A NEW GENERATION OF PERFORMANCE LDPE RESINS

Similar documents
Total Solutions. for Extrusion Coating & Laminating

Dow Packaging and Specialty Plastics. Solutions for Extrusion Coating

One resin can t possibly focus on all of these diverse needs. Now, however, one family of polyethylene resins can.

INNOVATION DRIVING PERFORMANCE AND FOR ROTATIONAL MOLDING APPLICATIONS

INFUSE Olefin Block Copolymers (OBCs) versus f-pvc

Chemical Resistance of TRENCHCOAT Protective Film

Innovative material science for pipe applications from a global technology leader

Case and Carton Sealing: Hot melt Adhesive Solutions

The perfect fit in stretch hood. Stretch Hood. Plastics North America. Resin Solutions

AGILITY PERFORMANCE LDPE IN BLENDS ELEVATES FILM MECHANICALS AND EXTRUSION OUTPUT TO THE NEXT LEVEL

How AFFINITY Polyolefin Plastomers Can Improve Cast Film Polypropylene Performance

improved hot melt adhesives for hard-to-bond substrates

The Material of Choice for Photovoltaic Encapsulant Films

Silane Crosslinking of Low Voltage Wire and Cable Applications of ENGAGE ENR / LLDPE Blend

INFUSE Olefin Block Copolymers (OBCs) versus SEBS and f-pvc Compounds

Understanding FDA Food Packaging Regulations

PlumbShield. For use with Potable & Non-Potable Water Applications. Advantages. Standard Features

ULDPE Copolymers ATTANE. Toughness and clarity to give your packaging the winning edge. Plastics North America

Automotive Thermosets Rev-up Performance, Design, and Efficiency

IMPACT MODIFIER (21518XP) Maleic Anhydride (MAH) Grafted Polyolefin for Polyamide Applications

Flexible Acrylic Resin XP Translucent Grade

PARALOID EXL-2655 Impact Modifier For Thermoset Applications

PARALOID EXL-2690 IMPACT MODIFIER

PARALOID EXL-5900 Optical Properties Modifier For Polycarbonate and Polystyrene

PARALOID EXL-2620 (Powder) MBS Impact Modifier For Polycarbonate, Polyesters and their Blends

PARALOID TMS-2670 MBS Impact Modifier For Epoxy Resin Applications

D.E.R. 330 Liquid Epoxy Resin

AIRSTONE Mold Building System

The extreme performance polymer: Exceed XP performance polymers. Mosha H. Zhao ExxonMobil Chemical Company February 25, 2019 Houston, TX

This product is suitable for use in applications such as: Civil Engineering Marine and Protective Coatings

Highly Efficient LDPE Resins for Extrusion Coating Applications

D.E.H. 26 Epoxy Curing Agent

New ENERLYTE Polyurethane Elastomer

Adhesives for Tapes: Packaging & beyond. Dow.com

TRENCHCOAT Protective Film

Dow Specialty Elastomers for Thermoplastic Polyolefins

Creating bio-based polyols for adhesives and sealants

Fast Facts. Trinseo MAGNUM ABS Resins (Acrylonitrile Butadiene Styrene) for Medical Applications

DOWLEX TM GM LLDPE AND AGILITY TM PERFORMANCE LDPE FOR GREATER MEANS IN INDUSTRIAL AND CONSUMER PACKAGING APPLICATIONS

TRANSFORMATION TECHNOLOGY OVERMOLDING. Strong bonds for rigid and soft-touch plastics

TRANSFORMATION TECHNOLOGY OVERMOLDING. Strong bonds for rigid and soft-touch plastics

SURECEL 445 FOAM CELL PROMOTER

Pharma & Food Solutions. ETHOCEL One of the Few Water-Insoluble Polymers Approved for Global Pharmaceutical Applications

INJECTION MOLDING OF PULSE ENGINEERING RESINS (unfilled & filled grades)

Materials. Powering Ideas.

Materials. Powering Ideas.

D.E.R. 684-EK40 Epoxy Resin Solution

Automotive. Material Solutions for Automotive. Materials. Powering Ideas.

