Issues 14 November 2008 Rice Global E&C Forum - Houston 12

9%Ni Plates 9% Nickel Steel Pipe Have been widely used for cryogenic storage tanks since the 1960 s. Have proven to be well suited for cryogenic service. 9%Ni Pipe EisenBau Krämer has 3 mills in Germany and are specialists in Longitudinal Welded Large Diameter Pipe 14 November 2008 Rice Global E&C Forum - Houston 13

9% Ni Welding Technology Development EBK started development 5 years ago Numerous welding consumables and welding procedures investigated Welding Procedure now ready for project application Matched plate strength Applicable to both longitudinal and girth welds CTE mismatch issue resolved Welding Procedure qualified by ABS and DNV for longitudinal and girth welding 14 November 2008 Rice Global E&C Forum - Houston 14

World s First 9%Ni Steel Line Pipe 9Ni Pipe during Production Steel: ASTM 553 Type I (Source: EisenBau Krämer) 14 November 2008 Rice Global E&C Forum - Houston 15

9Ni Pipe Weld longitudinal weld girth weld Source: EBK, Stainless Steel World America 2008, Houston, 9-10 September 2008, Paper PS08040 14 November 2008 Rice Global E&C Forum - Houston 16

9% Ni Welding Technology Development Corus Tubes started development 4 years ago Now manufactures 9%Ni Alloy Pipe on its UOE double submerged arc welded (DSAW) mill in Hartlepool, UK. Longitudinal Welding Procedure has been developed to generate material properties in the weld that exceed those in the parent plate. Girth Welding Procedure now being developed. 14 November 2008 Rice Global E&C Forum - Houston 17

Cabot Nanogel Expansion Pack Insulation System Hydrophobic Elastically Compressible Low Conductivity High-Efficiency Aerogel Insulation System 14 November 2008 Rice Global E&C Forum - Houston 18

History of Aerogel 1931: Aerogel invented by Dr. Steven Kistler 1950: Monsanto commercialized an aerogel under trade name Santocell. Exited business in 1970 because of high production costs using old manufacturing method. 1950: First patent issued on use of aerogel for cryogenic storage tank by Air Products 1961: Patent issued to Chicago Bridge & Iron for aerogel in cryogenic storage tanks 1996: NASA uses aerogel for thermal insulation on Mars spacecraft 1996-1998: New cost-efficient aerogel manufacturing processes developed by Cabot and others 2004: Aerogel first used in deepwater subsea oil pipelines 2008: Cabot Nanogel Compression Packs to be used for world's longest aerogel-insulated subsea tieback in US Gulf of Mexico (Helix Danny project) 14 November 2008 Rice Global E&C Forum - Houston 19

Nanogel Expansion Pack -Cryogenic Vibration Test (Photo Source: Cabot Corporation) This is one of the mechanical and thermal tests performed on Nanogel Expansion Packs to confirm suitability to LNG service 14 November 2008 Rice Global E&C Forum - Houston 20

Case Study 8 KM 14 November 2008 Rice Global E&C Forum - Houston 21

Pipelines LNG Pipelines (2) LPG Pipelines (2) LPG Cool-Down Pipeline LNG BOG Return Pipeline Utilities Pipelines (10) Power and Communication Cables (2) 14 November 2008 Rice Global E&C Forum - Houston 22

Monitoring System Multiple Redundancies for Highly Reliability Temperature Measurements along Pipeline Leak Detection by Temperature and Annulus Pressure Intrusion Detection Bulkhead Monitoring PLET Monitoring Annulus Venting 14 November 2008 Rice Global E&C Forum - Houston 23

Redundancies and Safety Margin Strength of 9% Ni Steel SMYS at room T used in the design Bulkheads: inherent 100% redundancy Two conical sections Fatigue life 900 times the number of likely complete full thermal cycles (10) Monitoring System 14 November 2008 Rice Global E&C Forum - Houston 24

Thermal Hydraulic Performance Loading Satisfies Pressure and Heat Gain Limits LNG Pipeline: OHTC = 0.107 W/m 2 /K including spacer effect LNG Recycle Boil-Off Gas Rate Satisfactory Commissioning: One Week Duration Natural Warm-Up: One Month LNG purging can expedite warm-up 14 November 2008 Rice Global E&C Forum - Houston 25

Pipeline Contraction and Stress Software ABAQUS FEA software for main pipeline AUTOPIPE for connection piping Multiple end condition (anchored/free) combinations Parameters sensitivity studies: soil, burial, dimensions, length, water depth 380 Stress (MPa) 360 340 320 300 Inner Pipe Stress Onshore end anchored Offshore end free 0 1000 2000 3000 4000 5000 6000 7000 8000 X Distance (m) 14 November 2008 Rice Global E&C Forum - Houston 26

Pipeline Analysis Results 32 X44 LNG Pipeline, Onshore Anchored, Offshore Free Max inner pipe stress 374 MPa 64% SMYS Max outer pipe stress 106 MPa 24% SMYS Offshore end displacement 200 mm Onshore anchor displ. 62 mm Onshore anchor load 4351 kn Pipeline max vert. displ. 15 mm Pipeline stress within limit, and contraction acceptable for all sensitivity cases, and for other dimensions and length 14 November 2008 Rice Global E&C Forum - Houston 27

LNG Bulkhead FEA Analysis Stresses well within allowable values Linearized Stress is used in ASME Code to compare with Allowable acceptable acceptable acceptable 14 November 2008 Rice Global E&C Forum - Houston 28

