Winter Air Quality in Yellowstone National Park

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National Park Service U.S. Department of the Interior Natural Resource Program Center Winter Air Quality in Yellowstone National Park 2008-2009 Natural Resource Technical Report NPS/NRPC/ARD/NRTR 2010/285

ON THE COVER Upper Gyser Basin in Yellowstone National Park, Wyoming Photograph by JR Douglass

Winter Air Quality in Yellowstone National Park 2008-2009 Natural Resource Technical Report NPS/NRPC/ARD/NRTR 2010/285 John D. Ray, Ph.D. National Park Service Air Resources Division PO BOX 25287 Denver, CO 80225 February 2010 U.S. Department of the Interior National Park Service Natural Resource Program Center Denver, Colorado

2008 GPMP Data Summary The National Park Service, Natural Resource Program Center publishes a range of reports that address natural resource topics of interest and applicability to a broad audience in the National Park Service and others in natural resource management, including scientists, conservation and environmental constituencies, and the public. The Natural Resource Technical Report Series is used to disseminate results of scientific studies in the physical, biological, and social sciences for both the advancement of science and the achievement of the National Park Service mission. The series provides contributors with a forum for displaying comprehensive data that are often deleted from journals because of page limitations. All manuscripts in the series receive the appropriate level of peer review to ensure that the information is scientifically credible, technically accurate, appropriately written for the intended audience, and designed and published in a professional manner. This report received informal peer review by subject-matter experts who were not directly involved in the collection, analysis, or reporting of the data. Views, statements, findings, conclusions, recommendations, and data in this report are those of the author(s) and do not necessarily reflect views and policies of the National Park Service, U.S. Department of the Interior. Mention of trade names or commercial products does not constitute endorsement or recommendation for use by the National Park Service. This report is available from the NPS Air Resources Division (http://www.nature.nps.gov/air) and the Natural Resource Publications Management Web site (http://www.nature.nps.gov/publications/nrpm) on the Internet. Please cite this publication as: Ray, J. D. 2010. Winter air quality in Yellowstone National Park: 2008-2009. Natural Resource Technical Report NPS/NRPC/ARD/NRTR 2010/285. National Park Service, Denver, Colorado. NPS 101/101071, February 2010 ii

Executive Summary The air quality in Yellowstone National Park was monitored at two locations within the park as part of the adaptive management program on the use of over-snow winter motor vehicles and at a location near the center of West Yellowstone. The leading indicators used were ambient concentrations of carbon monoxide (CO) and particulate matter of 2.5 micrometers or less (PM 2.5 ). The monitoring data from West Entrance near the town of West Yellowstone, MT is the primary indicator for overall air quality and the relationship to traffic, because of its longer record and detailed traffic counts. Old Faithful is a destination for most of the winter use vehicles; CO and PM 2.5 concentrations are lower at Old Faithful than at the West Entrance. CO and PM 2.5 are also monitored outside the park in the town of West Yellowstone, MT in cooperation with the park; summary data are reported here for comparison. The results for the winter season of 2008-2009 are: Hourly and 8-hour average concentrations of CO are down slightly at the West Entrance, but are nearly the same as the previous year at Old Faithful. Air quality at Yellowstone meets the national standards set by the Environmental Protection Agency (EPA) for CO and PM2.5 to protect human health. The CO, however, is present above regional background concentrations (between 0.1 and 0.2 ppm) in areas near vehicle routes, especially during the winter. Daily average concentrations of PM2.5 continue to decrease in the park while measurements of PM2.5 within the town of West Yellowstone are the same or higher than in previous winters. PM2.5 concentrations in the Town of West Yellowstone do not violate the national standard. This report updates prior air quality and emission reports. Prior reports (http:// www.nature.nps.gov/air/studies/yell/ yellaqwinter.cfm) provide monitoring details and background information. iii

