For More Information, Please Contact Us: CB - CERATIZIT (Taiwan) Group Head Office ADD: 3F., NO. 217, Sec. 2, New Taipei Blvd., Hsin Chuang Dist., New Taipei City 24250, Taiwan (R.O.C.) TEL: + 886-2-8521-6688 FAX: + 886-2-8521-1011 E-mail: sales@cbceratizit.com CB - CERATIZIT (Xiamen) China Head Office ADD: 69 Xingxi Rd, Xinglin, Jimei, Xiamen, China 361022 TEL: +86-592-666-1000 FAX: +86-592-621-9599 E-mail: sales@cbceratizit.com YOUR SOLUTION MATTERS We reserve the right to make technical changes for improvement of the product.
Blanking and Lamination EDM & Preform For Precision Stamping YOUR SOLUTION MATTERS EN
Catalogue Abstract 03 Catalogue CB-CERATIZIT Introduction... 04 Corporate Value... 06 Production Sites... 08 Grade Property & Recoendation Composition & Property... 10 Concept of NF Corrosion Free Grade... 13 Carbide Blocks For WEDM Corrosion Resistant Grade...14 Normal Grade... 15 Carbide Rods For High Speed Stamping Sintered Solid Rods...16 Ground Solid Rods... 17 Preform For Stamping Preform... 19 Abstract Catalogue Technical Information Thickness Tolerance Table... 20 Mechanical Property... 21
04 CB-CERATIZIT Introduction About CB-CERATIZIT CB-CERATIZIT is the Asian market leader in carbide rod blanks, industrial wear parts and wood & stone applications and specific cutting tool segments through quality products, fast delivery and responsive customer service. CB-CERATIZIT offers global production and technological supports as well as localised services. CB-CERATIZIT combined has more than 130 years of tungsten carbide industry experience. We are confident CB-CERATIZIT is the best partner for our growth oriented customers by providing carbide solutions. CB-CERATIZIT Introduction CB-CERATIZIT Industry Chain Tungsten Ore Aonium Paratungstate (APT) Tungsten Powder Industrial Wear Parts Rods
CB-CERATIZIT Introduction 05 1 1 21 5 17 1 1 1 Introduction Sales offices and Production sites worldwide CERATIZIT CB-CERATIZIT CB-CERATIZIT Ready to Press Powder Tungsten Carbide Wood and Stone Cutting Tools
06 CB-CERATIZIT Corporate Value CB-CERATIZIT We value customer feedback We help to shape the industry trend We improve continuously We are CB-CERATIZIT 1 Customer Service Grade Selection Guide our customer to apply best solution for success. Corporate Value CB-CERATIZIT 2 3 4 Breakthrough Achieve Outperformance Enable our customer to achieve outperformance is our key objective. Competitiveness Enhance Competitiveness Strengthen the competitiveness of our customer is our long term goal. Training Continuous Learning Nurturing talents for sustainable long term growth.
CB-CERATIZIT Corporate Value 07 Core Competency Professional, Dedication, Tailor-made service Our Promises: Customer Focus To relentlessly work to provide better solutions for our customers Stable Quality To keep stable quality contributes to our customer s brand reputation. On-time Delivery To provide lean production for our customers. Stock Availability To find solution for each and every customer s grade requirements. Comprehensive Specification To work with customers for tailor-made products. Sustainable Capacity To grow together with our customers. CB-CERATIZIT Corporate Value Continuous Research and Development To provide leadership for industry specific solutions.
08 CB-CERATIZIT Production Sites Xiamen Production Centre Established in 2003, CB-CERATIZIT Xiamen Production Centre has grown to become the leading carbide production plant in Asia. Our Excellence production centre is technologically and capably equipped to support new carbide grade innovation and dynamic customer demands. We stand by our production and inspection procedures that upkeep strictly to ISO international standard. CB-CERATIZIT Production Sites EDM & Preform Production Centre Established in 1978 & 1999, CB-CERATIZIT Taiwan & Xiamen Industrial Wear Parts Production Centre, together with production lines dedicated to manufacture EDM and preforms for high speed stamping industry, we are capable to produce wide range of customized carbide wear parts upon customer requests, CB-CERATIZIT and CERATIZIT combined has more than 130 years of tungsten carbide industry experience. We are confident that CB-CERATIZIT is the best partner for our growth-oriented customers in providin solutions for machining problem.