Rev. Oct 2017 valid until next revision

AFFINITY GA Polyolefin Elastomer-based Hot Melt Adhesives for Case and Carton Sealing Applications

Insulating and Protecting Flowlines and Subsea Equipment

Calcium Carbonate in Blown HDPE Film

Supertough 32ST05S01 Innovative Technology Polyethylene Blown Film Grade

Supplying a Multitude of Products for Measurable Results

PalmaLite Resin 2 Liquid Epoxy Resin is a mono-functional reactive diluent modified liquid epoxy resin

Sustainable Packaging Innovation: Delivering Sustainable Solutions Across the Value Chain

Product Portfolio. Construction

PACKAGING SOLUTIONS FOR IMPROVED LOAD STABILITY

Multilayer Polyethylene Films For Food Service Packaging Applications FlexPackCon 2017

Polyurethanes for roller coating ROLLERS

ENTEC POLYMERS 1900 Summit Tower Blvd., Suite 900 Orlando, FL P: EntecPolymers.com

Performance and productivity.

PARALOID K-120ND Processing Aid for Vinyl Compounds

NORTH AMERICA EPOXY CURING AGENTS EPOXY

DOW PuraGuard Propylene Glycol USP/EP. Your Security for Purity

Norman Aubee & Brad Kramer NOVA Chemicals Corporation

Helping you shape what s next

Let s jointly advance better building. WALOCEL MKW Methyl Cellulose Powering Performance of High Quality Cement Renders. Dow Construction Chemicals

SELEXOL Booster. Boosting the Performance of Physical Absorption Processes

Biaxially Oriented Polyethylene (BOPE) Films Fabricated via Tenter Frame Process and Applications Thereof

A Leap in Polyolefin Applications with Advanced Calcium Carbonates

APPLICATION Additive in polypropylene-compatible systems. TYPICAL PROPERTIES DESCRIPTION

Why Choose Blown, Cast or Lamination Processes to achieve Barrier Properties?

Dow Pharma Solutions. ETHOCEL High Productivity (HP) Polymers Safe. Fast. Efficient.

Performance-Enhancing Science Applications Coatings, Adhesives, Sealants and Elastomers

Comfort Science Solutions

D y n a m a r. Polymer Processing Additives. Eric W. Adair Advanced Chemist John Horns Specialist Application and Product Development Dyneon LLC

Product Data Sheet. Eastar Copolyester Key Attributes

MARLEX METALLOCENE POLYETHYLENE

PAPER OR PLASTIC? NEW DEVELOPMENTS IN SILICONIZING FILMIC SUBSTRATES

Material handling and industrial engineering. HYPERLAST TM and DIPRANE TM Elastomers

ETHOCEL High Productivity (HP) Polymers Safe. Fast. Efficient.

Widely accepted for use in polyethylene film applications that involve food contact see Food Contact Acceptability section.

Construction Chemicals. Cellulosics and Redispersible Powders Product Guide

ETHOCEL High Productivity (HP) Polymers Safe. Fast. Efficient.

NEXT GENERATION DOWEX MARATHON ION EXCHANGE RESINS FOR INDUSTRIAL WATER TREATMENT. Small change, big impact.

I M GREEN TM POLYETHYLENE INNOVATION AND DIFFERENTIATION FOR YOUR PRODUCT

Go Beyond Adhesion: the Dual Functionality of Tie-Layers

AMP-95. Key Performance Advantages. Multifunctional Additive for Latex Paints. We make the best perform better.

METHOCEL. TM Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow

Energy Recovery: Minimizing Landfill Discards Maximizing Resource Capture

Scapa Photovoltaic Range. Solar Module Solutions

Capstan drive units Mechanical handling rollers

UCARSOL GT 900 Antifoam

Elium Liquid thermoplastics. Room temperature cure Very high stiffness Ductile composites

CONTENTS: POLYETHYLENE POLYPROPYLENE HDPE EX EX3-88S 2 EX3-188S 3 EX5 (HM9458F) F (FILM GRADE) 5 LDPE LLDPE 289AA 6 HOMOPOLYMER

High Melt Strength Polypropylene

ABSTRACT INTRODUCTION. PO Innovations in Extrusion Coating High Value Solutions in a Critical Processing Technology

Plastolyn R1140. Hydrogenated hydrocarbon resins for improved film properties in flexible packaging

I m green tm Polyethylene Innovation and differentiation for your product

Transcription:

A NEW GENERATION OF PERFORMANCE LDPE RESINS

AGILITY PERFORMANCE LDPE MEET THE GROWING FAMILY AGILITY Resins constitute a new family of resins which is elevating the performance standards of the LDPE category through: SPEED: Enables higher throughput on existing extrusion equipment FLEXIBILITY: Offers solutions for multiple markets extrusion coating, blown and cast film, and polyolefin foams and improved long term supply security and flexibility AESTHETICS: Delivers improved optics to meet the growing need for more transparent packaging STRENGTH: Requires less LDPE in LDPE/LLDPE blends, improving physical properties while maintaining output AGILITY resins are designed to challenge the limits and bring the best performance attributes of conventional autoclave and tubular into one resin, offering customers a sustainable, long-term solution meeting and exceeding the performance targets of conventional autoclave LDPE resins. Dow has integrated this technology with its expanding global manufacturing footprint in the U.S. Gulf Coast to provide global solutions for customers and industry. Based on Dow s novel patented advanced tubular technology, AGILITY resins are a new generation of packaging resins developed to meet industry needs for higher line speed and optimal material use as well as to offer an improved long-term supply versus autoclave technology. The LDPE global market is projected to grow 2.8% annually until 225, while at the same time autoclave technology will be growing slower than the market due to old asset closures. 1 AGILITY resins have proven to deliver improved performance standards not only for extrusion coating and lamination, but also for cast and blown films and foams covering a wide range of applications: Extrusion coatings for beverages, consumer and industrial packaging Extrusion laminates for food, pharma and medical packaging Performance polyolefin foams for protective logistics packaging Lamination films for food, beverages, home and personal care goods Collation shrink films for consumer packaging Agricultural films Frozen food packaging Stand-up pouches 1 Source: IHS Global PE report, 215 2

Table 1: Overview of AGILITY Resins Commercial Product Applications Benefits Melt Index dg/min Density g/cm 3 Product Additives Extrusion Technology AGILITY 1 Agricultural films Food packaging and lamination films Shrink films.18.92 None Blown Films AGILITY 11 AGILITY 12 Stretch films for logistics packaging.65.92 None Blown Films Food packaging and lamination films Improved output/mechanics.65.921 AB Blown Films AGILITY 121 Protective foams for protective packaging Food packaging and lamination films 1.85.92 None Blown and Cast Films AGILITY 122 Bread bags 1.85.921 S/AB Blown and Cast Films AGILITY 21 High clarity collation shrink film Improved output/ mechanics/optics balance.25.924 None Blown Films NEW! AGILITY 12 Agricultural films Food packaging and lamination films Shrink films High performance blending partner for LLDPE resins such as INNATE Precision Packaging Resins, ELITE Enhanced Polyethylene (EPE) and DOWLEX Polyethylene for improved output and mechanics.25.919 None Blown Films NEW! AGILITY EC 7 Board laminates for liquid beverages and semi-solid food Tableware Food sachets Pouches for food and pharma Release liners for labels Imaging paper Medium to high density foams for protective packaging High speed/light weights for extrusion coating & lamination Very smooth surface finishing foams for protective packaging 3.9.919 None Extrusion Coating & Lamination/ Polyolefin Foams NEW! AGILITY EC 722 Paper and board coating and lamination for liquid board laminates and pouches where packaging integrity for shelf-life is key Very low density foams for protective packaging High performance blending partner for ELITE EPE for high speed/ light weights extrusion coating & lamination Light foams for protective packaging 1.5.918 None Extrusion Coating & Lamination/ Polyolefin Foams NEW! AGILITY EC 78 Paper and board coating and lamination, especially sachets for food packaging where fast packaging speed is key Very high speed/light weights for extrusion coating & lamination 8..918 None Extrusion Coating & Lamination AGILITY 1, 11, 12, 121, 122, 12, 21 NAA and LAA, for other regions availability check sales representative AGILITY EC 7, EC 722 and EC 78 global 3

RAISING THE BAR IN FILMS AGILITY Resins enable an uncoupling from conventional rules in LDPE between melt strength and melt index. This offers those customers in the blown film industry serving a wide range of applications within food and industrial packaging and agricultural films the ability to produce thinner films faster for improved conversion efficiency and sustainability. AGILITY 12 Resin is specifically designed to be used as a blending partner with LLDPE resins such as DOWLEX Polyethylene, ELITE Enhanced Polyethylene (EPE), and INNATE Precision Packaging Resins for best output/mechanics balance: Improved output: up to +18% vs. industry standard film resin such as DOW LDPE 132I/31E lower apparent viscosity at the same MI lower screen pressure (by about 1%) Higher melt strength vs. standard fractional tubular resins for improved bubble stability and processability Good film properties Dart and MD secant modulus similar to AGILITY 1 MD tear 1-25% improved Figure 1: Comparative melt strength AGILITY 12 vs. standard LDPE (19 C) Melt Strength (cn) 26 24 22 2 18 16 14 12 1 8 6 4 2 AGILITY 12 AGILITY 1 DOW LDPE 132I 1 2 3 4 5 6 7 8 Velocity (mm/s) Both at 24 cn 18 cn AGILITY 12 and AGILITY 1 Similar melt strength 33% Improvement vs. DOW LDPE 132I for better bubble stability and processability Figure 2: Packaging and conversion performance comparison in blends, 2% AGILITY 12 loading with INNATE Precision Packaging Resins Max Output Rate Average Haze Total 12% 8% 4% % Average Dart Average Secant Modulus at 2% Normalized Tear 4