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Introduction This report is an annual update that summarizes the carbon monoxide (CO) and particulate matter of 2.5 micrometers or less (PM 2.5 ) monitoring data from winter 2008-2009. It also provides a historical perspective on monitoring data at Yellowstone National Park (Ray 2007, 2008). The primary objective is to identify trends in air quality that might reflect on winter use policy and present conditions as compared to the national standards set by the Environmental Protection Agency (EPA) (EPA 2008). Details on monitoring locations and methods were given in prior reports (Air Resource Specialists 2009; Ray 2007, 2008). (http://www.nature.nps.gov/air/ studies/yell/yellaqwinter.cfm ) Summary Statistics Hourly data are summarized here for comparison to the National Ambient Air Quality Standard (NAAQS) set by EPA for CO and PM2.5 and to several other statistical metrics used in prior reports. The standards given in Table 1 are for averaging periods of 1-hour, 8-hours, or 24-hours. Normally, air quality data compared to a standard encompass a full year. However, the data summary tables here are only for the winter vehicle traffic period in Yellowstone National Park, a three-month period when snow conditions are suitable for over-snow travel. Summaries of over-snow vehicle (OSV) traffic counts are provided in Tables 2 and 3. The OSV traffic is down for the 2008-2009 winter by 28% for the West Entrance (NPS 2009). The daily average snowmobile traffic is about 112 units/ day through the West Entrance and 174 units/day for all entrances. In practice, holidays and weekends tend to have higher traffic counts and other periods less. Table 1. Ambient air quality standards (AAQS) for carbon monoxide (CO) and particulate matter less than 2.5 micrometers (PM 2.5 ) ppm = parts per million; μg/m 3 = Micrograms per cubic meter Standard Pollutant 1-hr CO (ppm) * 8-hr CO (ppm) * National AAQS CO 35 9 Montana AAQS CO 23 9 Wyoming AAQS CO 35 9 Standard Pollutant 24-hr PM 2.5 98 th percentile (μg/m 3 ) New NAAQS PM 2.5 35 Montana AAQS PM 2.5 35 Wyoming AAQS PM 2.5 65 * Not to be exceeded more than once per year. Link to EPA NAAQS standards: http:// www.epa.gov/air/criteria.html ; WY DEQ http://deq.state.wy.us/aqd/standards.asp ; MT DEQ http://www.deq.state.mt.us/airmonitoring/citguide/appendixb.html The 3-year average of the 98 th percentile of 24-hour concentrations at each monitor within an area must not exceed 35 μg/m 3. The winter 98 th percentile in the associated tables is given only to demonstrate the improvement between winter seasons. Comparison with the annual standard is not shown. For consistency, the 24-hour day is used to average the hourly PM 2.5. Revised PM 2.5 standard by EPA Oct. 2006, down from 65 μg/m 3 Wyoming has proposed a state standard of 35 μg/m 3. http://deq.state.wy.us/aqd/ proposedrules.asp 1

Yellowstone NP - Winter Air Quality, 2008-2009 Table 2. Winter OSVs entering at the Yellowstone West Entrance station Winter Season Snowmobiles West Snowcoaches West West Entrance Total 2008 2009 10,139 1,495 11,634 2007 2008 14,135 1,582 15,717 2006 2007 14,682 1,453 16,135 2005 2006 13,104 1,371 14,475 2004 2005 8,743 1,185 9,928 2003 2004 14,765 1,181 15,946 2002 2003 33,458 998 34,456 2001 2002 50,888 889 51,777 2000 2001 45,689 816 46,505 1999 2000 42,620 777 43,397 1998 1999 44,213 767 44,980 1997 1998 40,869 706 41,575 * Data presented in this table are from the NPS Public Use Statistic web page: http://www.nature.nps.gov/mpur/ Table 3. Winter OSVs entering all Yellowstone gates Winter Season Snowmobiles Snowcoaches Total 2008 2009 15,655 2,418 18,073 2007 2008 23,814 2,653 26,467 2006 2007 24,516 2,448 26,964 2005 2006 21,916 2,463 24,379 2004 2005 15,695 1,926 23,842 2003 2004 22,423 2,058 17,753 2002 2003 47,799 1,653 24,076 2001 2002 69,196 1,605 49,404 2000 2001 67,653 1,591 70,787 1999 2000 62,531 1,535 69,188 1998 1999 62,878 1,396 63,927 1997 1998 60,110 1,326 64,204 * Data presented in this table are from the NPS Public Use Statistic web page: http://www.nature.nps.gov/mpur/ 2