CB-CERATIZIT Production Sites 09 Innovative R&D Team In order to solve the corrosion problem of cemented carbide, CB CERATIZIT experts collaborated with branded WEDM machine manufacturers to create the new corrosion resistant carbide grades NF series, Corrosion resistance concept works in the beginning of grade preparation by mixing the powder with corrosion inhibitor elements. Once the NF grade carbide contacts with dielectric substance (e.g. water, lubricant etc.), a thin layer of oxide will form on the surface of the carbide for protection. It will isolate the carbide with the outside environment and thus preventing it from further corrosion, the protection is sustainable, and continuous throughout the whole machining processing. The NF series corrosion free grade has the below advantages: 1.) Able to sustain in more extreme dielectric medium condition in the WEDM process, thus help to eliminate corrosion factor due to poor filtration and also help to cut down filtration cost. 2.) Reduce extra prevention measure to avoid carbide corrosion which may affect the quality of work pieces and therefore save cost. 3.) Maintain a good surface quality after machining, improve tool life. Hardness / Wear Resistance The mechanical property of carbide can be altered by changing grain size and constitute to cope with wide range of tool performance demand. Consequently, features of CB-CERATIZIT grade can also be modified in accordance with different machining methodology. CB-CERATIZIT can offer best-fit solutions for special work piece metals such as harden material with high wear resistance, Nicochrome which can withstand high temperature, and Composite material with complicated mechanical properties. CB-CERATIZIT Production Sites Natural diamond Poly-crystal Diamond / Diamond Coating Cubic Boron Nitride Ceramic(O) Ceramic(N) Toughness Cermet High Speed Steel Carbide Criteria relevant for application Wear resistance, Hardness Compressive strength Impact strength Transverse rupture strength Tribological properties Specific weight Magnetic properties Modulus of elasticity, Rigidity Thermal properties Corrosion resistance, Resistance to oxidation Toughness
10 Grade Property & Recoendation Composition & Property TRS Grade Corrosion Free Grade Ultrafine / Fine ISO Code Co Density Hardness Fracture T.R.S. Toughness K IC (±0.5%) (g/cm 3 ) HRA HV30 kgf/ 2 MPa MPa*m 1/2 NFS16 K20~K30 8.2 14.56 92 1610 350 3430 9.5 9.5 Submicron NFS26 K40 13 14.08 90.5 1410 350 3430 12 12 Medium NFM23 K30~40 11.5 14.18 90.7 1430 340 3 11.5 NFM24 K40 12 14.1 89.8 1 340 3 12 12 Grade Property & Recoendation Composition & Property Ultrafine Submicron Fine Medium Medium/Coarse NFM25 TF25+ WF30 CF8* KG7 CF10* CF12* KG4 K30~K40 K10~K20 K10~K30 K20~K30 K40 K20~K30 K30~K40 K30~K40 12 11 13 8 15 10 12 12 14.12 14.15 14.15 14.67 13.95 14.46 14.27 14.3 88.8 92.3 90 92.2 89.3 91 90.3 89.3 1240 1660 1355 1645 1280 1470 1390 1280 320 380 350 340 340 350 340 3135 3750 3 3235 3 3 3430 3 17 17 99 12 12 10 10 13 13 12 12 12.5 13 13 KG5 K30~K40 12 14.31 88.3 1200 340 3 17 17 * Taiwan Market Only. Please contact our representative if additional grade requirement is needed. Tungsten carbide grain size (μm) 0.2-0.5 0.5-0.8 0.8-1.3 1.3-2.5 2.5-6.0 Classification Ultrafine Submicron Fine Medium Coarse * The classification of carbides grain size corresponds to the recoendations of the Powder Metallurgy Association.