RAISING THE BAR IN EXTRUSION COATING & LAMINATION AGILITY EC Resins have been specially designed to meet coatings industry needs on high conversion speed and light coating weights for improved conversion efficiency and sustainability. Additionally, AGILITY resins offer customers and the industry a sustainable, long-term supply solution to autoclave technology. In addition to the latest commercial grade, AGILITY EC 7, the first product introduced, the technology platform is expanding the family with two more resins designed to meet current and future needs of the packaging industry. AGILITY EC 7 is specifically designed to allow for: High coating speeds Light coating weights AGILITY EC 722 is specifically designed to be used as a blend partner in ELITE EPE rich blends, for example up to 7%, for: High coating speeds Light coating weights Improved sealability AGILITY EC 78 is specifically designed to allow for: Very high coating speeds Very light coating weights AGILITY resins versus incumbent autoclaves offer LDPE s following advantages: Global availability Improved long-term supply flexibility Excellent adhesion Good organoleptics Ease of process even at high speed Figure 3: Comparative neck-in AGILITY EC 7 and AGILITY EC 78 Figure 5: Comparative neck-in AGILITY EC 722 Blended with 7% ELITE 586 in all cases, extruded at 32ºC Neck-In of coating web in mm 18 16 14 12 1 8 6 4 2 25 g/m 2 3 m/min 1 g/m 2 65 m/min Neck-In of coating web in mm 25 2 15 1 5 25 g/m 2 1 m/min 25 g/m 2 3 m/min DOW LDPE 722 DOW LDPE PG 78/PT 77 DOW LDPE 71E AGILITY EC 7 AGILITY EC 78 DOW LDPE PG 74 DOW LDPE PT 77 DOW LDPE 77G AGILITY EC 722 DOW LDPE 54I Figure 4: Comparative draw down 1 AGILITY EC 7 and AGILITY EC 78 Figure 6: Comparative draw down 1 AGILITY EC 722 Blended with 7% ELITE 586 in all cases Draw Down of coating web in (m/min) 6 5 4 3 2 1 32ºC 29ºC DOW LDPE 722 DOW LDPE PG 78/PT 77 DOW LDPE 71E AGILITY EC 7 AGILITY EC 78 Draw Down of coating web in (m/min) 6 5 4 3 2 1 32ºC 29ºC DOW LDPE PG 74 DOW LDPE PT 77 DOW LDPE 77G AGILITY EC 722 DOW LDPE 54I 1 Draw down: Data generated in Pack Studios lab by fixing the throughput as 15 [g/sqm] at 1 [m/min] line speed and ramping the substrate speed until the first considerable instability of either instable web edges, edge tear or web tear occurred. 5

RAISING THE BAR IN FOAMS FOR PROTECTIVE PACKAGING The e-commerce retail market, accounting for roughly 7% of global retail sales, has been growing spectacularly over the past years, and it is projected to keep growing at double-digit rates annually. This will drive growth of the logistics packaging market and polyolefin foams 1. AGILITY Resins, designed with very high melt strength, have proven to deliver a very stable foaming process and improved mechanics, optimizing material use in polyolefin foams used mainly for protective logistics packaging. Figure 7: Comparative foam structures AGILITY EC 7 For medium to high density foams, AGILITY EC 7 offers the following advantages: Potential for smaller cell sizes Potential for reduced foam density Improved mechanical properties Reduced corrugation Broad processing window Very smooth surface For very low density foams (<2 kg/m 3 ), AGILITY EC 722 offers the following advantages: Improved cell stabilization Very good processability (equivalent to a 2. MI resin) Figure 8: Comparative foam conversion and performance AGILITY EC 7 Load at 5% Compression Average Secant Modulus @ 2% Cell Size CD 12% 8% 4% % COMPETITIVE LDPE Tensile Strength @ 25% Strain MD AGILITY EC 7 Competitive High Melt Strength LDPE Cell Size MD Tensile Strength @ 25% Strain MD 1 Source: Euromonitor, 215 6

