Specialty Polyolefins Let s progress together Evasin
Arkema Specialty Polyolefins With five brands sold globally, Arkema offers the widest range of reactive and non-reactive specialty polyolefins: Evatane ethylene vinyl acetate copolymers (18-42% VA) Lotryl ethylene acrylate copolymers Evasin* EVOH ethylene vinyl alcohol Lotader reactive polyolefins (up to 8% reactive group) Orevac T reactive EVA copolymers Orevac G grafted polyolefins (PE,PP, EVA) Arkema Specialty Polyolefins are used in applications as diverse as: Packaging Tie layer for multilayers barrier films and extrusion lamination Oxygen barrier layer Sealing and Seal/Peel resins Hot melt adhesives EVA binder High stability hot melt Deep freeze hot melt adhesives Construction Additives for bitumen rutting resistance Adhesive for pipe coating Aluminum panels Plastic compounds Impact modifiers for PA, PET, PBT, PPS, POM Coupling agents for HFFR and composites Automotive compounds Compatibilization of recycled plastics Automotive Fuel tank Sound deadening foams Thermo adhesive film Energy Cables compounds (LV, MV, HFFR) Photovoltaic panels Evasin* EVOH Oxygen barrier Ethylene content (% mol) (g/10min) 190 C - 2.16 kg 210 C - 2.16 kg Melting point ( C) Crystalization point ( C) Glass transition point ( C) O 2 Transmission Rate (65% RH) (20 C) Main applications EV 2951F 29 3 187 162 60 0.3 Bottles, pipes EV 3251F 32 1.6 3.5 183 159 59 0.38 Bottles, sheets, films EV 3851F 38 1.6 3.7 173 151 54 0.71 Sheets, thermoforming, films EV 4405F 44 5.5 166 146 56 1.35 EV 4451F 44 1.8 167 146 56 1.35 Test method ASTM D1238 / ISO 1133 DSC ISO 11357 DSC ISO 11357 DMA ISO 11357 *Evasin is a brand of Chang Chun Petrochemicals ASTM D3985 / ISO 14663-2 Sheets, thermoforming, shrinks, films Sheets, thermoforming, shrinks, films
Ethylene - Acrylate copolymers lotryl.com Bases Specified properties* Typical properties** Main applications Comonomer content (%) (g/10 min) (190 C 2.16 kg) Melting point ( C) Vicat softening Ring and ball Flexural modulus (MPa) Hardness Shore A/D 18MA02 17-20 2-3 83 53-50 -/25 20MA08 19-21 7-9 76 46-20 83/- EMA 24MA005 23-26 0.4-0.6 72 45-18 84/- Autoclave 24MA02 23-26 1-3 68 49-18 79/- 29MA03 27-31 2.0-3.5 61 <40 175 10 75/- 2012 20 ** 11 ** 79 42-25 84/21 Bestpeel 2407 24 ** 7 ** 69 <40-14 79/22 17BA04 16-19 3.5-4.5 93 60-45 -/32 28BA175 26-30 150-200 75 40 94 23 80/- EBA 30BA02 28-32 1.5-2.5 75 41 >190 <10 75/- Autoclave 35BA40 33-37 35-45 66 <40 110 <10 70/- 35BA320 33-37 260-350 65 <40 85 <10 52/- 20MA08T 19-21 7-9 97 49-36 EMA 24MA02T 23-26 1-3 95 40-17 Tubular 29MA03T 27-31 2.0-3.5 92 <40-12 35BA40T EBA 33-37 35-45 89 <23 134 <10 HMA Tubular high content 260-350 90 <23 102 <10 FTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D790 ASTM D2240 Internal method ISO 1133 ISO 11357-3 ISO 306 NF EN1238 ISO 178 ISO 868 Hot melt adhesives Films / Sheets coating Foams / Sound dampening Modification of thermoplastic polymers EBA (Ethylene-Butyl Acrylate copolymer) EMA (Ethylene-Methyl Acrylate copolymer) Extrusion coating / Lamination Cables Combined with Lotryl, some masterbatches are available to enhance slip and antiblock properties.