Grade Property & Recoendation Composition & Property 11 Corrosion Free Grade Ultrafine/ Fine 1μm NFS16 Innovative Grade. For stamping <0.6 stainless steel, Widely use in Electronics and Automotive connectors and lead frame industry. Hardness of HRA92, grade with combined high wear resistance and high toughness properties. Fine/ Ultrafine grain size & corrosion resistance that help to maintain a good surface quality and improve material stability & tool precision. MPa Submicron Medium 1μm 1μm NFS26 Optimized from WF30, for thin metal sheet and copper alloy stamping. Widely use in connector stamping, semi conductor stamping and electronics stamping industry. Submicron grain size & corrosion resistance help to maintain a good surface quality and improve material stability & tool precision. NFM23 Optimized from KG4 (Hardness on upper limit of KG4). For stamping silicon steel, rotor, stator. Medium grain size & corrosion resistance properties help to improve tool stability & precision. Good wear and corrosion resistance. Highly optimized for general use. NFM24 Optimized from KG4 (hardness on lower limit of KG4). For stamping silicon steel, rotor, stator, Iron sheet and aluminum sheet. Medium grain size & corrosion resistance help to improve tool stability & precision. Good wear and corrosion resistance. Highly optimized for general use. NFM25 Optimized from KG5, for stamping 0.5-1.5 metal sheet, iron plate and for strippers purpose. Fine grain size & corrosion resistance help to improve tool stability & precision. Good balance of wear resistance and toughness. Grade Property & Recoendation Composition & Property
12 Grade Property & Recoendation Composition & Property Ultrafine TF25+ For stamping thin copper alloy, lead frame and for making small punches. Ultrafine grade with high wear resistance, homogenous grain size, tremendously improve tool life. 1μm Composition & Property Grade Property & Recoendation Submicron Fine Medium 1μm 1μm WF30 For thin metal sheet, copper alloy stamping. Widely used in connector stamping, semi-conductor stamping and electronics stamping industry. CF8 For lead frame stamping and for perform making. KG7 For silicon steel, rotor, stator, iron sheet, aluminum stamping. Fine grain size, highly optimized for general use, A balance between toughness and surface quality. CF10 For thin electronic plate and copper alloy stamping. For perform making. CF12 For thin metal sheet and copper alloy stamping. KG4 For silicon steel, rotor, stator, iron sheet, aluminum stamping. Medium grain size, highly optimized for general application. 1μm Medium / Coarse KG5 For metal sheet stamping, medium/coarse grain size, high toughness. Highly optimized for general use. 1μm
Grade Property & Recoendation Concept of NF Corrosion Free Grade 13 Corrosion is still a topic which must be taken seriously. While in the past years corrosion was mainly associated with wire erosion, today s increasing demands mean that follow-up processes like further machining operations and handling are now also becoming more and more important. Severe wear in active components is frequently due to corrosive damage. Storage Corrosion speed Current density [µa/cm 2 ] Transport Coating 100,00000 10,00000 1,00000 0,10000 0,01000 0,00100 0,00010 Erosion NF- Standard Grinding,regrinding Cleaning Stamping,bending,forming NF Grade 0,00001-500 -250 0 250 500 Potential[mv] Reduced tendency towards corrosion The causes for wear can often be determined only through detailed metallurgic examination. CB CERATIZIT offers this service to its PARTNERS in the tool and die industry. Graph NF-process chain Corrosion-resistant carbide CB CERATIZIT s corrosion-resistant NF grades have become the standard in the tool and die industry. Maximum metallurgical consistency in combination with a factor 80 reduction in susceptibility to and speed of corrosion provide for longer machining times and maximum security, as depicted in the graphic showing the NF processes. Measured current density potential curves Grade Property & Recoendation Concept of NF Corrosion Free Grade Layer for protection Detailed information about our patented corrosion protection can be found in our technical article Newsletter of EDM and High Speed Stamping. Re and Cr mixed binder WC TEM picture of the protection layer of a carbide grade containing Cr and Re If you are interested or have any question, you re welcome to contact CB CERATIZIT or visit our website: www.cbceratizit.com