PACK STUDIOS: A NEW MODEL FOR COLLABORATION To further enable the development of packaging innovation, Dow introduced Pack Studios, a collaborative capability of Dow Packaging and Specialty Plastics, which helps accelerate packaging application projects through a global network of labs, experts and testing equipment. Currently, there are six Pack Studios centers around the globe Freeport, Texas; Horgen, Switzerland; Mozzate, Italy; São Paulo, Brazil; Shanghai, China; and the newest location in Ringwood, Illinois near Chicago. Each center features a collaboration room to inspire solution-based thinking, laboratory facilities for material development, and fabrication and testing equipment to validate packaging applications. Customers and other members of the packaging value chain who visit Pack Studios have the opportunity to collaborate with a dedicated Dow technical team and a global network of industry professionals that have a wealth of experience in packaging application, materials and design. Talk to us. Working together will enable us to find better ways to capture the value of future opportunities in packaging applications! www.dowpackstudios.com At Pack Studios customers are able to test applications for primary, secondary and tertiary packaging. Pack Studios allows us to: Minimize the downtime associated with prototyping and testing, along with the wear and tear on your own equipment. Accelerate the development of new packaging applications by providing the materials expertise and prototype capabilities you need to deliver innovative packaging solutions. Validate packaging concepts through modeling, sensory testing, and supply chain analytics. Do quick evaluations of existing and nascent technologies for better packaging. 7

North America U.S. & Canada 1 8 441 4369 1 989 832 1426 Mexico + 1 8 441 4369 Latin America Argentina + 54 11 4319 1 Brazil + 55 11 5188 9 Colombia + 57 1 219 6 Mexico + 52 55 521 47 Europe/Middle East 8 3694 6367 31 115 672626 Italy 8 783 825 South Africa 8 99 578 Asia Pacific + 8 7776 7776 + 63 7965 5392 + 86 21 3851 4988 China + 4 889 789 dow.com dowpackaging.com The principles of Responsible Care and Sustainable Development influence the production of printed literature for The Dow Chemical Company ( Dow ). As a contribution towards the protection of our environment, Dow s printed literature is produced in small quantities and on paper containing recovered/post-consumer fiber and using 1 percent soy-based ink whenever possible. NOTICE: Any photographs of end-use applications in this document represent potential end-use applications but do not necessarily represent current commercial applications, nor do they represent an endorsement by Dow of the actual products. Further, these photographs are for illustration purposes only and do not reflect either an endorsement or sponsorship of any other manufacturer for a specific potential end-use product or application, or for Dow, or for specific products manufactured by Dow. NOTICE: No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, the Customer is responsible for determining whether products and the information in this document are appropriate for the Customer s use and for ensuring that the Customer s workplace and disposal practices are in compliance with applicable laws and other governmental enactments. Dow assumes no obligation or liability for the information in this document. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. NOTICE: If products are described as experimental or developmental : (1) product specifications may not be fully determined; (2) analysis of hazards and caution in handling and use are required; (3) there is greater potential for Dow to change specifications and/or discontinue production; and (4) although Dow may from time to time provide samples of such products, Dow is not obligated to supply or otherwise commercialize such products for any use or application whatsoever. NOTICE REGARDING MEDICAL APPLICATION RESTRICTIONS: Dow will not knowingly sell or sample any product or service ( Product ) into any commercial or developmental application that is intended for: a. long-term or permanent contact with internal bodily fluids or tissues. Long-term is contact which exceeds 72 continuous hours; b. use in cardiac prosthetic devices regardless of the length of time involved ( cardiac prosthetic devices include, but are not limited to, pacemaker leads and devices, artificial hearts, heart valves, intra-aortic balloons and control systems, and ventricular bypass-assisted devices); c. use as a critical component in medical devices that support or sustain human life; or d. use specifically by pregnant women or in applications designed specifically to promote or interfere with human reproduction. Dow requests that customers considering use of Dow products in medical applications notify Dow so that appropriate assessments may be conducted. Dow does not endorse or claim suitability of its products for specific medical applications. It is the responsibility of the medical device or pharmaceutical manufacturer to determine that the Dow product is safe, lawful, and technically suitable for the intended use. DOW MAKES NO WARRANTIES, EXPRESS OR IMPLIED, CONCERNING THE SUITABILITY OF ANY DOW PRODUCT FOR USE IN MEDICAL APPLICATIONS. This document is intended for global use. Published September, 216. 216 The Dow Chemical Company Responsible Care is a service mark of the American Chemistry Council. Dow is a partner in the American Chemistry Council Responsible Care initiative. Form No. 5-211-916 SMG SMG 12969