LNG Bulkhead Buckling Calculation Compressive forces in split-sleeve are checked for buckling Maximum compressive stress is 10817 psi Well below limit of 43308 psi No Risk for Buckling 14 November 2008 Rice Global E&C Forum - Houston 29

LNG Bulkhead Brittle Fracture Calculation Brittle fracture analysis per API 579 considered due to low product temperature Bulkhead radius and LNG pipe-to-bulkhead weld are critical areas Assumed 360 circumferential flaw with depth of ¼ thickness Factor of 2.0 applied to stresses at welds to account for discontinuities at or near surface. 14 November 2008 Rice Global E&C Forum - Houston 30

LNG Bulkhead Brittle Fracture Calculation Fatigue/strength results fall within accepted values. Component OD (in) t (in) Crack Size (in) T ( F) K 1 (ksi in) K 1C (ksi in) CVN (ft lbs) Bulkhead Radius 37.0 0.75 0.1875 20 59.16 105 73 Inner Pipe 32.0 0.375 0.09375-256 59.18 70 33 Mid Bulkhead 32.5 0.75 0.1875-256 53.48 70 33 Bulkhead Mid Leg 38.0 0.75 0.1875-93 40.42 70 33 Welds Outer Casing 44.0 0.75 0.1875 37 0.112 70 33 Outer Pipe 44.0 0.75 0.1875 53 24.72 53 20 14 November 2008 Rice Global E&C Forum - Houston 31

LNG Bulkhead Fatigue Calculation All allowable cycles are well above the defined cycles for each event. 14 November 2008 Rice Global E&C Forum - Houston 32

Design Code /Criteria Check Issue Analysis Results Applicable Codes/Notes Pipe Stress - Max Stresses: ASME B31.4 Longitudinal Inner Pipe = 374 MPa Allowable = 80% SMYS (64% SMYS) Outer Pipe = 120 MPa (27% SMYS) Bulkhead Stress Max. Stress = 359 MPa ASME Sec VIII Div 2 Allowable = 3 X Sm = 100 ksi (690 MPa) Membrane+ Bending Stresses Fatigue Min fatigue life: Bulkhead 8996 Full thermal cycles Small local plastic region allowed per code ASME Sec VIII, Appendices 4 and 5 Fatigue life conservatively based on carbon steel curve. 14 November 2008 Rice Global E&C Forum - Houston 33

Design Code/Criteria Check Issue Analysis Results Applicable Codes/Notes Brittle Fracture Bulkhead radius: 0.1875 deep defect allowed K 1 = 59.2 ksi*in 1/2 Bulkhead welds: 0.09375 deep defect allowed at inner pipe K 1 = 59.2 ksi* in 1/2 API 579 Bulkhead radius: Allowable K 1C = 105 ksi* in 1/2 Bulkhead welds: Allowable K 1C = 70 ksi* in 1/2 Buckling Max stresses: Split sleeve = 74 MPa compression ASME Code case 2286 Max Allowable Stresses: Split Sleeve = 300 MPa (local) 299 MPa (column) 14 November 2008 Rice Global E&C Forum - Houston 34

Fabrication Lay down and Storage Launch and Assembly Main Rail 1200 - m 1-km Pipeline Strings Fabricate 500-m pipe sections Hydro-Test 500-m pipe sections Assemble 500-m Pipe-in-Pipe Test Monitoring & Vent Systems Weld 2 x 500-m Sections together Field Joint Insert Nitrogen & Deploy Insulation String Make-Up Area 140-m 60-m 200-m 14 November 2008 Rice Global E&C Forum - Houston 35 35

Layout of Fabrication Facility 14 November 2008 Rice Global E&C Forum - Houston 36

Pipeline Installation - Pulling General Area of Pipe Pull Barge set-up for intermediate pipe-pull operations. General Area of Pipe Pull Barge set-up for final pipe-pull operations. 14 November 2008 Rice Global E&C Forum - Houston 37

Heavy Lift Barge for PLET and Platform Installation 14 November 2008 Rice Global E&C Forum - Houston 38

Qualification by Certification Agencies ABS Approval in Principle Issued April 2006 Fit for Service Certificate Issued October 2008 DNV Approval in Principle Issued March 2006 In final review for issuing Fitness for Service Certificate; expected date is end of Nov 2008 14 November 2008 Rice Global E&C Forum - Houston 39

14 November 2008 Rice Global E&C Forum - Houston 40

Conclusions Technology breakthrough on welding enables the application of 9% Ni steel in subsea LNG pipelines The Case Study on the ambient pressure insulated 9%Ni steel subsea LNG pipelines show that The stresses in the LNG pipe and bulkheads satisfy design codes with significant margins Contraction are acceptable Fatigue life is 900 times the number of thermal cycles likely to be encountered Thermal performance is satisfactory The pipeline technology provides significant cost advantage The pipeline technology has received Fit for Service certification, is ready for project use 14 November 2008 Rice Global E&C Forum - Houston 41

Thank You! 14 November 2008 Rice Global E&C Forum - Houston 42

Discussion C. Neal Prescott Executive Director Offshore Technology Neal.prescott@fluor.com +1 (281) 263-3361 Dr. Jeff Zhang Manager, Subsea & Deepwater Technology Jeff.zhang@fluor.com +1 (281) 263-8556 14 November 2008 Rice Global E&C Forum - Houston 43