14 Carbide Blocks For WEDM Corrosion Resistant Grade W L T NF Grade sintered carbide blocks for EDM Corrosion Resistant Grade Carbide Blocks For WEDM L 100 105 150 200 Tol. +0/+1.0 +0/+1.0 W 100 150 200 105 150 200 105 150 200 200 1. Other dimensions and ground item are upon request 2. Thickness tolerance refer to Pg20 Tol. T Grade NFS16 NFS26 NFM23 NFM24 NFM25 +0/+1.0 1-60 +0/+1.0 1-60 +0/+1.0 1-60 20-60 20-60 20-60 =Standard item
Carbide Blocks For WEDM Normal Grade 15 W L T Sintered carbide blocks for EDM L Tol. W Tol. T Grade TF25+ WF30 KG4 KG7 KG5 100 +0/+1.0 1-20 21-60 100 105 150 200 +0/+1.0 +0/+1.0 150 200 105 150 200 105 150 200 200 1. Other dimensions and ground item are upon request 2. Thickness tolerance refer to Pg20 +0/+1.0 +0/+1.0 1-10 11-60 1-10 11-60 1-20 21-60 1-10 1-60 1-10 11-60 1-20 21-60 20-60 20-60 20-60 =Standard item Carbide Blocks For WEDM Normal Grade
16 Carbide Rods For High Speed Stamping Sintered Solid Rods L D Carbide Rods For High Speed Stsmping Sintered Solid Rods OD L 2.0 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 13.0 14.0 15.0 16.0 17.0 18.0 19.0 20.0 24.0 25.0 32.0 42.0 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.4 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.2/+0.5 +0.3/+0.6 +0.3/+0.6 +0.3/+0.6 +0.3/+0.6 +0.3/+0.6 +0.3/+0.7 +0.3/+0.7 +0.3/+0.7 +0.3/+0.7 +0.4/+0.8 +0.4/+0.8 +0.7/+1.3 +0.7/+1.3 1. Production range: Ø1-Ø80, other dimensions are upon request 2. Length tolerance : +1/+1.5 Sintered Rods For High Speed Stamping OD Tol. Grade TF25+ WF30 KG4 KG7 KG5 =Standard item
Carbide Rods For High Speed Stamping Ground Solid Rods 17 L D H6 Ground Solid Rods OD L OD Tol. Grade TF25+ WF30 KG4 KG7 KG5 2.0 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 13.0 14.0 15.0 16.0 17.0 18.0 19.0 20.0 24.0 25.0 32.0 +0.006/-0 +0.006/-0 +0.008/-0 +0.008/-0 +0.008/-0 +0.008/-0 +0.008/-0 +0.008/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.009/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.011/-0 +0.013/-0 +0.013/-0 +0.013/-0 +0.013/-0 +0.016/-0 Carbide Rods For High Speed Stamping Ground Solid Rods 1. Production range: Ø1-Ø80, other dimensions are upon request 2. Length tolerance: +1/+1.5 3. Ground tolerance can be upon request =Standard item
16 抗腐蝕NF 原理材質特性與推薦材質特性與推薦抗腐蝕 NF 原理
Preform For Stamping Preform 19 Customized Preform For the tool and die industry we exclusively deliver sintered parts which are produced on our state-of-the-art machines by the CB CERATIZIT skilled workers. It is therefore necessary to speak the same language with regard to the dimensions indicated in the drawings in order to manufacture products correctly (see illustrations below). In this context, it is a big advantage for you that you can illustrate the hole specifications etc. in a simplified way. The part will then be supplied in accordance with the appropriate tables. The way of transmitting the drawing represents a significant factor with regard to the time taken to process an order and the quality that is achieved. This is why we are going to use drawing transmission via e-mail to a larger degree. The file format should be.dwg or.dxf and large data amounts should be zipped. Preform Counterbore for M6 head socket screw Stepped bore for nuts fixed with adhesive Brazeed steel plug for M6 ØD3 ØD2 ØD1 Ød Ød Start hole(ø1/1.5/2/2.5/3/4) Preform drawing 1 Preform For Stamping Preform Ød Datum faces 10 30 50 70 85 100 70 70 75 65 60 80 20 (8X) Ø6 50 20 20 55 60 80 Ød1 110 Preform drawing 2 Preform drawing 3
20 Technical Information Thickness Tolerance Table Blocks Thickness Tolerance Table Thickness/ 70 65 60 55 50 45 40 35 30 Technical Information Thickness Tolerance Table 25 20 15 10 5 0 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 Tolerance/ CB CERATIZIT provides customized semi-finished products as well