Discussion The West Entrance station continues to have higher concentrations of CO and PM 2.5 than the Old Faithful station (Tables 4 & 5). This is a result of higher traffic density at the entrance station, where over-snow vehicles (OSV) stop and idle for a time and then accelerate (Bishop et al. 2007; Ray 2008). In addition, the air quality monitoring station is close to the road. Dual peaks in CO happen daily in correlation with the OSV traffic activity between 8-10 am and 3-5 pm. At the Old Faithful station, CO peaks between 11 am and 2 pm when there is the most OSV activity in the parking area. The CO at the West Entrance was lower in 2008-2009 than any previous year, based on all the statistical metrics of measurements. Total OSV traffic through the west entrance was also down from the previous year (Figure 1). The CO concentrations at the west entrance are now less than 10% of the National Ambient Air Quality Standard (NAAQS) set by the US Environmental Protection Agency. For CO, the NAAQS is 9 ppm for an 8-hour period (Table 1). For PM 2.5, the concentrations are less than 15% of the NAAQS and have followed a similar trend to CO at the West Entrance (Figure 2). In most urban locations these conditions would be considered acceptable air quality, although CO is still higher than the summertime conditions for CO or the regional background concentrations of about 0.15 ppm (Ray 2007, 2008) At Old Faithful, the hourly CO concentrations are now generally 1 ppm or less; 90 percent of the time the CO concentrations are 0.2 ppm or less. The PM 2.5 concentrations have remained nearly the same for the three previous winter seasons and are now close to the same as at the West Entrance station. The timing in peak PM 2.5 at Old Faithful still differs from when the peak OSV traffic is present and in that regard differs from the observations at the west entrance. Both the CO and PM 2.5 at Old Faithful are well below the NAAQS. Winter air quality at the West Entrance and Old Faithful is primarily influenced by emissions from 4-stroke snowmobile and snowcoach engines. Some smoke and pollutants are transported from town and the nearest housing units to the park entrance area when the winds are from the west. By contrast, the monitor in the town of West Yellowstone serves as a reference for conditions where 2-stroke snowmobile traffic dominates and there is a mix of wheeled vehicles and residential heating as additional CO and PM 2.5 sources. Note that the PM 2.5 concentrations are much closer to the NAAQS, possibly because of the greater emissions from 2-stroke engines in the snowmobiles. CO is elevated within the town of West Yellowstone and higher than at the park s west entrance, but does not approach the CO NAAQS. Conclusions The air quality has stabilized at the monitoring stations in Yellowstone National Park over the previous 4-5 years. This is primarily from the requirement for Best Available Technology (BAT) snowmobiles (Federal Register 2007) and a much lower number of snowmobiles entering the park (NPS 2009). Air quality statistical indicators were lower this winter than in the previous winter at the West Entrance. This partly reflects the lower number of OSV traffic during the 2008-2009 winter season. The winter air quality remains below the health standards set by EPA for the locations where monitoring occurs. 3

Yellowstone NP - Winter Air Quality, 2008-2009 Table 4. Statistical comparison of CO (ppm) between Yellowstone NP winter monitoring stations. West Entrance Winter season Max 1-hr % of Std Max 8-hr % of Std Average 90 th percentile 2 nd high 1hr CO 2nd high 8hr CO 2008-2009 2.4 7% 0.6 6% 0.2 0.3 2.3 0.6 2007-2008 6.1 17% 1.6 18% 0.2 0.4 4.2 1.5 2006-2007 3.7 11% 0.8 9% 0.2 0.3 3.5 0.8 2005-2006 2.1 6% 0.9 10% 0.2 0.4 1.7 0.7 2004-2005 2.8 8% 1.0 11% 0.2 0.4 2.6 0.9 2003-2004 6.4 18% 1.3 14% 0.3 0.5 3.1 1.1 2002-2003 8.6 25% 3.3 37% 0.6 1.3 8.4 2.1 2001-2002 16.0 46% 5.4 60% 0.7 4.9 13.7 4.9 2000-2001 17.9 51% 6.1 68% 1.0 6.0 17.4 6.0 1999-2000 13.5 39% 5.4 60% 0.8 4.7 13.1 2.6 1998-1999 18.2 52% 8.9 99% 0.3 4.3 13.1 4.3 West Yellowstone, MT Winter season Max 1-hr % of Std Max 8-hr % of Std Average 90 th percentile 2 nd high 1hr CO 2nd high 8hr CO 2008-2009 7.9 23% 3.1 34% 0.5 0.9 5.9 3.0 2007-2008 6.7 19% 2.2 25% 0.4 0.7 5.7 2.2 2006-2007 5.0 14% 2.4 27% 0.5 0.9 4.3 2.4 Old Faithful Winter season Max 1-hr % of Std Max 8-hr % of Std Average 90 th percentile 2 nd high 1hr CO 2nd high 8hr CO 2008-2009 1.1 3% 0.4 4% 0.1 0.2 0.8 0.4 2007-2008 0.9 2% 0.4 5% 0.2 0.2 0.8 0.4 2006-2007 0.9 3% 0.4 4% 0.3 0.2 0.7 0.4 2005-2006 1.6 4% 0.5 6% 0.2 0.3 1.2 0.5 2004-2005 1.6 4% 0.8 7% 0.1 0.3 1.4 0.5 2003-2004 2.2 6% 0.9 10% 0.3 0.5 1.7 0.9 2002-2003 2.9 8% 1.2 13% 0.2 0.5 2.0 1.0 4