Ethylene - Vinyl acetate copolymers evatane.com Bases Specified properties* Typical properties** Main applications Comonomer content (%) (g/10 min) (190 C 2.16 kg) Melting point ( C) Vicat softening Ring and ball Hardness Shore A Hot Melt adhesives Films / Sheets Foams Cables 18-150 17-19 135-175 88 43 102 85 Bitumen 18-500 17-19 450-550 86 43 94 90 Bitumen 20-20 19-21 17-23 83 46 127 89 Bitumen 24-03 23-25 2.5-3.5 80 46 183 83 Bitumen 28-03 26-28 3-4.5 76 41 166 82 Crude oil 28-05 27-29 5-8 72 40 160 80 28-25*** 27-29 22-29 71 <40 120 75 Solar panel 28-40 27-29 35-45 70 <40 106 73 Crude oil 28-150 EVA 27-29 135-175 69 <40 95 71 Crude oil 28-420 27-29 370-470 66 <40 84 70 Crude oil 28-800 30-32 700-900 63 <40 80 60 Crude oil 33-25 32-34 22-29 63 <40 119 67 33-45 32-34 38-48 62 <40 107 63 33-45 PV 32-34 38-48 62 <40 107 63 Solar panel 33-400 32-34 350-450 63 <40 84 60 40-55 38-41 48-62 55 <40 97 50 42-60 >41 65-85 48 <40 95 42 Ink FTIR ASTM D1238 DSC ASTM D1525 ASTM E28 ASTM D2240 Internal method ISO 1133 ISO 11357-3 ISO 306 NF EN1238 ISO 868 EVA (Ethylene-Vinyl Acetate copolymer) * Properties routinely measured during the standard quality control procedure ** indicative average values *** Photovoltaic (PV) quality available Sound dampening Others
Reactive terpolymers lotader.com orevac.com Lotader Orevac T Typical Properties* Main applications Reactive Co-monomer group (%) Reactive group (%) (g/10 min) Melting point Vicat softening Extrusion coating / Thermoadhesive Plastic modification (190 C 2.16 kg) ( C) Lamination films Coupling agent Bitumen Cables HFFR additives Others AX8700 BA (25%) 8 9 72 - PET, PBT, PPS Foams AX8750 BA (25%) 5 12 72 - PET, PBT, PPS AX8820 GMA - 4.5 2 107 88 PET, PBT, PPS Toners AX8840 Epoxide group - 8 5 104 87 PET, PBT, PPS Toners AX8900 MA (24%) 8 6 65 <40 PET, PBT, PPS Foams AX8930 MA (25%) 3 7 67 <40 PET, PBT, PPS Foams 4210 BA (6.5%) 3.6 10 105 69 Concentrate 3210 BA (6%) 3.1 5 107 76 PA 3410 MAH BA (17%) 3.1 5 89 47 PA 3430 MA (15%) 3.1 7 84 45 PA LX4110 Maleic anhydride EA (5%) 3 5 105 78 6200 High content EA (6.5%) 2.8 40 102 66 8200 EA (6.5%) 2.8 200 100 57 Hot melt TX8030 EA (13%) 2.8 3 95 65 Pipe coating 4700 EA (29%) 1.3 7 65 <40 PA 4503 MA (20%) 0.3 8 80 45 4613 MAH MA (24%) 0.3 7 98 41 9307Y VA (14%) 0.2 10.5 93 66 Maleic anhydride 9318 VA (18.5%) 0.2 7 86 54 Low content 9304 VA (25%) 0.2 7.5 80 49 9305 VA (28%) 0.6 180 68 <40 Hot melt FTIR FTIR ASTM D1238 DSC ASTM D1525 Int. method Int. method ISO 1133 ISO 11357-3 ISO 306 MA (Methyl Acrylate) BA (Butyl Acrylate) EA (Ethyl Acrylate) VA (Vinyl Acetate)
Grafted polyolefi ns (LDPE, LLDPE, HDPE, VLDPE, EVA) orevac.com Orevac PE Orevac PP Types Base polymer Reactivity (+ medium) (++ high) Typical Properties* (g/10min.) (190 C, 2.16k) Melting point ( C) Vicat softening Extrusion coating / Lamination Cast / Blown film coex Main applications Plastic modification/ Coupling agent / Cables HFFR Sheet coex Blow molding/ Tube coex Adhesion to / Affinity with 18211 EVA + 3.5 75 51 PE / PET / PS / PA / EVOH 18302N LLDPE ++ 1.5 123 84 Coupling agent PE / Mineral fillers / natural fibers 18334 LLDPE + 1.0 125 