Technical Information Mechanical Property 29 Hardness HV30 2500 2300 2100 1900 1700 1500 1300 1100 900 700 Hardness Hardness is a material's mechanical resistance to another, harder, material which penetrates it. This value is usually measured by "Vickers Harndess Procedure" (ISO 3878) or "Rockwell Hardness Procedure" (ISO 3738). Like wear resistance, hardness also increases with a smaller grain size and lower cobalt content. Therefore, hardness is often used as a reference for wear resistance. Ultrafine grades Submicron grades Fine / Medium grades Coarse grades Figure 1: Hardness in relation to the cobalt content and grain size Transverse rupture strength [MPa] 500 0 5 10 15 20 25 30 Cobalt content [%] 4500 4000 3500 3000 2500 2000 1500 0 5 10 15 20 25 30 Cobalt content [%] Transverse Rupture Strength Testing "Transverse Rupture Strength" is a coon procedure to analyse the mechanical property of carbide. Based on ISO 3327 standard, a material with fixed length is placed on two contact points and certain stress is given in the milddle until the material breaks. The average value of several tests is then determined as T.R.S. (Transverse Rupture Strength) Ultrafine grades Submicron grades Fine / Medium grades Coarse grades Figure 2: Transverse rupture strength in relation to the grain size and thecobalt content Technical Information Mechanical Property Toughness K IC [MN/m 3/2 ] 30 25 20 15 10 5 Fracture Toughness When a material is exposed to external stress, this leads to mechanical tensions. Under this circumstances, both the strengh and ductility of the material indicate the basis for the concept of toughness. In other words, toughness is defined as the capacity to resist fracture or rupture growth. "Palmqvist Method" is frequently applied to determine the toughness value, KIC. 0 0 5 10 15 20 25 30 Cobalt content [%] Ultrafine grades Submicron grades Fine / Medium grades Coarse grain grades Figure 3: Fracture toughness in relation to the grain size and the cobalt content
30 Technical Information Mechanical Property Compressive strength [N/ 2 ] 10000 9000 8000 7000 6000 5000 4000 3000 2000 0 5 10 15 20 25 Cobalt content [%] Compressive Strength One of the most remarkable properties of carbide is the extremely high compressive strengh under uniaxial stress. This precious property is applied to almost all applications. When metal binder content decreases and the grain size decreases, the compressive strength increases. A small grain carbide with a low metal binder content typically has a compressive strength of almost 7,000 N/2. The compressive strength decreases when the temperature increases. The degree of plastic deformation increase notably with the temperature, so that the results are variable when temperatures are high. Technical Information Mechanical Property Thermal conductivity [W/m*n C] 120 100 80 60 40 20 0 0 100 200 300 400 500 600 700 800 Temperature [ C] Submicron grades Fine / Medium grades Thermal Conductivity Coarse grades Extra-coarse grades Figure 4: Compressive strength in relation to the grain size and the cobalt content The thermal conductivity plays an important role in carbide applications, it determines the temperature in the wear areas and has a large influence on the carbide's thermal fatigure resistance and resistance to thermal fluctuations. The thermal conductivity of carbide is around twice as high as that of non-alloyed steel. Submicron grades Fine / Medium grades High y-phase content Coarse grades Low y-phase content Figure 5: Thermal conductivity in relation to the temperature of various micro-structures and grain sizes
Technical Information Mechanical Property 31 Modulus of elasticity [kn/ 2 ] 700 650 600 550 40 500 450 0 5 10 15 20 25 Cobalt content[%] Modulus of Elasticity The modulus of elasticity indicates the resistance of a material against elastic deformation. The modulus of elasticity for carbide is 2 to 3 times higher than in steel. It will increase linearly with decreaseing metal binder content. Figure 6: Modulus of elasticity of WC-Co carbides B R B -H C H S H Magnetic Saturation Carbides with cobalt as a metal binder are ferromagnetic. If a ferromagnetic material is exposed to a magnetic field strength H, the magnetic flux density B in this material increases (blue line). The flux density decreases when the field strength rises, until maximum saturation is achieved. Coercive Force Coercive Force is one of the property of magnetic material. The inverse field strength HC which is necessary to reduce the magnetic flux density to zero, or to 'de-magnetise' the material, is defined as coercive force. Coercive Force is usually measured in oersted (Oe) or ampere/meter (A/m) units and is denoted HC. It can be measured using a B-H analyzer or magnetometer. Figure 7: Hysteresis curve of a ferromagnetic material Technical Information Mechanical Property