Page 1/7 1 Identification of substance Product details MSDS ID Number: M-85875 Manufacturer/Supplier: W.R. Grace & Co. -Conn. 62 Whittemore Avenue Cambridge, MA 02140 Grace Canada, Inc. 294 Clements Road W. Ajax, Ontario L1S 3C6 Canada Information department: Environmental Health & Safety : +1-617-876-1400 (24 hours) +1-800-354-5414 (8AM - 5PM) t functional within Massachusetts In Canada: +1-905-683-8561 Transport Emergency: Chemtrec +1-800-424-9300 (24 hours) * 2 Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Hazardous components: 8052-42-4 Asphalt 50-100% 64742-04-7 Extracts (petroleum), heavy paraffinic distillate solvent 20-30% 9003-55-8 Styrene-butadiene rubber 10-20% * 3 Hazards identification Hazard description: Harmful Information pertaining to particular dangers for man and environment: SDS's are not required for finished articles. nevertheless, the following information is provided to assist with safe use. Harmful by inhalation. Eye Contact: Causes eye irritation. Skin Contact: Causes skin irritation. Ingestion: Harmful if swallowed. (Cont. on page 2)
Page 2/7 NFPA ratings (scale 0-4) 2 1 0 Health = 2 Fire = 1 Reactivity = 0 (Cont. from page 1) HMIS-ratings (scale 0-4) HEALTH *2 FIRE 1 REACTIVITY 0 Health = *2 Flammability = 1 Reactivity = 0 Additional information: Contact with residue from adhesive may cause eye and skin irritation. Skin absorption of residue may be harmful and may produce local skin tumors. * 4 First aid measures After inhalation: Adverse effects are not likely. If symptoms develop, get fresh air. If symptoms persist, consult a physician. If breathing has stopped, give artificial respiration then oxygen if needed. After skin contact: Immediately wash contaminated skin with soap or mild detergent and water. If this chemical soaks clothing, immediately remove clothing and wash skin. If residue remains, clean with waterless handcream or abrasive soap. Never use solvents. If skin irritation continues, consult a doctor. After eye contact: If contact with residue causes eye irritation, flush eyes with water for at least 15 minutes while holding eyelids open. Seek immediate medical advice. After swallowing: Due to physical nature of this product, ingestion is not likely. 5 Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Additional information Collect contaminated fire fighting water separately. It must not enter the sewage system. * 6 Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. (Cont. on page 3)
Page 3/7 Measures for cleaning/collecting: Sweep up spilled product into receptacles. Dispose contaminated material as waste according to section 13 of the MSDS. (Cont. from page 2) * 7 Handling and storage Handling: Information for safe handling: Avoid eye and skin contact with residue from adhesive. Release liners are slippery. Remove from work area immediately after membrane application. To avoid skin contact, use gloves. Clean hands after contact with adhesive residue. Membrane is slippery when wet or covered with frost. Release liners may cause slip and trip hazards. FOR PROFESSIONAL USE ONLY. KEEP OUT OF CHILDREN'S REACH. Information about protection against explosions and fires: Empty containers may retain hazardous residue, both liquid and vapor. Removal of release liner may generate a static electrical discharge (spark). Storage: Information about storage in one common storage facility: Store in original containers. Further information about storage conditions: ne. 8 Exposure controls and personal protection Additional information about design of technical systems: further data; see item 7. Components with limit values that require monitoring at the workplace: 8052-42-4 Asphalt REL Short-term value: C 5* mg/m³ *15-min TLV 0.5* mg/m³ *inh. fraction; as benzene-soluble aerosol; BEIp 7783-06-4 hydrogen sulphide PEL Short-term value: C 20; 50* ppm *10-min peak; once per 8-hr shift REL Short-term value: C 15* mg/m³, C 10* ppm *10-min TLV Short-term value: (21) 7 mg/m³, (15) 5 ppm Long-term value: (14) 1.4 mg/m³, (10) NIC-1 ppm Additional information: The lists that were valid during the creation were used as basis. (Cont. on page 4)