Table 5. Statistical comparison of PM 2.5 (μg/m 3 ) between Yellowstone NP winter monitoring stations. West Entrance Winter season Max 1-hr Max Daily ( 24-hr) 98 th percentile * % of Std Average 2008-2009 53 5.1 4.8 14% 1.5 2007-2008 44 9.5 7.8 22% 2.6 2006-2007 40 8.8 8.7 25% 2.1 2005-2006 44 7.0 6.0 10% 1.9 2004-2005 21 6.0 6.0 9% 2.9 2003-2004 29 8.0 7.0 11% 4.0 2002-2003 81 15.0 17.0 26% 8.2 West Yellowstone, MT Winter season Max 1-hr Max Daily ( 24-hr) 98 th percentile * % of Std Average 2008-2009 145 27.5 27 77% 12.3 2007-2008 167 24.7 22 63% 5.6 2006-2007 119 32.0 32 91% 12.9 Old Faithful Winter season Max 1-hr Max Daily ( 24-hr) 98 th percentile * % of Std Average 2008-2009 23 5.7 5.2 15% 3.1 2007-2008 32 8.1 5.8 17% 3.2 2006-2007 20 6.6 6.4 18% 3.3 2005-2006 56 9.0 9.0 13% 3.5 2004-2005 38 6.0 9.0 14% 4.0 2003-2004 151 16.0 9.0 14% 4.9 2002-2003 200 37.0 21.0 33% 6.9 * It is recognized that the PM2.5 comparisons here are for only a 3-month winter period and not over 12-months as the PM2.5 is normally calculated. PM2.5 percent of standard are calculated based on the Oct. 2006 revised standard for consistency. 5

Yellowstone NP - Winter Air Quality, 2008-2009 Comparison of Winter Traffic and CO Concentrations West Entrance Counts 60,000 50,000 40,000 30,000 20,000 10,000 0 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 Winter End Year 9 8 7 6 5 4 3 2 1 0 2nd Max. 8-hr CO Winter vehicles 2nd Max 8-hr CO Figure 1. A comparison of the winter season OSV traffic volume through the west entrance and one metric for the air quality, the second highest daily concentration of the CO 8-hour average in ppm. 60,000 Comparison of Winter Traffic and PM 2.5 Concentrations 20 West Entrance Counts 50,000 40,000 30,000 20,000 10,000 15 10 5 98 th percentile PM2.5 0 1998 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 Winter End Year 0 Winter vehicles 98th % Daily Max PM2.5 Figure 2. A comparison of the winter season OSV traffic volume through the west entrance and one metric for the particulate matter air quality, the 98th percentile of the winter season daily average concentration. 6

Literature Cited Air Resource Specialists. 2009. Data transmittal report for the Yellowstone National Park winter use air quality study, 2008-2009. Air Resource Specialists, Fort Collins, Colorado. Available from http://www.nature.nps.gov/air/studies/yell/yellaqwinter.cfm Bishop, Gary A., R. Stadtmuller, D. H. Stedman, and John D. Ray. 2007. Portable emission measurements of snowcoaches and snowmobiles in Yellowstone National Park. J. Air & Waste Manage. Assoc. 59, 936 942 (2009). Available from http://www.feat.biochem.du.edu EPA. 2008. National Ambient Air Quality Standards (NAAQS). U.S. Environmental Protection Agency, Washington, D.C. Available from http://www.epa.gov/ttn/naaqs/ Federal Register. 2007. Rules and Regulations, Final Rule governing the winter use in three parks. Vol. 72, No. 239 / Thursday, December 13, 2007/ page 70781. Available from http://www.nps.gov/yell/parkmgmt/upload/finalrule13dec2007.pdf National Park Service, Public Use Statistics. 2009. Yellowstone visitor and vehicle count statistics. U.S. Department of Interior, National Park Service, Washington, D.C. Available from http://www.nature.nps.gov/mpur/ Ray, J. D. 2007. Winter air quality in Yellowstone National Park: 2006 2007. Natural Resource Technical Report NPS/NRPC/ARD/NRTR 2007/065. National Park Service, Fort Collins, Colorado. Available from http://www.nature.nps.gov/air/studies/yell/yellaqwinter.cfm Ray, J. D. 2008. Winter air quality in Yellowstone National Park: 2007 2008. Natural Resource Technical Report NPS/NRPC/ARD/NRTR 2008/139. National Park Service, Fort Collins, Colorado. Available from http://www.nature.nps.gov/air/studies/yell/yellaqwinter.cfm 7

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