101 PE / PA / EVOH 18341 LLDPE + 1.5 121 95 Concentrate Coupling agent Concentrate Concentrate Concentrate PE / Mineral fillers / PA/ EVOH 18342N HDPE + 3.5 125 110 PE / Epoxy primer / EVOH / 3LPE coating 18362 PE/EVA LLDPE + 2.0 123 94 PE / PA / EVOH 18507 grades HDPE ++ 5.0 128 - Coupling agent PE / Mineral fillers / natural fibers 18910 LLDPE + 1.5 117 77 PE / PS / PA / EVOH IM300 VLDPE + 1.2 112 <40 Impact modifier PA IM800 VLDPE ++ 0.5 55 <40 Impact modifier PA OE825 LLDPE ++ 3.0 118 99 Concentrate Concentrate Concentrate Concentrate PE / PA/ EVOH OE850 LLDPE ++ 7.5 104 89 Concentrate Concentrate PE: Alu / Primed films / EVOH 18722 Random PP + 7.0** 143 120 PP, PA, EVOH 18725N Random PP + 13** 124 - PP,PA, Epoxy, Metals 18729 Homo PP + 4.5** 162 137 PE, PA, EVOH PP 18732 Copo PP + 8.0** 134 120 PP, PA, EVOH, Alu, Epoxy grades 18750 Homo PP + 35** 160 121 PP, PA, EVOH, Alu 18751 Homo PP + 35** 160 138 PP, PA, EVOH, Alu CA100/CA100N Homo PP 1% 10*** 167 147 Concentrate Coupling agent PP / mineral fillers / glass & natural fibers FTIR ASTM D1238 DSC ASTM D1525 internal method ISO 1133 ISO 11357-3 ISO 306 * Indicative average values ** (230 C, 2.16 kg) *** (190 C, 325 g)
A global presence Arkema produces more than 100 Specialty Polyolefins grades in four sites in Europe and one in North America and is represented in several sales offices in Asia, Latin America. Several of our production lines have online quality control to deliver consistent quality. ISO certificates are available in our web sites. Arkema France - A French «Société Anonyme» registered with the Commercial and Companies Register of Nanterre (France) under number 319 632 790 Dircom - 4482E/01.2016/30 - pof Photos: Arkema, Thinkstock, Fotolia - Design: Rythmic Production plant R&D Sales office Depending on the grade, we offer the following packaging: 25 kg bags, 500/550 kg cardboard boxes and 1000/1100 kg big bags. Arkema operates in more than 50 countries. For help finding a local representative, please consult our web sites or contact one of the following regional customer contact centers. EUROPE Headquaters Arkema France 420, rue d Estienne d Orves 92700 Colombes FRANCE Tel.: (+33) 1 49 00 80 80 Fax: (+33) 1 49 00 83 96 NORTH AMERICA Altuglas International 100 PA Route 413 Bristol, PA 19007 USA Tel.: (+1) 215 826 2600 ASIA Arkema Pte Ltd Representative offi ce 19th Floor, ITF Tower 140/41 Silom Road, Suriyawonge Bangrak 10500 B THAILAND Tel.: (+66) 2 237 62 57 SOUTH AMERICA Arkema Quimica Ltda Av. Ibirapuera 2033 4 andar - Bairro Moema CEP 04029-901 São Paulo BRAZIL Tel.: (+55) 11 21 48 85 22 Disclaimer: Please consult Arkema s disclaimer regarding the use of Arkema s products on http://www.arkema.com/en/products/productsafety/disclaimer/index.html Regulatory information: for information on regularoty compliance, consult your local representative. Read and understand the Material Safety Data Sheet (MSDS) before using these products. evatane.com lotader.com lotryl.com orevac.com Headquarters: Arkema France 420, rue d Estienne d Orves 92705 Colombes Cedex France Tel.: 33 (0)1 49 00 80 80 Fax: 33 (0)1 49 00 83 96 arkema.com