: Lime Water, Saturated

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Transcription:

Date of issue: 05/20/2013 Revision date: 11/08/2017 Supersedes: 11/08/2017 Version: 1.1 SECTION 1: Identification 1.1. Identification Product form Product name Product code : Mixtures : Lime Water, Saturated : LC16160 1.2. Recommended use and restrictions on use Use of the substance/mixture Recommended use Restrictions on use 1.3. Supplier : For laboratory and manufacturing use only. : Laboratory chemicals : Not for food, drug or household use LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 info@labchem.com - www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Serious eye damage/eye irritation Category 2B H320 Full text of H statements : see section 16 Causes eye irritation 2.2. GHS Label elements, including precautionary statements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) : Warning 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS US) : H320 - Causes eye irritation : P264 - Wash exposed skin thoroughly after handling P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313 - If eye irritation persists: Get medical advice/attention SECTION 3: Composition/Information on ingredients 3.1. Substances 3.2. Mixtures Name Product identifier % GHS-US classification Water (CAS-No.) 7732-18-5 99.8 Not classified Calcium Hydroxide (CAS-No.) 1305-62-0 0.2 Skin Irrit. 2, H315 Eye Dam. 1, H318 Aquatic Acute 3, H402 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. 11/08/2017 EN (English US) Page 1

First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Wash skin with plenty of water. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. : Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after eye contact : Mild eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media 5.2. Specific hazards arising from the chemical Fire hazard Explosion hazard Reactivity : Water spray. Dry powder. Foam. Carbon dioxide. : Not flammable. :. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. : Dike and contain spill. 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. For emergency responders Protective equipment : Ventilate spillage area. Avoid contact with skin and eyes. : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials : Store in a well-ventilated place. Keep cool. : Strong acids. : None known. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TWA (mg/m³) 5 mg/m³ (Calcium hydroxide; USA; Time-weighted average exposure limit 8 h; TLV - Adopted Value) 11/08/2017 EN (English US) 2/6

OSHA OSHA PEL (TWA) (mg/m³) 5 mg/m³ NIOSH NIOSH REL (TWA) (mg/m³) 5 mg/m³ 8.2. Appropriate engineering controls Appropriate engineering controls Environmental exposure controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Ensure good ventilation of the work station. : Avoid release to the environment. 8.3. Individual protection measures/personal protective equipment Personal protective equipment: Safety glasses. Eye protection: Safety glasses Respiratory protection: Respiratory protection not required in normal conditions SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid. Color : Colorless Odor Odor threshold ph ph solution : 9 Melting point : Freezing point Boiling point Flash point Relative evaporation rate (butyl acetate=1) Flammability (solid, gas) :. Vapor pressure Relative vapor density at 20 C Relative density Solubility Log Pow Auto-ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosion limits Explosive properties :. 11/08/2017 EN (English US) 3/6

Oxidizing properties 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity None. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials Strong acids. 10.6. Hazardous decomposition products None. SECTION 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure Acute toxicity LD50 dermal rabbit LD50 oral rat ATE US (oral) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity single exposure Specific target organ toxicity repeated exposure Aspiration hazard Symptoms/effects after eye contact SECTION 12: Ecological information 12.1. Toxicity Ecology - general EC50 Daphnia 1 Threshold limit algae 1 : Skin and eye contact > 2500 mg/kg body weight (Rabbit; Experimental value; OECD 402: Acute Dermal Toxicity) 90000 mg/kg 90000 mg/kg body weight : Causes eye irritation. : Mild eye irritation. : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. 49.1 mg/l (EC50; OECD 202: Daphnia sp. Acute Immobilisation Test; 48 h; Daphnia magna; Static system; Fresh water; Experimental value) 184.57 mg/l (EC50; OECD 201: Alga, Growth Inhibition Test; 72 h; Pseudokirchneriella subcapitata; Static system; Fresh water; Experimental value) 11/08/2017 EN (English US) 4/6

12.2. Persistence and degradability Lime Water, Saturated Persistence and degradability Persistence and degradability Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD Persistence and degradability Biodegradability: not applicable. Adsorbs into the soil. 12.3. Bioaccumulative potential Lime Water, Saturated Bioaccumulative potential Bioaccumulative potential Bioaccumulative potential Not bioaccumulative. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Effect on the global warming GWPmix comment : No known effects from this product. : No known effects from this product. SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory 15.2. International regulations CANADA Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations 11/08/2017 EN (English US) 5/6

Listed on the Canadian IDL (Ingredient Disclosure List) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 11/08/2017 Full text of H-phrases: see section 16: H315 H318 H320 H402 NFPA health hazard NFPA fire hazard NFPA reactivity Causes skin irritation Causes serious eye damage Causes eye irritation Harmful to aquatic life : 1 - Materials that, under emergency conditions, can cause significant irritation. : 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health Flammability Physical Personal protection : 1 Slight Hazard - Irritation or minor reversible injury possible : 0 Minimal Hazard - Materials that will not burn : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. : B B - Safety glasses, Gloves SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 11/08/2017 EN (English US) 6/6