1. Chemical and company identification Name of chemical (Product name) MATERIAL SAFETY DATA SHEET Manufacturer Nye Lubricants Address 12 Howland Road Division Fairhaven, Ma 02719 Telephone 1-508-996-6721 Fax E-mail Supplier Tsuchiya Co., Ltd. Address 9-29, Kamimaezu 2-chome, Department Naka-ku, Nagoya 460-8330 Telephone www.tsuchiya-group.co.jp Fax E-mail Emergency Contact Emergency Telephone MSDS Author Product Code 2. Hazards identification GHS classification The product is not classified according to GHS. GHS label elements Symbols Signal words Hazard statement Precautionary statement Prevention Response Storage Disposal Other hazards which do not result in classification None known. Supplemental information Not applicable. None. None. The mixture does not meet the criteria for classification. Observe good industrial hygiene practices. Wash hands after handling. Store away from incompatible materials. Dispose of waste and residues in accordance with local authority requirements. Not classified. 3. Composition/information on ingredients Substance or mixture 4. First aid measures If inhaled If on skin If in eyes If swallowed Mixture If symptoms develop, remove affected person from source of exposure into fresh air. Get immediate medical attention. Wash off with soap and water. Get medical attention if symptoms occur. Wash clothing separately before reuse. Get immediate medical attention. If ingestion of a large amount does occur, seek medical attention. Do not induce vomiting without medical advice. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give anything by mouth to a victim who is unconscious or is having convulsions. Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 1 / 6
Most important symptoms/effects, acute and delayed Protection of first-aid responders Notes to physician Direct contact with eyes may cause temporary irritation. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Treat symptomatically. 5. Fire-fighting measures Extinguishing media Water fog. Foam. Dry chemical. Dry chemical powder. Carbon dioxide (CO2). Extinguishing media to avoid Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards Special fire fighting procedures Protection of fire-fighters 6. Accidental release measures Personal precautions, protective equipment and emergency measures Environmental precautions Methods or materials for containment and cleaning up 7. Handling and storage Handling Technical measures (e.g. Local and general ventilation) Safe handling advice Contact avoidance measures Storage Hygiene measures During fire, gases hazardous to health may be formed. Move containers from fire area if you can do it without risk. Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Keep unnecessary personnel away. For personal protection, see section 8 of the MSDS. Observe precautions from other sections. Prevent entry into waterways, sewers, basements or confined areas. Soak up with inert absorbent material. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Clean contaminated surface thoroughly. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills in original containers for re-use. For waste disposal, see section 13 of the MSDS. Clean up spills immediately, observing precautions in Protective Equipment section. Sweep up and shovel into suitable containers for disposal. No specific recommendations. Observe good industrial hygiene practices. Strong oxidizing agents. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Safe storage conditions Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the MSDS). Safe packaging materials Keep in original container. 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Engineering measures Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 2 / 6
Personal protective equipment Respiratory protection Hand protection Eye protection MATERIAL SAFETY DATA SHEET An air purifying respirator with an organic vapor cartridge may be used under certain circumstances where airborne concentrations are expected to exceed exposure limits, or if irritation or symptoms are experienced. No personal respiratory protective equipment normally required. For prolonged or repeated skin contact use suitable protective gloves. Wear safety glasses; chemical goggles (if splashing is possible). Skin and body protection Wear nitrile, neoprene, PVC or viton gloves. 9. Physical and chemical properties Appearance Odor ph Physical state Form Color Liquid. Liquid. Semi-solid Light yellow Slight Melting point/freezing point Boiling point, initial boiling point, and boiling range Flash point 462.2 F (239.0 C) ASTM D-92 Upper/lower flammability or explosive limits Flammability limit - lower (%) Flammability limit - upper (%) Explosive limit - lower (%) Explosive limit - upper (%) Vapor pressure Vapor density Specific gravity Solubility(ies) Partition coefficient (n-octanol/water) Auto-ignition temperature Decomposition temperature Viscosity (Coefficient of viscosity) Other information Density Flash point class Shelf life 10. Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions 0.88 g/cm³ Combustible IIIB 4 years The product is stable and non-reactive under normal conditions of use, storage and transport. Stable. No dangerous reaction known under conditions of normal use. Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 3 / 6
Conditions to avoid Incompatible materials Hazardous decomposition products Heat, flames and sparks. Avoid temperatures exceeding the flash point. Contact with incompatible materials. Strong acids, alkalies and oxidizing agents. Carbon monoxide, carbon dioxide and/or low molecular weight hydrocarbons. 11. Toxicological information Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Knowledge about health hazard is incomplete. Respiratory sensitization Knowledge about sensitization hazard is incomplete. Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Other information 12. Ecological information Ecotoxicity Knowledge about sensitization hazard is incomplete. Knowledge about mutagenicity is incomplete. This product does not contain any carcinogens or potential carcinogens as listed by IARC. Knowledge about health hazard is incomplete. This product has no known adverse effect on human health. This material is not expected to be harmful to aquatic life. Persistence and degradability No data is available on the degradability of this product. Bioaccumulation Mobility in soil No data available. No data available. Hazardous to the ozone layer No data available. Other hazardous effects 13. Disposal considerations Dispose in accordance with all applicable regulations. Residual waste Contaminated packaging Local disposal regulations 14. Transport information International regulations IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Contract with a disposal operator licensed by the Law on Disposal and Cleaning. When your own wastewater treatment plant is not available, collect entire waste and then charge to a licensed industrial waste management professional with manifests for industrial waste. Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 4 / 6
National regulations Follow regulation in section 15 for domestic transportation. 15. Regulatory information Industrial Safety and Health Act Notifiable substances Labeling substances Poisonous and Deleterious Substances Control Act Specified poisonous substances Poisonous substances Deleterious substances Act on the Evaluation of Chemical Substances and Regulation of Their Manufacture, etc. Class I specified chemical substances Class II specified chemical substances Monitoring chemical substances Priority Assessment Chemical Substances (PACs) Reporting Exempted Substances Law concerning Pollutant Release and Transfer Register Specified class 1 substances (substance name, ordinance number and content) Class 1 substances (substance name, ordinance number and content) Class 2 substances (substance name, ordinance number and content) Ship Safety Law, Dangerous Goods Marine Transport and Storage Rule Air Law, Enforcement Rule Explosives Control Act 16. Other information Bibliography HSDB - Hazardous Substances Data Bank IARC Monographs. Overall Evaluation of Carcinogenicity National Toxicology Program (NTP) Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices Japan Society for Occupational Health, Recommendation of Occupational Exposure Limits JIS Z 7252:2009 Classification of chemicals based on Globally Harmonized System of Classification and Labelling of Chemicals (GHS) JIS Z 7253:2012 Hazard communication of chemicals based on GHS Labelling and Safety Data Sheet (SDS) Japan Chemical Industry Association (JCIA) GHS Guideline, June 2012 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release. Nye Lubricants, Inc. makes no warranty with respect thereto and disclaims all liability with respect thereon. This safety data sheet was prepared in accordance with JIS Z 7253:2012. The information in the sheet was written based on the best knowledge and experience currently available. Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 5 / 6
This data sheet contains changes from the previous version in section(s): Composition / Information on Ingredients: Component Summary Company name: Nye Lubricants, Inc. Product name 990 Version #: 07 Revision date: September-26-2014 Issue date: March-01-2011 6 / 6