Page 4/7 Personal protective equipment: General protective and hygienic measures: Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Gloves should be worn to prevent skin contact and should be impermeable and resistant to the product. (Cont. from page 3) Material of gloves Gloves should be impermeable and resistant to the product. Selection of material should be considered before use. Eye protection: Tightly sealed goggles Safety glasses with side shields should be worn to prevent contact due to splashing. Under high vapor mist concentrations, tightly sealed goggles should be worn. Body protection: Protective work clothing * 9 Physical and chemical properties General Information Form: Color: Odor: Solid According to product specification Characteristic Change in condition Melting point/melting range: Undetermined. Boiling point/boiling range: Undetermined. Flash point: > 210 C (> 410 F) Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. Density at 20 C (68 F): ~1.1 g/cm³ (~9.18 lbs/gal) Solubility in / Miscibility with Water: t miscible or difficult to mix. 10Stability and reactivity Thermal decomposition: decomposition if used according to specifications. Dangerous products of decomposition: Carbon monoxide and carbon dioxide (Cont. on page 5)
Page 5/7 Additional information: See section 7 for information on handling, storage and conditions to be avoided. (Cont. from page 4) * 11Toxicological information Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: 12Ecological information Additional ecological information: General notes: Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. 13Disposal considerations Product: Comply with Federal, State and local regulations. Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. 14Transport information Maritime Transport IMDG: Marine pollutant: * 15Regulations SARA (Superfund Amendments and Reauthorization Act) Section 302/304 (extremely hazardous substances): Section 313 Reportable Ingredients (Chemicals present below reporting threshold are exempt): SARA Section 312/Tier I & II Hazardard Catagories: Health Immediate (acute) Health Delayed (chronic) Yes Flammable Reactive Pressure (Cont. on page 6)
Page 6/7 National Chemical Inventory Status TSCA (Toxic Substances Control Act - United States): All ingredients are listed or exempt from listing unless otherwise noted below. Remarks: CEPA (Canadian DSL): All ingredients are listed or exempt from listing unless otherwise noted below. California Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: WHMIS Classification(s): D2B - Toxic material causing other toxic effects Carcinogenicity Categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) 9003-55-8 Styrene-butadiene rubber 8052-42-4 Asphalt 14807-96-6 Talc NTP (National Toxicology Program) (Cont. from page 5) TLV-ACGIH (Threshold Limit Value for Carcinogens established by ACGIH) 8052-42-4 Asphalt A4 14807-96-6 Talc A4 NIOSH-Cancer (National Institute for Occupational Safety and Health) 8052-42-4 Asphalt OSHA-Cancer (Occupational Safety & Health Administration) European EINECS (Cont. on page 7)
Page 7/7 Philippines Inventory of Chemicals and Chemical Substances PICCS Inventory of Existing Chemical Substances manufactured or imported in China IECSC Australian Inventory of Chemical Substances AICS Existing and New Chemical Substance List ENCS Inventory listing could not be confirmed for one or more substances. Korean Existing Chemical Inventory Product related hazard information: Hazard symbols: Harmful Hazard-determining components of labelling: hydrogen sulphide Risk phrases: Harmful by inhalation. Safety phrases: Keep container in a well-ventilated place. Do not breathe gas/fumes/vapor/spray. Wear suitable protective clothing. This material and its container must be disposed of as hazardous waste. (Cont. from page 6) * 16Other information "The data included herein are presented in accordance with various environment, health and safety regulations. It is the responsibility of a recipient of the data to remain currently informed on chemical hazard information, to design and update its own program and to comply with all national, federal, state and local laws and regulations applicable to safety, occupational health, right-to-know and environmental protection." Department issuing MSDS: Other Information: BITUTHENE LOW TEMPERATURE WATERPROOFING MEMBRANE, MEMBRANE STRIPS BITUTHENE SYSTEM 4000 WATERPROOFING MEMBRANE, MEMBRANE STRIPS PERM-A-BARRIER WALL FLASHING, PERM-A-BARRIER WALL MEMBRANE, PERM-A-BARRIER LOW TEMPERATURE MEMBRANE, PERM-A-BARRIER DETAIL MEMBRANE, GRACE ICE & WATER SHIELD, GRACE ROOF DETAIL MEMBRANE, PITTWRAP CW, GRACE SELECT, VYCOR V40 WEATHER BARRIER STRIPS, GRACE VYCOR PLUS TAPES, GRACE BASIK, GRACE VYCOR DECK PROTECTOR, GRACE VYCOR ALL PURPOSE FLASHING, GRACE VYCOR ALUMINUM FLASHING, PREPRUFE SCS DETAIL TAPE, GENERIC 40-MIL FLASHING LOG, PERM-A-BARRIER ALUMINUM FLASHING, Perm-A-Barrier Detail Membrane S, PAB Aluminum Flashing S, PERM-A-BARRIER ALUMINUM MEMBRANE, PERM-A-BARRIER ALUMINUM MEMBRANE LOWTEMP